Mesostructures and properties of transparent block copolymer/silica nanocomposite monoliths

Composite Interfaces

Volumn 14, Issue 5-6, 2007, Pages 545-557

  Jung, Youn Won ^a   Park, Sung Soo ^a   Kim, Youngkyoo ^b   Ha, Chang Sik ^a  

^a Pusan National University   (South Korea)

^b Kyungpook National University   (South Korea)

Author keywords

Block copolymer; Mesoporous materials; Rheology; Silica; Small angle x ray scattering (SAXS); Thermal properties

Indexed keywords

BLOCK COPOLYMERS; CALCINATION; MESOPOROUS MATERIALS; MICELLIZATION; RHEOLOGY; SILICA; SOL-GEL PROCESS; THERMODYNAMIC PROPERTIES; TRANSMISSION ELECTRON MICROSCOPY; X RAY SCATTERING;

DISORDERED STRUCTURES; HEXAGONALLY STRUCTURED MONOLITHS; MESOSTRUCTURES;

NANOCOMPOSITES;

EID: 34547495260     PISSN: 09276440     EISSN: 15685543     Source Type: Journal    
DOI: 10.1163/156855407781291245     Document Type: Article

References (40)

1. N. A. Melosh, P. Lipic, F. A. Bates, F. Wudl, G. D. Stucky and B. F. Chmelka, Molecular and mesoscopic structures of transparent block copolymer-silica monoliths, Macromolecules 32, 4332-4342 (1999).
2. H. J. Kim, H. S. Kim and Y. K. Kwon, Synthesis of an amphiphilic- conjugated triblock copolymer of poly(9,9-didodecylfluorene-2,7-diyl) and poly(hydroxyethyl methacrylate), Macromol. Res. 13, 529-532 (2005).
3. F. Schüth, Superstructures of mesoporous silicas, Curr. Opin. Colloid Interface Sci. 3, 174-180 (1998).
4. D. Shao, P. Yang, Q. Huo, B. F. Chmelka and G. D. Stucky, Topological construction of mesoporous materials, Curr. Opin. Solid State Mater. Sci. 3, 111-121 (1998).
5. A. Firouzi, D. Kumar, L. M. Bull, T. Besier, P. Sieger, Q. Huo, S. A. Walker, J. A. Zasadzinski, C. Glinka, J. Nicol, D. Margolese, G. K. Stucky and B. F. Chmelka, Cooperative organization of inorganic-surfactant and biomimetic assemblies, Science 267, 1138-1143 (1995).
6. Q. Huo, D. I. Margolese, U. Ciesla, P. Feng, T. E. Gier, P. Sieger, R. Leon, P. M. Petroff, F. Schüth and G. D. Stucky, Generalized synthesis of periodic surfactant/inorganic composite materials, Nature 368, 317-321(1994).
7. G. J. Kim, H. S. Kim, Y. S. Ko and Y. K. Kwon, Synthesis and characterization of co-surfactant templated mesoporous materials with enhanced hydrothermal stability, Macromol. Res. 13, 499-505 (2005).
8. Y. Lu, R. Gangull, C. A. Drewien, M. T. Anderson, C. J. Brinker, W Gong, Y. Guo, H. Soyez, B. Dunn, M. H. Huang and J. I. Zink, Continuous formation of supported cubic and hexagonal mesoporous films by sol-gel dip-coating, Nature 389, 364-368 (1997).
9. M. Ogawa, T. Igarashi and K. Kuroda, Preparation of transparent silica-surfactant nanocomposite films with controlled microstructures, Bull. Chem. Soc. Japan 70, 2833-2837 (1997).
10. D. Zhao, P. Yang, N. Melosh, J. Feng, B. F. Chmelka and G. D. Stucky, Continuous mesoporous silica films with highly ordered large pore structures, Adv. Mater. 10, 1380-1385 (1998).
11. S. H. Tolbert, A. Firouzi, G. D. Stucky and B. F. Chmelka, Magnetic field alignment of ordered silicate surfactant composites and mesoporous silica, Science 278, 264-268 (1997).
12. G. S. Attard, J. C. Glyde and C. G. Goltner, Liquid-crystalline phases as templates for the synthesis of mesoporous silica, Nature 378, 366-368 (1995).
13. R. Ryoo, C. H. Ko, S. J. Cho and J. M. Kim, Optically transparent, single-crystal-like oriented mesoporous silica films and plates, J. Phys. Chem. B 101, 10610-10613 (1997).
14. M. E. Raimondi, T. Maschmeyer, R. H. Templer and J. M. Seddon, Synthesis of direct templated aligned mesoporous silica coatings within capillaries, Chem. Commun. 19, 1843-1844 (1997).
15. F. Marlow, M. D. McGehee, D. Zhao, B. F. Chmelka and G. D. Stucky, Doped mesoporous silica fibers: a new laser material, Adv Mater. 11, 632-636 (1999).
16. M. Templin, A. Franck, A. Du Chesne, H. Leist, Y. Zhang, R. Ulrich, V. Schadler and U. Wiesner, Organically modified aluminosilicate mesostructures from block copolymer phases, Science 278, 1795-1798 (1997).
17. D. Zhao, J. Feng, Q. Huo, N. Melosh, G. H. Fredrickson, B. F. Chmelka and G. D. Stucky, Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores, Science 279, 548-552 (1998).
18. C. G. Goltner and M. Antonietti, Mesoporous materials by templating of liquid crystalline phases, Adv. Mater. 9, 431-436 (1997).
19. M. A. Hillmyer, P. M. Lipic, D. A. Hajduk, K. Almdal and F. S. Bates, Self-assembly and polymerization of epoxy resin-amphiphilic block copolymer nanocomposites, J. Am. Chem. Soc. 119, 2749-2750 (1997).
20. P. Yang, D. Zhao, B. F. Chmelka and G. D. Stucky, Triblock-copolymer- directed syntheses of large-pore mesoporous silica fibers, Chem. Mater. 10, 2033-2036 (1998).
21. C. G. Goltner, S.Henke, M. C. Weissenberger and M. Antonietti, Mesoporous silica from lyotropic liquid crystal polymer templates, Angew. Chem. Int. Ed. Engl. 37, 613-616 (1998).
22. N. A. Melosh, P. Davidson, P. Feng, D. J. Pine and B. F. Chmelka, Macroscopic shear alignment of bulk transparent mesostructured silica, J. Amer. Chem. Soc. 123, 1240-1241 (2001).
23. U. Jeng, C. H. Hsu, Y. H. Lai, W. T. Chung, H. S. Shen, H. Y. Lee, Y. F. Song, K. S. Liang and T. L. Liu, Recent SAXS progress at NSRRC, Macromol. Res. 13, 506-513 (2005).
24. F. Kleitz, W. Schmidt and F. Schüth, Calcination behavior of different surfactant-templated mesostructured silica materials, Micropor. Mesopor. Mater. 65, 1-29 (2003).
25. J. Blanchard, P. Trens, M. Hudson, and F. Schuth, Synthesis of hexagonally packed porous titanium oxo-phosphate, Micropor. Mesopor. Mater. 39, 163-170 (2000).
26. D. Y. Ryu, U. Feong, D. H. Lee, J. Kim, H. S. Youn and J. K. Kim, Phase behavior of deuterated polystyrene-block-poly(n-pentyl methaerylate) copolymers, Macromolecules 36, 2894-2902 (2003).
27. D. Y. Ryu, U. Jeong, J. K. Kim and T. P. Russel, Closed-loop phase behavior in block copolymers, Nature Mater. 1, 114-117 (2002).
28. I. W. Hamley (Ed.), The Physics of Block Copolymers, 4th edn, pp. 131. Oxford Science Publications, Oxford, UK (1998).
29. D. Zhao, Q. Huo, J. Feng, B. F. Chmelka and G. D. Stucky, Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures, J. Amer. Chem. Soc. 120, 6024-6036 (1998).
30. P. Alexandridis, U. Olsson and B. Lindman, Structural polymorphism of amphiphilic copolymers: six lyotropic liquid crystalline and two solution phases in a poly(oxybutylene)-b-poly(oxyethylene)-water-xylene system, Langmuir 13, 23-34 (1997).
31. Q. Huo, R. Leon, P. M. Petroff and G. D. Stucky, Mesostructure design with gemini surfactants: supercage formation in a three-dimensional hexagonal array, Science 268, 1324-1327 (1995).
32. H. A. Klok and S. Lecommandous, Supramolecular materials via block copolymer self-assembly, Adv. Mater. 13, 1217-1229 (2001).
33. S. Y. Gu, J. Ren and Q. F. Wang, Rheology of poly(propylene)/clay nanocomposites, J. Appl. Polym. Sci. 91, 2427-2434 (2004).
34. G. Luengo, F. J. Schmitt, R. Hill and J. Israelachvili, Thin film rheology and tribology of confined polymer melts: contrasts with bulk properties, Macromolecules 30, 2482-2494 (1997).
35. Y. Kim, C. S. Ha, T. K. Kang, Y. Kim and W. J. Cho, Rheological properties, tensile properties, and morphology of PP/EPDM/ionomer ternary blends, J. Appl. Polym. Sci. 51, 1453-1461 (1994).
36. Y. H. Hyun, S. T. Lim, H. J. Choi and M. S. Jhon, Rheology of poly(ethylene oxide)/organoclay nanocomposites, Macromolecules 34, 8084-8093 (2001).
37. C. L. Rohn, Analytical Polymer Rheology. Structure Processing Property Relationships, p. 202. Hanser Publishers, Munich (1995).
38. J. K. Mishra, K. J. Hwang and C. S. Ha, Preparation, mechanical and rheological properties of a thermoplastic polyolefin (TPO)/organoclay nanocomposite with reference to the effect of maleic anhydride modified polypropylene as a compatibilizer, Polymer 46, 1995-2002 (2005).
39. R. S. Sinha, K. Okamoto and M. Okamoto, Structure-property relationship in biodegradable poly(butylene succinate)/layered silicate nanocomposites, Macromolecules 36, 2355-2367 (2003).
40. R. S. Sinha, P. Maity, M. Okamoto, K. Yamada and K. Ueda, New polylactide/layered silicate nanocomposites. 1. Preparation, characterization, and properties, Macromolecules 35, 3104-3110 (2002).