Synthesis and crystal structures of [W(3,6-dichloro-1,2-benzenedithiolate) 3]n- (n = 1, 2) and [Mo(3,6-dichloro-1,2- benzenedithiolate)3]2-: Dependence of the coordination geometry on the oxidation number and counter-cation in trigonal-prismatic and octahedral structures

European Journal of Inorganic Chemistry

Volumn , Issue 15, 2005, Pages 3088-3092

  Sugimoto, Hideki ^a   Furukawa, Yuuki ^a   Tarumizu, Makoto ^a   Miyake, Hiroyuki ^a   Tanaka, Koji ^b   Tsukube, Hiroshi ^a  

^a Osaka Prefecture University   (Japan)

^b INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

Author keywords

Coordination modes; Molybdenum; S ligands; Salt effects; Tungsten

Indexed keywords

CHELATION; COORDINATION REACTIONS; CRYSTAL STRUCTURE; GEOMETRY; MOLYBDENUM; OXIDATION; POSITIVE IONS; REACTION INTERMEDIATES; X RAY CRYSTALLOGRAPHY;

BENZENEDITHIOLATE; COORDINATION GEOMETRY; COORDINATION MODES; COUNTER CATIONS; GEOMETRICAL CHANGES; OXIDATION NUMBERS; PRISMATIC STRUCTURES; S LIGANDS; SALT EFFECT; SYNTHESIS AND CRYSTAL STRUCTURE;

TUNGSTEN;

EID: 23744442627     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200500074     Document Type: Article

References (18)

1. C. Faulmann, P. Cassoux, Progress in Inorganic Chemistry: Solid-State Properties (Electronic, Magnetic, Optical) of Dithiolene Complex-Based Compounds (Ed.: E. I. Stiefel), John Wiley & Sons, New Jersey, 2004, 52, 399-489.
2. S. D. Cummings, R. Eisenberg, Progress in Inqrganic Chemistry: Luminescence and Photochemistry of Metal Dithiolene Complexes (Ed.: E. I. Stiefel), John Wiley & Sons, New Jersey, 2004, 52, 315-367.
3. S. J. N. Burgmayer, Progress in Inorganic Chemistry: Dithiolene in Biology (Ed.: E. I. Stiefel), John Wiley & Sons, New Jersey, 2004, 52, 491-537.
4. J. McMaster, J. M. Tunney, C. D. Garner, Progress in Inorganic Chemistry: Chemical Analogs of the Catalytic Centers of Molybdenum and Tungsten Dithiolene Containing Enzymes (Ed.: E. I. Stiefel), John Wiley & Sons, New Jersey, 2004, 52, 539-583.
5. J. A. McCleverty, Prog. Inorg. Chem. 1968, 10, 49-221.
6. A. Davison, R. H. Holm, Inorg. Synth. 1967, 10, 8-26.
7. C. L. Beswick, J. M. Schulman, E. I. Stiefel, Progress in Inorganic Chemistry: Structures and Structural Trends in Homoleptic Dithiolene Complexes (Ed.: E. I. Stiefel), John Wiley & Sons, New Jersey, 2004, 52, 55-110.
8. G. F. Brown, E. I. Stiefel, Inorg. Chem. 1973, 12, 2140-2147.
9. D. V. Fomitchev, B. S. Lim, R. H. Holm, Inorg. Chem. 2001, 40, 645-654.
10. F. Knoch, D. Sellmann, W. Kem, Z. Kristallogr. 1993, 250, 300-302.
11. C. Lorber, J. P. Donahue, C. A. Goddard, E. Nordlander, R. H. Holm, J. Am. Chem. Soc. 1998, 120, 8102-8112.
12. B. S. Lim, J. P. Donahue, R. H. Holm, Inorg. Chem. 2000, 39, 263-273.
13. T. E. Burrow, R. H. Morris, A. Hills, D. L. Hughes, R. L. Richards, Acta Crystallogr., Sect. C 1993, 49, 1591-1594.
14. H. Huynh, T. Lugger, F. E. Hahn, Eur. J. Inorg. Chem. 2002, 3007-3009.
15. C. A. Goddard, R. H. Holm, Inorg. Chem. 1999, 38, 5389-5398.
16. A. Altomare, M. Burla, M. Camalli, G. Cascarano, C. Giacovazzo, A. Guagliardi, A. Moliterni, G. Polidori, R. Spagna, J. Appl. Crystallogr. 1999, 32, 115-119.
17. P. T. Beurskens, G. Admiraal, G. Beurskens, W. P. Bosman, R. de Gelder, R. Israel, J. M. M. Smits, 1999. The DIRDIF-99 program system, Technical Report of the Crystallography Laboratory, University of Nijmegen, The Netherlands.
18. Crystal Structure Analysis Package, Rigaku and Rigaku/MSC, 2000-2004, 9009 New Trails Dr., The Woodlands, TX 77381, USA.