High atom-economical one-pot synthesis of secondary phosphines and their borane complexes using recycling phosphorus donor reagent

Organic Letters

Volumn 8, Issue 8, 2006, Pages 1677-1680

  Baccolini, Graziano ^a   Boga, Carla ^a   Mazzacurati, Marzia ^a   Sangirardi, Federico ^a  

^a UNIVERSITY OF BOLOGNA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33646469713     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol060284d     Document Type: Article

References (27)

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26. 15
27. As suggested by a reviewer, we have tested the possibility of obtaining other crowded sec-phosphines. As first results, we report that isopropyl(phenyl)phosphine and bis(2-methylphenyl)phosphine are obtained in good yields. Characterization data of these compounds are in agreement with those reported in the literature: Busacca, C. A.; Lorenz, J. C.; Grinberg, N.; Haddad, N.; Hrapchak, M.; Latli, B.; Lee, H.; Sabila, P.; Saha, A.; Sarvestani, M.; Shen, S.; Varsolona, R.; Wei, X.; Senanayake, C. H. Org. Lett. 2005, 7, 4277-4280. Work is in progress to evaluate limitations using other bulky groups.