Rapid formation of triarylphosphines by microwave-assisted transition metal-catalyzed C-P cross-coupling reactions

Organic Letters

Volumn 4, Issue 20, 2002, Pages 3541-3543

  Stadler, Alexander ^a   Kappe, C Oliver ^a  

^a UNIVERSITY OF GRAZ   (Austria)

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ARTICLE;

EID: 0012046510     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol026716b     Document Type: Article

References (23)

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14. All microwave irradiation experiments were performed using the SmithSynthesizer from Personal Chemistry AB. For a detailed description of this instrument, see the following: Stadler, A.; Kappe, C. O. J. Comb Chem. 2001, 3, 624-630.
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19. CAUTION! Extreme care must be taken in order to avoid arcing (see ref 10) and destruction of the glass vessel in exposing these metaldoped vials (Figure S1 in Supporting Information) to microwave irradiation. For the use of Pd-doped porous glass tubing in microwave-assisted C-C coupling reactions, see the following: Li, J.; Mau, A. W.-H.; Strauss, C. R. Chem. Commun. 1997, 1275-1276.
20. Trans-di(μ-acetato)bis[o-(di-o-tolyl-phosphino)benzyl]dipalladium (II). For details, see the following: Herrmann, W. A.; Bohm, V. P. W.; Reisinger, C.-P. J. Organomet. Chem. 1999, 576, 23-41.
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