Role of noncovalent interactions in the enantioselective reduction of aromatic ketimines with trichlorosilane

Organic Letters

Volumn 6, Issue 13, 2004, Pages 2253-2256

  Malkov, Andrei V ^a   Mariani, Andrea ^a   MacDougall, Kenneth N ^a   Kočovský, Pavel ^a  

^a UNIVERSITY OF GLASGOW   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

IMINE; SILANE DERIVATIVE;

ARTICLE; ASYMMETRIC CATALYSIS; CATALYSIS; CATALYST; CHEMICAL REACTION; ENANTIOSELECTIVITY; HYDROGEN BOND; MOLECULAR INTERACTION; REACTION ANALYSIS; REDUCTION; STEREOCHEMISTRY; STRUCTURE ANALYSIS;

EID: 3142759422     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol049213+     Document Type: Article

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36. 11b
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41. 18 would dictate the formation of a different transition state, which may result in lower enantioselectivity.