Catalytic conversion of biomass pyrolysis products by mesoporous materials: Effect of steam stability and acidity of Al-MCM-41 catalysts

Chemical Engineering Journal

Volumn 134, Issue 1-3, 2007, Pages 51-57

  Iliopoulou, E F ^a,b   Antonakou, E V ^b   Karakoulia, S A ^a   Vasalos, I A ^b   Lappas, A A ^b   Triantafyllidis, K S ^a  

^a ARISTOTLE UNIVERSITY OF THESSALONIKI   (Greece)

^b Centre for Research Technology Hellas   (Greece)

Author keywords

Acidity; Al MCM 41; Bio oil; Catalytic biomass pyrolysis; Chemicals phenols; Hydrothermal stability

Indexed keywords

ACIDITY; ALUMINOSILICATES; CATALYSTS; HYDROCARBONS; MESOPOROUS MATERIALS; MOLECULAR WEIGHT; PHENOLS; PYROLYSIS;

CATALYTIC MATERIALS; CORROSIVE ACIDS; STEAMING TEMPERATURE;

BIOMASS;

ACIDITY; ALUMINOSILICATES; BIOMASS; CATALYSTS; HYDROCARBONS; MESOPOROUS MATERIALS; MOLECULAR WEIGHT; PHENOLS; PYROLYSIS;

EID: 34548218277     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2007.03.066     Document Type: Article

References (25)

1. Demirbas M.F., and Balat M. Recent advances on the production and utilization trends of bio-fuels: a global perspective. Energy Convers. Managem. 47 (2006) 2371-2381
2. McKendry P. Energy production from biomass (part 1): overview of biomass. Bioresour. Technol. 83 (2002) 37-46
3. Yaman S. Pyrolysis of biomass to produce fuels and chemical feedstocks. Energy Convers. Managem. 45 (2004) 651-671
4. Demirbas A. Mechanism of liquefaction and pyrolysis reactions of biomass. Energy Convers. Managem. 41 (2000) 633-646
5. Bridgwater A.V., and Peacocke G.V.C. Fast pyrolysis processes for biomass. Renew. Sustain. Energy Rev. 4 (2000) 1-73
6. Demirbas A. Biomass resource facilities and biomass conversion processing for fuels and chemicals. Energy Convers. Managem. 42 (2001) 1357-1378
7. Meier D., and Faix O. State of the art of applied fast pyrolysis of lignocellulosic materials-a review. Bioresour. Technol. 68 (1999) 71-77
8. Islam M.N., and Beg M.R.A. The fuel properties of pyrolysis liquid derived from urban solid wastes in Bangladesh. Bioresour. Technol. 92 (2004) 181-186
9. Horne P.A., and Williams P.T. Premium quality fuels and chemicals from the fluidized bed pyrolysis of biomass with zeolite catalyst upgrading. Renewable Energy 5 (1994) 810-812
10. Bridgwater A.V. Catalysis in thermal biomass conversion. Appl. Catal. A: Gen. 116 (1994) 5-47
11. Williams P.T., and Nugranad N. Comparison of products from the pyrolysis and catalytic pyrolysis of rice husks. Energy 25 (2000) 493-513
12. Huber G.W., and Dumesic J.A. An overview of aqueous-phase catalytic processes for production of hydrogen and alkanes in a biorefinery. Catal. Today 111 (2006) 119-132
13. Stoikos T. In: Bridgwater A.V., and Grassi G. (Eds). Biomass Pyrolysis Liquids, Upgrading and Utilisation (1991), Elsevier, London 227-239
14. Bridgwater A.V. Production of high grade fuels and chemicals from catalytic pyrolysis of biomass. Catal. Today 29 (1996) 285-295
15. Antonakou E., Lappas A., Nilsen M.H., Bouzga A., and Stöcker M. Evaluation of various types of Al-MCM-41 materials as catalysts in biomass pyrolysis for the production of bio-fuels and chemicals. Fuel 85 (2006) 2202-2212
16. Williams P.T., and Horne P.A. The influence of catalyst type on the composition of upgraded biomass pyrolysis oils. J. Anal. Appl. Pyrol. 31 (1995) 39-61
17. ® lignin using HZSM-5 catalyst. Fuel Process. Technol. 62 (2000) 17-30
18. Adam J., Antonakou E., Lappas A., Stöcker M., Nilsen M.H., Bouzga A., Hustad J.E., and Øye G. In-situ catalytic upgrading of biomass derived fast pyrolysis vapours in a fixed bed reactor using mesoporous materials. Microporous Mesoporous Mater. 96 (2006) 93-101
19. Triantafyllidis K.S., Iliopoulou E.F., Antonakou E.V., Lappas A.A., Wang H., and Pinnavaia T.J. Hydrothermally stable mesoporous aluminosilicates (MSU-S) assembled from zeolites seeds as catalysts for biomass pyrolysis. Micropor. Mesopor. Mater. 99 (2007) 132-139
20. Ateş F., Pütün A.E., and Pütün E. Pyrolysis of two different biomass samples in a fixed-bed reactor combined with two different catalysts. Fuel 85 (2006) 1851-1859
21. Twaiq F.A., Mohamed R.A., and Bhatia S. Liquid hydrocarbon fuels from palm oil by catalytic cracking over aluminosilicate mesoporous catalysts with various Si/Al ratios. Microporous Mesoporous Mater. 64 (2003) 95-107
22. Twaiq F.A.A., Mohamad A.R., and Bhatia S. Performance of composite catalysts in pulm oil cracking for the production of liquid fuels and chemicals. Fuel Process. Technol. 85 (2004) 1283-1300
23. Corma A., Grande M.S., Gonzalez-Alfaro V., Orchilles A.V., and Cracking Activity. Hydrothermal stability of MCM-41 and its comparison with amorphous silica-alumina and a USY Zeolite. J. Catal. 159 (1996) 375
24. Beck J.S., Vartuli J.C., Roth W.J., Leonowicz M.E., Kresge C.T., Schmitt K.D., Chu C.T.W., Olson D.H., Sheppard E.W., McCullen S.B., Higgins J.B., and Schlenker J.L. A new family of mesoporous molecular sieves prepared with liquid crystals templates. J. Am. Chem. Soc. 114 (1992) 10834-10843
25. Triantafyllidis K.S., Lappas A.A., Vasalos I.A., Liu Y., Wang H., and Pinnavaia T.J. Gas-oil cracking activity of hydrothermally stable aluminosilicate mesostructures (MSU-S) assembled from zeolite seeds: effect of the type of framework structure and porosity. Catal. Today 112 (2006) 33-36