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3 catalyzed the reaction of norbornene with 2,5-dichloroaniline to afford the hydroamination product in 78% yield. Similar results can be achieved by using a literature method, see: S. Repichet, C. L. Roux, N. Roques, J. Dubac, Tetrahedron Lett. 2003, 44, 2037-2040.
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3 catalyzed the reaction of norbornene with 2,5-dichloroaniline to afford the hydroamination product in 78% yield. Similar results can be achieved by using a literature method, see: S. Repichet, C. L. Roux, N. Roques, J. Dubac, Tetrahedron Lett. 2003, 44, 2037-2040.
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47
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34748844554
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We found that no hydroamination products could be detected by using tertbutylamine and phenylmethanamine under the current reaction conditions. By using 4methylbenzene-sulfonamide, a 32% isolated yield was obtained; further optimization is needed to obtain desirable results.
-
We found that no hydroamination products could be detected by using tertbutylamine and phenylmethanamine under the current reaction conditions. By using 4methylbenzene-sulfonamide, a 32% isolated yield was obtained; further optimization is needed to obtain desirable results.
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48
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34748895475
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A similar result was previously reported, see ref.[6b
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[6b]
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49
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34748879425
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[8d]
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[8d]
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