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C50H82O12Si8Zn 2)2, Mr, 2461.32, monoclinic, P21/n, a, 14.8772(6) Å, b, 17.9401(7) Å, c, 21.9733(8) Å, β= 90.006(1)°, V, 5864.6(4) Å3, Z= 2, Dx= 1.394 g·cm-3, F(000, 2600, μ, 10.38 cm-1, T, 110 K, 53279 reflections measured, GOF, 1.041, Rw(F2, 0.0869, R(F, 0.0327. Data were collected on a Nonius Kappa CCD area detector with a graphite monochromator λ, 0.71073 Å
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Reaction conditions: 100 μmol of the dimeric catalyst, 15 mL of CHO, 35 mL of toluene, 120 °C, 80 bar.
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Reaction conditions: 100 μmol of the dimeric catalyst, 15 mL of CHO, 35 mL of toluene, 120 °C, 80 bar.
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A silanol group is more acidic than a cyclohexanol, which is a good indication that the silanol is a better leaving group. See ref 14.
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2 mixtures at 120 °C and 20% conversion is typically lower than 2%.
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2 mixtures at 120 °C and 20% conversion is typically lower than 2%.
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