Trimethylsilyl trifluoromethanesulfonate as a metal-free, homogeneous and strong lewis acid catalyst for efficient one-pot synthesis of α-aminonitriles and their fluorinated analogues

Synlett

Volumn , Issue 15, 2007, Pages 2395-2399

  Prakash, G K Surya ^a   Panja, Chiradeep ^a   Do, Clement ^a   Mathew, Thomas ^a   Olah, George A ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

Author keywords

aminonitriles; Fluorinated ketones; Metal free organocatalyst; Multicomponent reaction; TMSOTF

Indexed keywords

AMINONITRILE; KETONE; LEWIS ACID; TRIFLUOROMETHANESULFONIC ACID TRIMETHYLSILYL ESTER; TRIMETHYLSILYL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYST; FLUORINATION; ONE POT SYNTHESIS; STRECKER SYNTHESIS;

EID: 34948892808     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2007-985594     Document Type: Article

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103. 4. Removal of the solvent under reduced pressure provided the crude products. The crude product was triturated with excess hexanes for several times and removal of the solvents under reduced pressure afforded the Strecker product (α-aminonitriles) in almost analytically pure form (by NMR). The products were characterized by analyzing their spectral data and comparing them with those of the authentic samples (see supporting information, which is available from the authors, and ref. 10).