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54
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2642640537
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note
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2-symmetrical cases is reached only with an aryl substituent.
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For a discussion of older work on chiral ferrocenyl amines, see: a) R. Herrmann, G. Hübener, F. Siglmüller, I. Ugi, Liebigs Ann. Chem. 1986, 251-268; b) I. R. Butler, W. R. Cullen, Can. J. Chem. 1983, 61, 2354 - 2358. For recent developments, see : c) D. Enders, R. Lochtman, G. Raabe, Synlett 1996, 126-128; d) D. Enders, R. Lochtman, ibid. 1997, 355-356; e) T. Hayase, Y. Inoue, T. Shibata, K. Soai, Tetrahedron Asymmetry 1996, 7, 2509-2510; f) X. Verdaguer, U. E. W. Lange, M. T. Reding, S. L. Buchwald, J. Am. Chem. Soc. 1996, 118, 6784-6785.
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For a discussion of older work on chiral ferrocenyl amines, see: a) R. Herrmann, G. Hübener, F. Siglmüller, I. Ugi, Liebigs Ann. Chem. 1986, 251-268; b) I. R. Butler, W. R. Cullen, Can. J. Chem. 1983, 61, 2354 - 2358. For recent developments, see : c) D. Enders, R. Lochtman, G. Raabe, Synlett 1996, 126-128; d) D. Enders, R. Lochtman, ibid. 1997, 355-356; e) T. Hayase, Y. Inoue, T. Shibata, K. Soai, Tetrahedron Asymmetry 1996, 7, 2509-2510; f) X. Verdaguer, U. E. W. Lange, M. T. Reding, S. L. Buchwald, J. Am. Chem. Soc. 1996, 118, 6784-6785.
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For a discussion of older work on chiral ferrocenyl amines, see: a) R. Herrmann, G. Hübener, F. Siglmüller, I. Ugi, Liebigs Ann. Chem. 1986, 251-268; b) I. R. Butler, W. R. Cullen, Can. J. Chem. 1983, 61, 2354 - 2358. For recent developments, see : c) D. Enders, R. Lochtman, G. Raabe, Synlett 1996, 126-128; d) D. Enders, R. Lochtman, ibid. 1997, 355-356; e) T. Hayase, Y. Inoue, T. Shibata, K. Soai, Tetrahedron Asymmetry 1996, 7, 2509-2510; f) X. Verdaguer, U. E. W. Lange, M. T. Reding, S. L. Buchwald, J. Am. Chem. Soc. 1996, 118, 6784-6785.
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For a discussion of older work on chiral ferrocenyl amines, see: a) R. Herrmann, G. Hübener, F. Siglmüller, I. Ugi, Liebigs Ann. Chem. 1986, 251-268; b) I. R. Butler, W. R. Cullen, Can. J. Chem. 1983, 61, 2354 - 2358. For recent developments, see : c) D. Enders, R. Lochtman, G. Raabe, Synlett 1996, 126-128; d) D. Enders, R. Lochtman, ibid. 1997, 355-356; e) T. Hayase, Y. Inoue, T. Shibata, K. Soai, Tetrahedron Asymmetry 1996, 7, 2509-2510; f) X. Verdaguer, U. E. W. Lange, M. T. Reding, S. L. Buchwald, J. Am. Chem. Soc. 1996, 118, 6784-6785.
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For a discussion of older work on chiral ferrocenyl amines, see: a) R. Herrmann, G. Hübener, F. Siglmüller, I. Ugi, Liebigs Ann. Chem. 1986, 251-268; b) I. R. Butler, W. R. Cullen, Can. J. Chem. 1983, 61, 2354 - 2358. For recent developments, see : c) D. Enders, R. Lochtman, G. Raabe, Synlett 1996, 126-128; d) D. Enders, R. Lochtman, ibid. 1997, 355-356; e) T. Hayase, Y. Inoue, T. Shibata, K. Soai, Tetrahedron Asymmetry 1996, 7, 2509-2510; f) X. Verdaguer, U. E. W. Lange, M. T. Reding, S. L. Buchwald, J. Am. Chem. Soc. 1996, 118, 6784-6785.
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For a similar preparation of the diphosphines 27, see ref. [12b]
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For a similar preparation of the diphosphines 27, see ref. [12b].
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