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Volumn 46, Issue 18, 2007, Pages 7244-7246

Long-lived and efficient emission from mononuclear amidophosphine complexes of copper

Author keywords

[No Author keywords available]

Indexed keywords

COPPER; ORGANOMETALLIC COMPOUND; PHOSPHINE DERIVATIVE;

EID: 34548642088     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic7009513     Document Type: Article
Times cited : (99)

References (31)
  • 1
    • 0141542056 scopus 로고    scopus 로고
    • Jr
    • (a) Vlcek, A., Jr. Coord. Chem. Rev. 2000, 200-202, 933-977.
    • (2000) Coord. Chem. Rev , vol.200-202 , pp. 933-977
    • Vlcek, A.1
  • 19
    • 34548621549 scopus 로고    scopus 로고
    • An XRD study of 4 confirmed an overall connectivity related to 2 and 3. The structure, however, suffered from severe twinning
    • An XRD study of 4 confirmed an overall connectivity related to 2 and 3. The structure, however, suffered from severe twinning.
  • 20
    • 34548640599 scopus 로고    scopus 로고
    • II/I couple, predicting a hypothetical reduction potential of -2.9 V. A quenching experiment was undertaken and a Stern-Volmer plot (Figure S1) shows linear dependence of luminescence decay rate vs concentration of quencher, indicating a diffusion-controlled electron-transfer process. See Supporting Information for experimental details.
    • II/I couple, predicting a hypothetical reduction potential of -2.9 V. A quenching experiment was undertaken and a Stern-Volmer plot (Figure S1) shows linear dependence of luminescence decay rate vs concentration of quencher, indicating a diffusion-controlled electron-transfer process. See Supporting Information for experimental details.
  • 21
    • 33845561689 scopus 로고    scopus 로고
    • 2 standard: Wallace, W. L.; Bard, A. J. J. Phys. Chem. 1979, 83, 1350-1357.
    • 2 standard: Wallace, W. L.; Bard, A. J. J. Phys. Chem. 1979, 83, 1350-1357.
  • 22
    • 0008662621 scopus 로고    scopus 로고
    • Quinine sulfate standard: Demas, J. N.; Crosby, G. A. J. Chem. Phys. 1971, 75, 991-1024.
    • Quinine sulfate standard: Demas, J. N.; Crosby, G. A. J. Chem. Phys. 1971, 75, 991-1024.
  • 24
    • 34548616650 scopus 로고    scopus 로고
    • Similar emission from crystalline and solution samples is consistent with an unchanged structure in solution
    • Similar emission from crystalline and solution samples is consistent with an unchanged structure in solution.
  • 25
    • 34548631246 scopus 로고    scopus 로고
    • The decay profile of 8 was highly reproducible in repeated data collection on independently crystallized, analytically pure samples.
    • The decay profile of 8 was highly reproducible in repeated data collection on independently crystallized, analytically pure samples.
  • 27
    • 34548622886 scopus 로고    scopus 로고
    • The calculation for 3 was performed using the hybrid DFT functional B3LYP/LACVP** as implemented in the Jaguar 6.5 program package (see Supporting Information).
    • The calculation for 3 was performed using the hybrid DFT functional B3LYP/LACVP** as implemented in the Jaguar 6.5 program package (see Supporting Information).
  • 28
    • 34548610073 scopus 로고    scopus 로고
    • The HOMO-1 and HOMO-2 orbitals feature appreciably more Cu d character: HOMO-1 (45% Cu; 13% P; 21% N; 20% C). HOMO-2 (46% Cu; 23% P; 15% N; 26% C).
    • The HOMO-1 and HOMO-2 orbitals feature appreciably more Cu d character: HOMO-1 (45% Cu; 13% P; 21% N; 20% C). HOMO-2 (46% Cu; 23% P; 15% N; 26% C).
  • 29
    • 12944312233 scopus 로고    scopus 로고
    • 0 metal shows both charge transfer (LMCT) and N lone pair to arene π* excited states: Da Re, R. E.; Jantunen, K. C.; Golden, J. T.; Kiplinger, J. L.; Morris, D. E. J. Am. Chem. Soc. 2005, 127, 682-689.
    • 0 metal shows both charge transfer (LMCT) and N lone pair to arene π* excited states: Da Re, R. E.; Jantunen, K. C.; Golden, J. T.; Kiplinger, J. L.; Morris, D. E. J. Am. Chem. Soc. 2005, 127, 682-689.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.