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Volumn 129, Issue 31, 2007, Pages 9622-9630

Excited state intervalence transfer in a rigid polymeric film

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE TRANSFER; LIGANDS; PHOTOCHEMICAL REACTIONS; SALTS;

EID: 34547807280     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja068074j     Document Type: Article
Times cited : (22)

References (101)
  • 6
    • 0022786147 scopus 로고    scopus 로고
    • (f.) Meyer, T. J. Pure Appl. Chem. 1986, 58, 1193.
    • (f.) Meyer, T. J. Pure Appl. Chem. 1986, 58, 1193.
  • 47
    • 34547772357 scopus 로고    scopus 로고
    • 15 A full analysis of the kinetic coupling mechanism requires temperature-dependent lifetime data and is outside the scope of this study.
    • 15 A full analysis of the kinetic coupling mechanism requires temperature-dependent lifetime data and is outside the scope of this study.
  • 56
    • 34547736201 scopus 로고    scopus 로고
    • Due to a lack of an appropriate actinometer in the NIR (i.e, one that can be excited with visible light near 500 nm that gives rise to a predictable spectral signature near 1500 nm, an estimation of the extinction coefficient for IT bands was calculated according to the method described in ref 18. The concentration of excited molecules at the excitation wavelength of 510 nm was calculated from the absorbance of the, bpy)2(Cl)Ru II(pz)RuII(Cl)(bpy)2]2+ MLCT band in PMMA (1.15 abs units) and the extinction coefficient for, bpy) 2(Cl)RuII(pz)RuII(Cl)(bpy)2] 2+ in acetonitrile, ∈510nm=2.6 × 104 M-1 cm-1 Powers, M. J, Meyer, T. J. J. Am. Chem. Soc. 1980, 102, 1289, The absorbance at 6880 cm-1 was measured 30 ns after the laser flash. Based on the time-resolved emission traces, the loss of t
    • -1. This is a lower limit since it assumes that the excited state observed is formed with unit efficiency. A less than unit efficiency would increase the extinction coefficient.
  • 64
    • 34547757630 scopus 로고
    • Ph.D. Dissertation, University of North Carolina at Chapel Hill, Chapel Hill, NC
    • Neyhart, G. A. Ph.D. Dissertation, University of North Carolina at Chapel Hill, Chapel Hill, NC, 1988.
    • (1988)
    • Neyhart, G.A.1
  • 66
    • 34547742817 scopus 로고    scopus 로고
    • Kober, E. M. Ph.D. Dissertation, University of North Carolina at Chapel Hill, Chapel Hill, NC, 1982.
    • (b) Kober, E. M. Ph.D. Dissertation, University of North Carolina at Chapel Hill, Chapel Hill, NC, 1982.
  • 83
    • 34547739773 scopus 로고    scopus 로고
    • s = 3.6.
    • s = 3.6.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.