Enantioselective hydrosilylation of ketimines with trichlorosilane promoted by chiral N-picolinoylaminoalcohols

Tetrahedron Letters

Volumn 48, Issue 45, 2007, Pages 7934-7937

  Zheng, Hongjie ^a,b   Deng, Jingen ^a   Lin, Wenqing ^a   Zhang, Xiaomei ^a  

^a CHENGDU INSTITUTE OF ORGANIC CHEMISTRY   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

Chiral amines; Hydrosilylation; Imines; Organocatalysis

Indexed keywords

ALCOHOL DERIVATIVE; AMINOALCOHOL; PICOLINE DERIVATIVE; SILANE DERIVATIVE;

ALCOHOL OXIDATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; ENANTIOSELECTIVITY; HYDROSILYLATION; REACTION ANALYSIS; STRUCTURE ANALYSIS;

EID: 35148865184     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2007.09.064     Document Type: Article

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33. 4, filtered and evaporated. Purification by chromatography (silica gel, hexane/EtOAc) afforded pure amine 5. The ee values were determined using established HPLC techniques with chiral stationary phases.