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Volumn 2, Issue 1, 2007, Pages 150-154

Bismuth- and hafnium-catalyzed hydroamination of vinyl arenes with sulfonamides, carbamates, and carboxamides

Author keywords

Bismuth; Hafnium; Homogeneous catalysis; Hydroamination; Synthetic methods

Indexed keywords

AMIDE; AROMATIC HYDROCARBON; BISMUTH; CARBAMIC ACID DERIVATIVE; HAFNIUM; SULFONAMIDE; VINYL DERIVATIVE;

EID: 33846316356     PISSN: 18614728     EISSN: 1861471X     Source Type: Journal    
DOI: 10.1002/asia.200600284     Document Type: Article
Times cited : (51)

References (53)
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    • Because the melting point of 1.4-dioxane is 11.8°C, DME was used alternatively at 8°C.
    • Because the melting point of 1.4-dioxane is 11.8°C, DME was used alternatively at 8°C.
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    • Although the possibility that TfOH is generated from the Hf(OTf) 4/ [Cu(CH3CN)4]PF6 system cannot be excluded completely, we assume that the results in Scheme 1 support the idea that Hf metal works as an active species at least for styrene 1c. For recently reported Brønsted acid catalyzed intermolecular hydroamination with amides, see reference [7
    • 6 system cannot be excluded completely, we assume that the results in Scheme 1 support the idea that Hf metal works as an active species at least for styrene 1c. For recently reported Brønsted acid catalyzed intermolecular hydroamination with amides, see reference [7].
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    • 6 system is not applicable to 4-methoxystyrene owing to competitive self-polymerization.
    • 6 system is not applicable to 4-methoxystyrene owing to competitive self-polymerization.


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