Application of time-resolved near-infrared spectroscopy (TRNIR) to the metal-to-ligand charge transfer (MLCT) excited state(s) of Os (phen)32 +

Chemical Physics

Volumn 326, Issue 1, 2006, Pages 71-78

  Dattelbaum, Dana M ^a,b   Kober, Edward M ^a,b   Papanikolas, John M ^a,b   Meyer, Thomas J ^a,b  

^a University of North Carolina at Chapel Hill   (United States)

^b LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

Electronic structure; Ligand ligand charge transfer; Metal to ligand charge transfer; Mixed valence; Transient near infrared

Indexed keywords

EID: 33745512150     PISSN: 03010104     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemphys.2006.02.033     Document Type: Article

References (57)

1. Treadway J.A., Strouse G.F., Anderson P.A., Keene R.F., and Meyer T.J. J. Chem. Soc. Dalton Trans. (2002) 3820
2. Kalyanasundaram K. Chemistry of Polypyridine and Porphyrin Complexes (1992), Academic Press, London
3. Balzani V., Barigelletti F., Campagna S., Belser P., and von Zelewsky A. Coord. Chem. Rev. 84 (1988) 85
4. Kober E.M., and Meyer T.J. Inorg. Chem. 23 (1984) 3877
5. Dallinger R.F., and Woodruff W.H. J. Am. Chem. Soc. 101 (1979) 4391
6. Omberg K.M., Schoonover J.R., Treadway J.A., Leasure R.M., Dyer R.B., and Meyer T.J. J. Am. Chem. Soc. 119 (1997) 7013
7. Cooley L.F., Bergquist P., and Kelley D.F. J. Am. Chem. Soc. 112 (1990) 2612
8. Malone R.A., and Kelley D.F. J. Chem. Phys. 95 (1991) 8970
9. Pogge J.L., and Kelley D.F. Chem. Phys. Lett. 238 (1995) 16
10. Cushing J.P., Butoi C., and Kelley D.F. J. Phys. Chem. A. 101 (1997) 7222
11. Shaw G.B., Brown C.L., and Papanikolas J.M. J. Phys. Chem. A. 106 (2002) 1483
12. Riesen H., Wallace L., and Krausz E. J. Chem. Phys. 102 (1995) 4823
13. Riesen H., Wallace L., and Krausz E. International Rev. Phys. Chem. 16 (1997) 291
14. Heath G.A., Yellowlees L.J., and Braterman P.S. Chem. Phys. Lett. 92 (1982) 646
15. Elliot C.M. J. Chem. Soc. Chem. Commun. (1980) 261
16. Heath G.A., Yellowlees L.J., and Braterman P.S. J. Chem. Soc. Chem. Commun. (1981) 287
17. Demadis K.D., Hartshorn C.M., and Meyer T.J. Chem. Rev. 101 (2001) 2655
18. Brunschwig B.S., Creutz C., and Sutin N. Chem. Soc. Rev. 31 (2002) 168
19. Hush N.S. Electrochim. Acta 13 (1968) 1005
20. Hush N.S. Prog. Inorg. Chem. 8 (1967) 391
21. Reimers J.R., and Hush N.S. Chem. Phys. 208 (1996) 177
22. Reimers J.R., and Hush N.S. J. Am. Chem. Soc. 117 (1995) 1302
23. Hush N.S. NATO Adv. Study Inst., Ser. C 58 (1980) 151
24. Piepho S.B., Krausz E.R., and Schatz P.N. J. Am. Chem. Soc. 100 (1978) 2996
25. Wong K.Y., and Schatz P.N. Prog. Inorg. Chem. 28 (1981) 369
26. Dattelbaum D.M., Hartshorn C.M., and Meyer T.J. J. Am. Chem. Soc. 123 (2002) 4938
27. J.V. Caspar, Ph.D. Dissertation, The University of North Carolina at Chapel Hill, Chapel Hill, NC, 1982.
28. D.M. Dattelbaum, K.D. Demadis, T.J. Meyer, P.S. White, in preparation.
29. -1. There is no electronic absorption feature in the ground state in this region. ΔOD was estimated by extrapolating the exponential ΔOD vs. time decay curve to time = 0 from a first observation time at t = 30 ns. The lifetime of the transient was 160 ns.
30. Emission lifetime measurements were made by using an apparatus described earlier in:. Trammell S.A., et al. J. Phys. Chem. B. 105 (2001) 8895
31. Kober E.M., and Meyer T.J. Inorg. Chem. 21 (1982) 3967
32. Kober E.M., and Meyer T.J. Inorg. Chem. 22 (1983) 1614
33. Crosby G.A. J. Chem. Ed. 60 (1983) 791
34. Danielson E., Lumpkin R.S., and Meyer T.J. J. Phys. Chem. 91 (1987) 1305
35. Kober E.M., Caspar J.V., Lumpkin R.S., and Meyer T.J. J. Phys. Chem. 90 (1986) 3722
36. E.M. Kober, Ph.D. Dissertation, The University of North Carolina at Chapel Hill, Chapel Hill, NC, 1982.
37. Huynh M.H.V., Dattelbaum D.M., and Meyer T.J. Coord. Chem. Rev. 249 (2005) 457
38. Sutin N. Prog. Inorg. Chem. 30 (1983) 441
39. Brunschwig B.S., and Sutin N. Coord. Chem. Rev. 187 (1999) 233
40. Sutin N. Adv. Chem. Phys. 106 (1999) 7
41. Chen P., and Meyer T.J. Chem. Rev. 98 (1998) 1439
42. Sutin N. Acc. Chem. Res. 15 (1982) 275
43. Turro C., Chung Y.C., Leventis N., Kuchenmeister M.E., Wagner P.J., and Leroi G.E. Inorg. Chem. 35 (1996) 5104
44. Omberg K.M., Schoonover J.R., Bernhard S., Moss J.A., Treadway J.A., Kober E.M., Dyer R.B., and Meyer T.J. Inorg. Chem. 37 (1998) 3503
45. Thompson D.G., Schoonover J.R., Timpson C.J., and Meyer T.J. J. Phys. Chem. A 107 (2003) 10250
46. Freed K.F., and Jortner J. J. Chem. Phys. 52 (1970) 6272
47. Bixon M., Jortner J., Cortes J., Heitele H., and Michel-Beyerle M.E. J. Phys. Chem. 98 (1994) 7289
48. Bixon M., and Jortner J. J. Chem. Phys. 48 (1968) 715
49. Englman R., and Jortner J. J. Mol. Phys. 18 (1970) 145
50. Robinson G.W., and Frosch R.P. J. Chem. Phys. 38 (1968) 1187
51. Freed K.F. Top. Curr. Chem. 31 (1972) 65
52. i (1) "transition". With two equivalent phen acceptor ligands, there are a total of 18 state-to-state components in LLCT(1) alone. For an overlapping manifold of three LLCT transitions there would be a total of 54 components!
53. Levine I.N. Molecular Spectroscopy (1975), Wiley, New York
54. Strickler S.J., and Berg R.A. J. Chem. Phys. 37 (1962) 814
55. Demadis K.D., El-Samanody E.-S., Coia G.M., and Meyer T.J. J. Am. Chem. Soc. 121 (1999) 535
56. Demadis K.D., Meyer T.J., and White P.S. Inorg. Chem. 37 (1998) 3610
57. Demadis K.D., Hartshorn C.M., and Meyer T.J. Chem. Rev. 101 (2001) 2655