Generating and dimerizing the transient 16-electron phosphinidene complex [Cp*Ir=PAr]: A theoretical and experimental study

Chemistry - A European Journal

Volumn 10, Issue 16, 2004, Pages 4063-4072

  Termaten, Arjan T ^a   Nijbacker, Tom ^a   Ehlers, Andreas W ^a   Schakel, Marius ^a   Lutz, Martin ^b   Spek, Anthony L ^b   McKee, Michael L ^c   Lammertsma, Koop ^a  

^a VU UNIVERSITY AMSTERDAM   (Netherlands)

^b UTRECHT UNIVERSITY   (Netherlands)

^c AUBURN UNIVERSITY   (United States)

Author keywords

Density functional calculations; Iridium; N ligands; P ligands

Indexed keywords

BEND GEOMETRY; REACTIVE PLANAR STRUCTURES; STERIC CONGESTION;

HYDROGEN BONDS; MOLECULAR DYNAMICS; MOLECULAR STRUCTURE; PHOSPHATES;

DIMERIZATION;

IRIDIUM; METAL COMPLEX; PHOSPHINIDENE COMPLEX; PHOSPHORUS; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CHEMICAL BOND; DENSITY FUNCTIONAL THEORY; DIMERIZATION; ELECTRON; GEOMETRY; HALOGENATION; LOW TEMPERATURE PROCEDURES; STEREOCHEMISTRY;

COMPUTER SIMULATION; CRYSTALLOGRAPHY, X-RAY; DIMERIZATION; ELECTRONS; IRIDIUM; MODELS, MOLECULAR; MOLECULAR CONFORMATION; ORGANOMETALLIC COMPOUNDS; PHOSPHINES; THERMODYNAMICS;

EID: 4444376741     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200400080     Document Type: Article

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