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Due to a lack of an appropriate actinometer in the NIR (i.e, one that can be excited with visible light near 500 nm that gives rise to a predictable spectral signature near 1500 nm, an estimation of the extinction coefficient for IT bands was calculated according to the method described in ref 18. The concentration of excited molecules at the excitation wavelength of 510 nm was calculated from the absorbance of the, bpy)2(Cl)Ru II(pz)RuII(Cl)(bpy)2]2+ MLCT band in PMMA (1.15 abs units) and the extinction coefficient for, bpy) 2(Cl)RuII(pz)RuII(Cl)(bpy)2] 2+ in acetonitrile, ∈510nm=2.6 × 104 M-1 cm-1 Powers, M. J, Meyer, T. J. J. Am. Chem. Soc. 1980, 102, 1289, The absorbance at 6880 cm-1 was measured 30 ns after the laser flash. Based on the time-resolved emission traces, the loss of t
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