-
1
-
-
33746295241
-
-
(a) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. 1995, 34, 1143-1170.
-
(1995)
Angew. Chem., Int. Ed
, vol.34
, pp. 1143-1170
-
-
Brintzinger, H.H.1
Fischer, D.2
Mülhaupt, R.3
Rieger, B.4
Waymouth, R.M.5
-
2
-
-
0004129985
-
-
Togni, A, Haltermann, R. L, Eds, Wiley-VCH: Weinheim, Germany, Vols, and 2
-
(b) Janiak, C. In Metallocenes; Togni, A., Haltermann, R. L., Eds.; Wiley-VCH: Weinheim, Germany, 1998; Vols. 1 and 2.
-
(1998)
Metallocenes
, vol.1
-
-
Janiak, C.1
-
3
-
-
0033740673
-
-
(c) Resconi, L.; Cavallo, L.; Fait, A.; Piemontesi, F. Chem. Rev. 2000, 100, 1253-1345.
-
(2000)
Chem. Rev
, vol.100
, pp. 1253-1345
-
-
Resconi, L.1
Cavallo, L.2
Fait, A.3
Piemontesi, F.4
-
4
-
-
0033557814
-
-
(a) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 38, 428-447.
-
(1999)
Angew. Chem., Int. Ed
, vol.38
, pp. 428-447
-
-
Britovsek, G.J.P.1
Gibson, V.C.2
Wass, D.F.3
-
6
-
-
0000061624
-
-
(c) Makio, H.; Kashiwa, N.; Fujita, T. Adv. Synth. Catal. 2002, 344, 477-493.
-
(2002)
Adv. Synth. Catal
, vol.344
, pp. 477-493
-
-
Makio, H.1
Kashiwa, N.2
Fujita, T.3
-
7
-
-
10044243570
-
-
(d) Park, S.; Han, Y.; Kim, S. K.; Lee, J.; Kim, H. K.; Do, Y. J. Organomet. Chem. 2004, 689, 4263-4276.
-
(2004)
J. Organomet. Chem
, vol.689
, pp. 4263-4276
-
-
Park, S.1
Han, Y.2
Kim, S.K.3
Lee, J.4
Kim, H.K.5
Do, Y.6
-
8
-
-
0033750413
-
-
(a) Ittel, S. D.; Johnson, L. K.; Brookhart, M. Chem. Rev. 2000, 700, 1169-1203.
-
(2000)
Chem. Rev
, vol.700
, pp. 1169-1203
-
-
Ittel, S.D.1
Johnson, L.K.2
Brookhart, M.3
-
9
-
-
0034808791
-
-
(b) Tian, J.; Hustad, P. D.; Coates, G. W. J. Am. Chem. Soc. 2001, 123, 5134-5135.
-
(2001)
J. Am. Chem. Soc
, vol.123
, pp. 5134-5135
-
-
Tian, J.1
Hustad, P.D.2
Coates, G.W.3
-
10
-
-
8844261118
-
-
(c) Bollmann, A.; Blann, K.; Dixon, J. T.; Hess, F. M.; Killian, E.; Maumela, H.; McGuinness, D. S.; Morgan, D. H.; Neveling, A.; Otto, S.; Overett, M.; Slawin, A. M. Z.; Wasserscheid, P.; Kuhlmann, S. J. Am. Chem. Soc. 2004, 126, 14712-14713.
-
(2004)
J. Am. Chem. Soc
, vol.126
, pp. 14712-14713
-
-
Bollmann, A.1
Blann, K.2
Dixon, J.T.3
Hess, F.M.4
Killian, E.5
Maumela, H.6
McGuinness, D.S.7
Morgan, D.H.8
Neveling, A.9
Otto, S.10
Overett, M.11
Slawin, A.M.Z.12
Wasserscheid, P.13
Kuhlmann, S.14
-
11
-
-
33746238079
-
-
(d) Boussie, T. R.; Diamond, G. M.; Goh, C.; Hall, K. A.; LaPointe, A. M.; Leclerc, M. K.; Murphy, V.; Shoemaker, J. A. W.; Turner, H.; Rosen, R. K.; Stevens, J. C.; Alfano, F.; Busico, V.; Cipullo, R.; Talarico, G. Angew. Chem., Int. Ed. 2006, 45, 3278-3283.
-
(2006)
Angew. Chem., Int. Ed
, vol.45
, pp. 3278-3283
-
-
Boussie, T.R.1
Diamond, G.M.2
Goh, C.3
Hall, K.A.4
LaPointe, A.M.5
Leclerc, M.K.6
Murphy, V.7
Shoemaker, J.A.W.8
Turner, H.9
Rosen, R.K.10
Stevens, J.C.11
Alfano, F.12
Busico, V.13
Cipullo, R.14
Talarico, G.15
-
12
-
-
33646444730
-
-
Arriola, D. J.; Carnahan, E. M.; Hustad, P. D.; Kuhlman, R. L.; Wenzel, T. T. Science 2006, 312, 714-719.
-
(2006)
Science
, vol.312
, pp. 714-719
-
-
Arriola, D.J.1
Carnahan, E.M.2
Hustad, P.D.3
Kuhlman, R.L.4
Wenzel, T.T.5
-
13
-
-
41549128231
-
-
(a) Murray, R. E.; George, V. M.; Nowlin, D. L.; Schultz, C. C.; Petersen, J. L. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 2002, 43, 294-295.
-
(2002)
Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.)
, vol.43
, pp. 294-295
-
-
Murray, R.E.1
George, V.M.2
Nowlin, D.L.3
Schultz, C.C.4
Petersen, J.L.5
-
14
-
-
34547726591
-
-
U.S. Patent 6,103,657 Union Carbide Corp, 2000
-
(b) Murray, R. E. U.S. Patent 6,103,657 (Union Carbide Corp.), 2000.
-
-
-
Murray, R.E.1
-
15
-
-
0000515038
-
-
(a) Woodman, P. R.; Alcock, N. W.; Munslow, I. J.; Sanders, C. J.; Scott, P. Dalton Trans. 2000, 3340-3346.
-
(2000)
Dalton Trans
, pp. 3340-3346
-
-
Woodman, P.R.1
Alcock, N.W.2
Munslow, I.J.3
Sanders, C.J.4
Scott, P.5
-
16
-
-
0141828307
-
-
(b) Knight, P. D.; O'Shaughnessy, P. N.; Munslow, I. J.; Kimberley, B. S.; Scott, P. J. Organomet. Chem. 2003, 683, 103-113.
-
(2003)
J. Organomet. Chem
, vol.683
, pp. 103-113
-
-
Knight, P.D.1
O'Shaughnessy, P.N.2
Munslow, I.J.3
Kimberley, B.S.4
Scott, P.5
-
17
-
-
0242720546
-
-
(c) Tsurugi, H.; Yamagata, T.; Tani, K.; Mashima, K. Chem. Lett. 2003, 32, 756-757.
-
(2003)
Chem. Lett
, vol.32
, pp. 756-757
-
-
Tsurugi, H.1
Yamagata, T.2
Tani, K.3
Mashima, K.4
-
18
-
-
2942534435
-
-
(d) Tsurugi, H.; Matsuo, Y.; Yamagata, T.; Mashima, K. Organometallics 2004, 23, 2797-2805.
-
(2004)
Organometallics
, vol.23
, pp. 2797-2805
-
-
Tsurugi, H.1
Matsuo, Y.2
Yamagata, T.3
Mashima, K.4
-
19
-
-
0242720546
-
-
(a) Tsurugi, H.; Yamagata, T.; Tani, K.; Mashima, K. Chem. Lett. 2003, 32, 756-757.
-
(2003)
Chem. Lett
, vol.32
, pp. 756-757
-
-
Tsurugi, H.1
Yamagata, T.2
Tani, K.3
Mashima, K.4
-
20
-
-
2942534435
-
-
(b) Tsurugi, H.; Matsuo, Y.; Yamagata, T.; Mashima, K. Organometallics 2004, 23, 2797-2805.
-
(2004)
Organometallics
, vol.23
, pp. 2797-2805
-
-
Tsurugi, H.1
Matsuo, Y.2
Yamagata, T.3
Mashima, K.4
-
21
-
-
0000864456
-
-
This insertion chemistry is reminiscent of metal, alkyl insertion into the C=N bond of carbodiimides to produce transition-metal amidinate complexes: Sita, L. R, Babcock, J. R. Organometallics 1998, 17, 5228-5230 and references therein
-
This insertion chemistry is reminiscent of metal - alkyl insertion into the C=N bond of carbodiimides to produce transition-metal amidinate complexes: Sita, L. R.; Babcock, J. R. Organometallics 1998, 17, 5228-5230 and references therein.
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-
-
-
22
-
-
0001364686
-
-
Reactions between bis-imines and main-group alkyl species (Zn, Mg, Al) are well-known: (a) Klerks, J. M.; Stufkens, D. J.; van Koten, G.; Vrieze, K. J. Organomet. Chem. 1979, 181, 271-283.
-
Reactions between bis-imines and main-group alkyl species (Zn, Mg, Al) are well-known: (a) Klerks, J. M.; Stufkens, D. J.; van Koten, G.; Vrieze, K. J. Organomet. Chem. 1979, 181, 271-283.
-
-
-
-
23
-
-
0005972014
-
-
(b) Jastrzebski, J. T. B. H.; Klerks, J. M.; van Koten, G.; Vrieze, K. J. Organomet. Chem. 1981, 210, C49-C53.
-
(1981)
J. Organomet. Chem
, vol.210
-
-
Jastrzebski, J.T.B.H.1
Klerks, J.M.2
van Koten, G.3
Vrieze, K.4
-
24
-
-
0000981079
-
-
(c) Kaupp, M.; Stoll, H.; Preuss, H.; Kaim, W.; Stahl, T.; van Koten, G.; Wissing, E.; Smeets, W. J. J.; Spek, A. L. J. Am. Chem. Soc. 1991, 113, 5606-5618.
-
(1991)
J. Am. Chem. Soc
, vol.113
, pp. 5606-5618
-
-
Kaupp, M.1
Stoll, H.2
Preuss, H.3
Kaim, W.4
Stahl, T.5
van Koten, G.6
Wissing, E.7
Smeets, W.J.J.8
Spek, A.L.9
-
25
-
-
0002341159
-
-
(d) Wissing, E.; Jastrzebski, J. B. H.; Boersma, J.; van Koten, G. J. Organomet. Chem. 1993, 459, 11-16.
-
(1993)
J. Organomet. Chem
, vol.459
, pp. 11-16
-
-
Wissing, E.1
Jastrzebski, J.B.H.2
Boersma, J.3
van Koten, G.4
-
26
-
-
0002911473
-
-
(e) Wissing, E.; van Gorp, K.; Boersma, J.; van Koten, G. Inorg. Chim. Acta 1994, 220, 55-61.
-
(1994)
Inorg. Chim. Acta
, vol.220
, pp. 55-61
-
-
Wissing, E.1
van Gorp, K.2
Boersma, J.3
van Koten, G.4
-
27
-
-
0032556394
-
-
(f) Bruce, M.; Gibson, V. C.; Redshaw, C.; Solan, G. A.; White, A. J. P.; Williams, D. J. Chem. Commun. 1998, 2523-2524.
-
(1998)
Chem. Commun
, pp. 2523-2524
-
-
Bruce, M.1
Gibson, V.C.2
Redshaw, C.3
Solan, G.A.4
White, A.J.P.5
Williams, D.J.6
-
28
-
-
0037119322
-
-
There is only one example of a reaction between transition-metal alkyl complexes and bis-imines: Riollet, V.; Coperet, C.; Basset, J.-M.; Rousset, L.; Bouchu, D.; Grosvalet, L.; Perrin, M. Angew. Chem., Int. Ed. 2002, 41, 3025-3027.
-
There is only one example of a reaction between transition-metal alkyl complexes and bis-imines: Riollet, V.; Coperet, C.; Basset, J.-M.; Rousset, L.; Bouchu, D.; Grosvalet, L.; Perrin, M. Angew. Chem., Int. Ed. 2002, 41, 3025-3027.
-
-
-
-
29
-
-
6544241298
-
-
Johnson, L. K.; Killian, C. M.; Brookhart, M. J. Am. Chem. Soc. 1995, 117, 6414-6415.
-
(1995)
Am. Chem. Soc
, vol.117
, pp. 6414-6415
-
-
Johnson, L.K.1
Killian, C.M.2
Brookhart, M.J.3
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30
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84858107111
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Preparation of 5. To a 40 mL vial was added 2.00 g (3.68 mmol) of Hf(CH2Ph)4 and 1.49 g (3.68 mmol) of N,N′-bis(2,6- diisopropylphenyl)-2,3-butanediimine followed by 8 mL of toluene to dissolve all reagents. The solution was stirred for 42 h at ambient temperature, yielding a dark orange solution. The solvent amount was reduced under reduced pressure to 4 mL. During solvent removal a yellow solid appeared. Hexane (25 mL) was added to this suspension to induce further precipitation. After the mixture was stirred for 10 min, the solid was collected on a frit, washed with 20 mL of hexanes, and dried under reduced pressure to give 2.55 g of product. The filtrate was stored overnight at -30 °C, causing the precipitation of additional solid. Upon workup (as above) a second crop of 0.3 g was isolated. Combined yield: 2.85 g, 82, 1H NMR (C6D6, 300 Hz, 23 °C, δ 7.29 dd, IH, 3JH-H, 7.8 Hz, 4
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2: C, 70.98; H, 7.23; N, 2.96. Found: C, 70.50; H, 7.14; N, 2.84.
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31
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84858091503
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2-N,N′,π).
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2-N,N′,π).
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32
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0000259894
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Scholz, J.; Hadi, G. A.; Thiele, K.-H.; Gorls, H.; Weimann, R.; Schumann, H.; Sieler, J. J. Organomet. Chem. 2001, 626, 243-259.
-
(2001)
J. Organomet. Chem
, vol.626
, pp. 243-259
-
-
Scholz, J.1
Hadi, G.A.2
Thiele, K.-H.3
Gorls, H.4
Weimann, R.5
Schumann, H.6
Sieler, J.7
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33
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34547795632
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See the Supporting Information for details
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See the Supporting Information for details.
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34
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Horton, A. D.; de With, J.; van der Linden, A. J.; van de Weg, H. Organometallics 1996, 15, 2672-2674.
-
(1996)
Organometallics
, vol.15
, pp. 2672-2674
-
-
Horton, A.D.1
de With, J.2
van der Linden, A.J.3
van de Weg, H.4
-
35
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0344206466
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For examples of a metal-bound PhCH2-B(C6F 5)3 anion, see: (a) Horton, A. D, de With, J. Organometallics 1997, 16, 5424-5436
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3 anion, see: (a) Horton, A. D.; de With, J. Organometallics 1997, 16, 5424-5436.
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36
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0000688216
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(b) Thorn, M. G.; Etheridge, Z. C.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1998, 17, 3636-3638.
-
(1998)
Organometallics
, vol.17
, pp. 3636-3638
-
-
Thorn, M.G.1
Etheridge, Z.C.2
Fanwick, P.E.3
Rothwell, I.P.4
-
37
-
-
33751507212
-
-
(c) Pindado, G. J.; Thornton-Pett, M.; Hursthouse, M. B.; Coles, S. J.; Bochmann, M. J. Chem. Soc., Dalton Trans. 1999, 1663-1668.
-
(1999)
J. Chem. Soc., Dalton Trans
, pp. 1663-1668
-
-
Pindado, G.J.1
Thornton-Pett, M.2
Hursthouse, M.B.3
Coles, S.J.4
Bochmann, M.5
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39
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0000263666
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For examples of a metal-unbound PhCH2-B(C6F 5)3 anion, see: (e) Pellecchia, C, Immirzi, A, Pappalardo, D, Peluso, A. Organometallics 1994, 13, 3773-3775
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3 anion, see: (e) Pellecchia, C.; Immirzi, A.; Pappalardo, D.; Peluso, A. Organometallics 1994, 13, 3773-3775.
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40
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34547807015
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Reference 17c
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(f) Reference 17c.
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41
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31544445229
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(g) Axenov, K. V.; Kilpelainen, I.; Klinga, M.; Leskela, M.; Repo, T. Organometallics 2006, 25, 463-471.
-
(2006)
Organometallics
, vol.25
, pp. 463-471
-
-
Axenov, K.V.1
Kilpelainen, I.2
Klinga, M.3
Leskela, M.4
Repo, T.5
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42
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34547771506
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Some of this work has appeared in the patent literature: Murray, R. E. U.S. Patent 6,096,676 Union Carbide Corp, 2000
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Some of this work has appeared in the patent literature: Murray, R. E. U.S. Patent 6,096,676 (Union Carbide Corp.), 2000.
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