Platinum-Catalyzed Intermolecular Hydroamination of Unactivated Olefins with Carboxamides

Organometallics

Volumn 23, Issue 8, 2004, Pages 1649-1651

  Wang, Xiang ^a   Widenhoefer, Ross A ^a  

^a DUKE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYZED PROTOCOLS; INTERMOLECULES; NUCLEOPHILIC ATTACK; PRECIPITOUS DROP;

ALKYLATION; AMINATION; CARRIER CONCENTRATION; CATALYSTS; CHEMICAL BONDS; COMPLEXATION; DECOMPOSITION; MIXTURES; PLATINUM; PRECIPITATION (CHEMICAL); PROTONS; REACTION KINETICS;

ETHYLENE;

EID: 2342426017     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0498549     Document Type: Article

References (21)

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18. Continued heating of the reaction mixture led to no further consumption of benzamide. Reaction of secondary amines with ethylene catalyzed by 1 led to neither conversion nor catalyst decomposition, presumably due to formation of a stable platinum amine complex.
19. A similar transformation has been achieved by stoichiometric aminomercuration/reduction: (a) Barluenga, J.; Jimenez, C.; Najera, C.; Yus, M. J. Chem. Soc., Perkin Trans. 1 1983, 591. (b) Barluenga, J.; Ferrera, L.; Najera, C.; Yus, M. Synthesis 1984, 831.
20. A similar transformation has been achieved by stoichiometric aminomercuration/reduction: (a) Barluenga, J.; Jimenez, C.; Najera, C.; Yus, M. J. Chem. Soc., Perkin Trans. 1 1983, 591. (b) Barluenga, J.; Ferrera, L.; Najera, C.; Yus, M. Synthesis 1984, 831.
21. 2 without the intermediacy of III.