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1
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85163234813
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Amination of aryl halides: M. Nishiyama, T. Yamamoto, Y. Koie, Tetrahedron Lett. 1998, 39, 617-620.
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Amination of aryl halides: M. Nishiyama, T. Yamamoto, Y. Koie, Tetrahedron Lett. 1998, 39, 617-620.
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-
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2
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85163230859
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Amination and Suzuki coupling of aryl chlorides: J. P. Wolfe, S. L. Buchwald, Angew. Chem. Int. Ed. 1999, 38, 2413-2416.
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Amination and Suzuki coupling of aryl chlorides: J. P. Wolfe, S. L. Buchwald, Angew. Chem. Int. Ed. 1999, 38, 2413-2416.
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3
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-
85163223281
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Stille cross-coupling: A. F. Littke, G. C. Fu, Angew. Chem. Int. Ed. 1999, 38, 2411-2412.
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Stille cross-coupling: A. F. Littke, G. C. Fu, Angew. Chem. Int. Ed. 1999, 38, 2411-2412.
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4
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85163229614
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Aromatic C-O bond formation: A. Aranyos, D. W. Old, A. Kiyomori, J. P. Wolfe, J. P. Sadighi, S. L. Buchwald, J. Am. Chem. Soc. 1999, 121, 4369-4378.
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5
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85163232473
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Representative examples. α-Arylation of ketones: J. M. Fox, X. Huang, A. Chieffi, S. L. Buchwald, J. Am. Chem. Soc. 2000, 122, 1360-1370.
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Representative examples. α-Arylation of ketones: J. M. Fox, X. Huang, A. Chieffi, S. L. Buchwald, J. Am. Chem. Soc. 2000, 122, 1360-1370.
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85163233685
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Rhodium promotes addition of boronic acids to aldehydes: M. Ueda, N. Miyaura, J. Org. Chem. 2000, 65, 4450-4452.
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7
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85163228539
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Alkyl Suzuki cross-couplings: M. R. Netherton, C. Dai, K. Neuschütz, G. C. Fu, J. Am. Chem. Soc. 2001, 123, 10099-10100.
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Alkyl Suzuki cross-couplings: M. R. Netherton, C. Dai, K. Neuschütz, G. C. Fu, J. Am. Chem. Soc. 2001, 123, 10099-10100.
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8
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85163234433
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Heck reactions: A. F. Littke, G. C. Fu, J. Am. Chem. Soc. 2001, 123, 6989-7000.
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Heck reactions: A. F. Littke, G. C. Fu, J. Am. Chem. Soc. 2001, 123, 6989-7000.
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9
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85163224522
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The use of electron-rich ferrocenylphosphanes has been extended also, albeit far less extensively to date, to organocatalytic transformations: S. I. Pereira, J. Adrio, A. M. S. Silva, J. C. Carretero, J. Org. Chem. 2005, 70, 10175-10177.
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The use of electron-rich ferrocenylphosphanes has been extended also, albeit far less extensively to date, to organocatalytic transformations: S. I. Pereira, J. Adrio, A. M. S. Silva, J. C. Carretero, J. Org. Chem. 2005, 70, 10175-10177.
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However, chiral phosphanes based on ferrocenophane moieties have been reported where all-carbon tethers link the cyclopentadienyl rings. For representative examples see: a
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However, chiral phosphanes based on ferrocenophane moieties have been reported where all-carbon tethers link the cyclopentadienyl rings. For representative examples see: a) T. Sturm, W. Weissensteiner, F. Spindler, K. Mereiter, A. M. López-Agenjo, B. R. Manzano, F. A. Jalón, Organometallics 2002, 21, 1766-1774;
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46
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85163231047
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For detailed discussions on the stereochemistry of substitution reactions on ferrocenylmethyl cations, see: G. Wagner, R. Herrmann in Ferrocenes Eds, A. Togni, T. Hayashi, VCH, Weinheim, 1995, Part 2, pp. 173-218
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For detailed discussions on the stereochemistry of substitution reactions on ferrocenylmethyl cations, see: G. Wagner, R. Herrmann in Ferrocenes (Eds.: A. Togni, T. Hayashi), VCH, Weinheim, 1995, Part 2, pp. 173-218.
-
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47
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85163225186
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H-P coupling constants are expected for large dihedral angles between the P-C-H and P-C-lone-pair planes: J. P. Albrand, D. Gagnaire, J. B. Robert, J. Chem. Soc. Chem. Commun. 1968, 1469-1470.
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H-P coupling constants are expected for large dihedral angles between the P-C-H and P-C-lone-pair planes: J. P. Albrand, D. Gagnaire, J. B. Robert, J. Chem. Soc. Chem. Commun. 1968, 1469-1470.
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85163223604
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[17a].
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[17a].
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53
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0344153297
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H. Seo, B. Y. Kim, J. H. Lee, H. J. Park, S. U. Son, Y. K. Chung, Organometallics 2003, 22, 4783-4791.
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54
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85163232380
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[17c]). However, for our purposes, this is not an economically convenient method, as a meso product would result from the subsequent cyclisation reaction with the primary phosphane.
-
[17c]). However, for our purposes, this is not an economically convenient method, as a meso product would result from the subsequent cyclisation reaction with the primary phosphane.
-
-
-
-
56
-
-
85163235642
-
-
[19,20a]).
-
[19,20a]).
-
-
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-
57
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-
85163229958
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[20a]) or acetic acid as the catalyst. Only the second procedure has been applied to the stereospecific synthesis of chiral phosphanes: R. J. Kloetzing, M. Lotz, P. Knochel, Tetrahedron: Asymmetry 2003, 14, 255-264.
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[20a]) or acetic acid as the catalyst. Only the second procedure has been applied to the stereospecific synthesis of chiral phosphanes: R. J. Kloetzing, M. Lotz, P. Knochel, Tetrahedron: Asymmetry 2003, 14, 255-264.
-
-
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59
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85163225530
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Analogous structural features have been observed also in 2-phospha[3]ferrocenophanes with nitrogen atoms in the bridging chain: B. Wrackmeyer, E. V. Klimkina, W. Milius, Inorg. Chem. Commun. 2004, 7, 884-888.
-
Analogous structural features have been observed also in 2-phospha[3]ferrocenophanes with nitrogen atoms in the bridging chain: B. Wrackmeyer, E. V. Klimkina, W. Milius, Inorg. Chem. Commun. 2004, 7, 884-888.
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85163234946
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For previous uses of 7 as a resolving agent, see, for instance: a J. M. Valk, T. D. W. Claridge, J. M. Brown, D. Hibbs, M. B. Hursthouse, Tetrahedron: Asymmetry 1995, 6, 2597-2610;
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For previous uses of 7 as a resolving agent, see, for instance: a) J. M. Valk, T. D. W. Claridge, J. M. Brown, D. Hibbs, M. B. Hursthouse, Tetrahedron: Asymmetry 1995, 6, 2597-2610;
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