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Liang, L.-C.1
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34548621549
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An XRD study of 4 confirmed an overall connectivity related to 2 and 3. The structure, however, suffered from severe twinning
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An XRD study of 4 confirmed an overall connectivity related to 2 and 3. The structure, however, suffered from severe twinning.
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20
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34548640599
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II/I couple, predicting a hypothetical reduction potential of -2.9 V. A quenching experiment was undertaken and a Stern-Volmer plot (Figure S1) shows linear dependence of luminescence decay rate vs concentration of quencher, indicating a diffusion-controlled electron-transfer process. See Supporting Information for experimental details.
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II/I couple, predicting a hypothetical reduction potential of -2.9 V. A quenching experiment was undertaken and a Stern-Volmer plot (Figure S1) shows linear dependence of luminescence decay rate vs concentration of quencher, indicating a diffusion-controlled electron-transfer process. See Supporting Information for experimental details.
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21
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33845561689
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2 standard: Wallace, W. L.; Bard, A. J. J. Phys. Chem. 1979, 83, 1350-1357.
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2 standard: Wallace, W. L.; Bard, A. J. J. Phys. Chem. 1979, 83, 1350-1357.
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22
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0008662621
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Quinine sulfate standard: Demas, J. N.; Crosby, G. A. J. Chem. Phys. 1971, 75, 991-1024.
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Quinine sulfate standard: Demas, J. N.; Crosby, G. A. J. Chem. Phys. 1971, 75, 991-1024.
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23
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0033810303
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Scaltrito, D. V.; Thompson, D. W.; O'Callaghan, J. A.; Meyer, G. J. Coord. Chem. Rev. 2000, 208, 243-266.
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Scaltrito, D.V.1
Thompson, D.W.2
O'Callaghan, J.A.3
Meyer, G.J.4
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24
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34548616650
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Similar emission from crystalline and solution samples is consistent with an unchanged structure in solution
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Similar emission from crystalline and solution samples is consistent with an unchanged structure in solution.
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25
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34548631246
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The decay profile of 8 was highly reproducible in repeated data collection on independently crystallized, analytically pure samples.
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The decay profile of 8 was highly reproducible in repeated data collection on independently crystallized, analytically pure samples.
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26
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33845550112
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Kirchhoff, J. R.; Gamache, R. E., Jr.; Blaskie, M. W.; Del Paggio, A. D.; Lengel, R. K.; McMillin, D. R. Inorg. Chem. 1983, 22, 2380-2384.
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Kirchhoff, J.R.1
Gamache Jr., R.E.2
Blaskie, M.W.3
Del Paggio, A.D.4
Lengel, R.K.5
McMillin, D.R.6
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27
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34548622886
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The calculation for 3 was performed using the hybrid DFT functional B3LYP/LACVP** as implemented in the Jaguar 6.5 program package (see Supporting Information).
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The calculation for 3 was performed using the hybrid DFT functional B3LYP/LACVP** as implemented in the Jaguar 6.5 program package (see Supporting Information).
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28
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34548610073
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The HOMO-1 and HOMO-2 orbitals feature appreciably more Cu d character: HOMO-1 (45% Cu; 13% P; 21% N; 20% C). HOMO-2 (46% Cu; 23% P; 15% N; 26% C).
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The HOMO-1 and HOMO-2 orbitals feature appreciably more Cu d character: HOMO-1 (45% Cu; 13% P; 21% N; 20% C). HOMO-2 (46% Cu; 23% P; 15% N; 26% C).
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29
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12944312233
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0 metal shows both charge transfer (LMCT) and N lone pair to arene π* excited states: Da Re, R. E.; Jantunen, K. C.; Golden, J. T.; Kiplinger, J. L.; Morris, D. E. J. Am. Chem. Soc. 2005, 127, 682-689.
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0 metal shows both charge transfer (LMCT) and N lone pair to arene π* excited states: Da Re, R. E.; Jantunen, K. C.; Golden, J. T.; Kiplinger, J. L.; Morris, D. E. J. Am. Chem. Soc. 2005, 127, 682-689.
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30
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0003988115
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Que, L, Jr, Ed, University Science Books: Sausalito, CA
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McMillin, D. R. In Physical Methods in Bioinorganic Chemistry: Spectroscopy and Magnetism; Que, L., Jr., Ed.; University Science Books: Sausalito, CA, 2000; pp 25-27.
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McMillin, D.R.1
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See, for example
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See, for example, Timpson, C. J.; Bignozzi, C. A.; Sullivan, B. P.; Kober, E. M.; Meyer, T. J. J. Phys. Chem. 1996, 100, 2915-2925.
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J. Phys. Chem
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Timpson, C.J.1
Bignozzi, C.A.2
Sullivan, B.P.3
Kober, E.M.4
Meyer, T.J.5
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