메뉴 건너뛰기




Volumn 129, Issue 41, 2007, Pages 12372-12373

Facile dehydrogenation of ethers and alkanes with a β-diiminate Pt fragment

Author keywords

[No Author keywords available]

Indexed keywords

ALKANE; CARBON; ETHER; HYDROGEN; LIGAND; METAL COMPLEX; PLATINUM DERIVATIVE;

EID: 35349026665     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja074488g     Document Type: Article
Times cited : (37)

References (32)
  • 9
    • 0003141829 scopus 로고    scopus 로고
    • Dehydrogenation of THF: (a) Gupta, M.; Kaska, W. C.; Jensen, C. M. Chem. Commun. 1997, 461.
    • Dehydrogenation of THF: (a) Gupta, M.; Kaska, W. C.; Jensen, C. M. Chem. Commun. 1997, 461.
  • 10
    • 0042567345 scopus 로고    scopus 로고
    • Dehydrogenation of tertiary amines: (b) Zhang, X.; Fried, A.; Knapp, S.; Goldman, A. S. Chem. Commun. 2003, 2060.
    • Dehydrogenation of tertiary amines: (b) Zhang, X.; Fried, A.; Knapp, S.; Goldman, A. S. Chem. Commun. 2003, 2060.
  • 21
    • 28944439469 scopus 로고    scopus 로고
    • Similar results observed with (nacnac)Ir: Bernskoetter, W. H.; Lobkovsky, E.; Chirik, P. J. Organometallics 2005, 24, 6250.
    • Similar results observed with (nacnac)Ir: Bernskoetter, W. H.; Lobkovsky, E.; Chirik, P. J. Organometallics 2005, 24, 6250.
  • 22
    • 35348933132 scopus 로고    scopus 로고
    • An analogous procedure was used to synthesize (nacnac)Pt(Me)(SMe 2) where the nacnac ligands contain p-Cl or OMe substituents: (a) Iverson, C. N, Carter, C. A. G, Scollard, J. D, Pribisko, M. A, John, K. D, Scott, B. L, Baker, R. T, Bercaw, J. E, Labinger, J. A. ACS Symp. Ser. 2004, 885, 319
    • 2) where the nacnac ligands contain p-Cl or OMe substituents: (a) Iverson, C. N.; Carter, C. A. G.; Scollard, J. D.; Pribisko, M. A.; John, K. D.; Scott, B. L.; Baker, R. T.; Bercaw, J. E.; Labinger, J. A. ACS Symp. Ser. 2004, 885, 319.
  • 23
    • 35348940040 scopus 로고    scopus 로고
    • The structure of 1b is given in the Supporting Information.
    • The structure of 1b is given in the Supporting Information.
  • 24
    • 0142040731 scopus 로고    scopus 로고
    • 2 in: Iverson, C. N.; Carter, C. A. G.; Baker, R. T.; Scollard, J. D.; Labinger, J. A.; Bercaw, J. E. J. Am. Chem. Soc. 2003, 125, 12674.
    • 2 in: Iverson, C. N.; Carter, C. A. G.; Baker, R. T.; Scollard, J. D.; Labinger, J. A.; Bercaw, J. E. J. Am. Chem. Soc. 2003, 125, 12674.
  • 25
    • 35348954187 scopus 로고    scopus 로고
    • 2) is formed as a byproduct.
    • 2) is formed as a byproduct.
  • 26
    • 35348940041 scopus 로고    scopus 로고
    • Pentene isomers were observed after 48 h at 50°C.
    • Pentene isomers were observed after 48 h at 50°C.
  • 30
    • 35349019647 scopus 로고    scopus 로고
    • Compound 2d was synthesized by adding excess TBE to 2c.
    • Compound 2d was synthesized by adding excess TBE to 2c.
  • 31
    • 35348988568 scopus 로고    scopus 로고
    • 1H NMR and GC.
    • 1H NMR and GC.
  • 32
    • 35348973379 scopus 로고    scopus 로고
    • Decomposition occurs rapidly above 60°C.
    • Decomposition occurs rapidly above 60°C.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.