Carbene- and carbyne-like behavior of the Mo-P multiple bond in a dimolybdenum complex inducing trigonal-pyramidal coordination of a phosphinidene ligand

Inorganic Chemistry

Volumn 46, Issue 16, 2007, Pages 6230-6232

  Alvarez, M Angeles ^a   Amor, Inmaculada ^a   García, M Esther ^a   García Vivó, Daniel ^a   Ruiz, Miguel A ^a  

^a UNIVERSITY OF OVIEDO   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 34548008861     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic701055y     Document Type: Article

References (36)

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24. 3, T = 120 K, Z = 4, R = 0.0194, GOF = 1.083.
25. DFT calculations were performed with the GAUSSIAN03 program package using the hybrid method B3LYP, together with the standard 6-31G* basis set on all atoms except Mo, for which a valence double-ζ quality basis set and LANL2DZ effective core potentials were used. See the Supporting Information for further details.
26. PC = 27 Hz, C=C].
27. Zhao, G.; Basuli, F.; Kilgore, U. J.; Fan, H.; Aneetha, H.; Huffman, J. C.; Wu, G.; Mindiola, D. J. J. Am. Chem. Soc. 2006, 128, 13575.
28. 3, T = 100 K, Z = 4, R = 0.0305, GOF = 1.057.
29. 4, minor isomer).
30. 4).
31. 3, T = 150 K, Z = 4, R = 0.0331, GOF = 1.062.
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34. 4).
35. 3, T = 100 K, Z = 4, R = 0.0524, GOF = 1.089.
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