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The small amount of compound 1 that does not crystallize and stay in solution was separated by chromatography during the purification of the phosphane-borane complex (see the Exp. Sect.).
-
The small amount of compound 1 that does not crystallize and stay in solution was separated by chromatography during the purification of the phosphane-borane complex (see the Exp. Sect.).
-
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89
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34748881732
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We have assigned to the P1 atom (see Scheme 2) the signal at δ, 48.7 ppm, typical chemical shift of a hexacoordinate phosphorus atom, while to the P2 atom we have assigned the signal at δ, 60.1 ppm, typical of a tricoordinate phosphorus atom with a delocalized lone-pair. In the present case, the P2 atom is probably coordinated to the third MgBr+ ion
-
+ ion.
-
-
-
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