Molecular and mesoscopic structures of transparent block copolymer-silica monoliths

Macromolecules

Volumn 32, Issue 13, 1999, Pages 4332-4342

  Melosh, N A ^a   Lipic, P ^c   Bates, F S ^c   Wudl, F ^a,b,d   Stucky, G D ^a,b   Fredrickson, G H ^a   Chmelka, B F ^a  

^a University of California   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c University of Minnesota   (United States)

^d UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

MOLECULAR DYNAMICS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHASE SEPARATION; POLYETHYLENE OXIDES; POLYMERIZATION; POLYPROPYLENE OXIDES; SILICA; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION ANALYSIS;

MICROPHASE SEPARATION; SILICA MONOLITHS;

BLOCK COPOLYMERS;

EID: 0032679432     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9817323     Document Type: Article

References (51)

1. Beck, J. S.; Vartuli, J. C.; Roth, W. J.; Leonowicz, M. E.; Kresge, C. T.; Schmitt, K. D.; Chu, C. T. W.; Olson, D. H.; Sheppard, E. W.; McCullen, S. B.; Higgins, J. B.; Schlanker, J. L. J. Am. Chem. Soc. 1992, 114, 10834.
2. Schüth, F. Curr. Opin. Colloid Interface Sci. 1998, 3, 174.
3. Zhao, D.; Yang, P.; Huo, Q.; Chmelka, B. F.; Stucky, G. D. Curr. Opin. Solid State Mater. Sci. 1998, 3, 111.
4. Firouzi, A.; Kumar, D.; Bull, L. M.; Besier, T.; Sieger, P.; Huo, Q.; Walker, S. A.; Zasadzinski, J. A.; Glinka, C.; Nicol, J.; Margolese, D.; Stucky, G. D.; Chmelka, B. F. Science 1995, 267, 1138.
5. Huo, Q.; Margolese, D. I.; Ciesla, U.; Feng, P.; Gier, T. E.; Sieger, P.; Leon, R.; Petroff, P. M.; Schüth, F.; Stucky, G. D. Nature 1994, 368, 317.
6. Raman, N.; Anderson, M.; Brinker, C. J. Chem. Mater. 1996, 8, 1682.
7. Lu, Y.; Gangull, R.; Drewien, C. A.; Anderson, M. T.; Brinker, C. J.; Gong, W.; Guo, Y.; Soyez, H.; Dunn, B.; Huang, M. H.; Zink, J. I. Nature 1997, 389, 364.
8. Ogawa, M.; Igarashi, T.; Kuroda, K. Bull. Chem. Soc. Jpn. 1997, 70, 2833.
9. Zhao, D.; Yang, P.; Melosh, N.; Feng, J.; Chmelka, B. F.; Stucky, G. D. Adv. Mater. 1998, 10, 1380.
10. Tolbert, S. H.; Firouzi, A.; Stucky, G. D.; Chmelka, B. F. Science 1997, 278, 264.
11. Attard, G. S.; Glyde, J. C.; Göltner, C. G. Nature 1995, 378, 366.
12. Ryoo, R.; Ko, C. H.; Cho, S. J.; Kim, J. M. J. Phys. Chem. B 1997, 101, 10610.
13. Raimondi, M. E.; Maschmeyer, T.; Templer, R. H.; Seddon, J. M. Chem. Commun. 1997, 19, 1843.
14. Marlow, F.; McGehee, M. D.; Zhao, D.; Chmelka, B. F.; Stucky, G. D. Adv. Mater., in press.
15. Templin, M.; Franck, A.; Du Chesne, A.; Leist, H.; Zhang, Y.; Ulrich, R.; Schädler, V.; Wiesner, U. Science 1997, 278, 1795.
16. Zhao, D.; Feng, J.; Huo, Q.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279, 548.
17. Göltner, C. G.; Antonietti, M. Adv. Mater. 1997, 9, 431.
18. Hillmyer, M. A.; Lipic, P. M.; Hajduk, D. A.; Almdal, K.; Bates, F. S. J. Am. Chem. Soc. 1997, 119, 2749.
19. Yang, P.; Zhao, D.; Chmelka, B. F.; Stucky, G. D. Chem. Mater. 1998, 10, 2033.
20. Göltner, C. G.; Henke, S.; Weissenberger, M. C.; Antonietti, M. Angew. Chem., Int. Ed. Engl. 1998, 37, 613.
21. Holmqvist, P.; Alexandridis, P.; Lindman, B. Macromolecules 1997, 30, 6788.
22. Zhao, D.; Huo, Q.; Feng, J.; Chmelka, B. F.; Stucky, G. D. J. Am. Chem. Soc. 1998, 120, 6024.
23. Brinker, C. J.; Scherer, G. W. Sol-Gel Science; Academic Press: San Diego, 1990.
24. Hench, L. L.; West, J. K. Chem. Rev. 1990, 90, 33.
25. Vega, A. J. J. Am. Chem. Soc. 1988, 110, 1049.
26. Fyfe, C. A.; Zhang, Y.; Aroca, P. J. Am. Chem. Soc. 1992, 114, 3252.
27. Janicke, M. T.; Landry, C. C.; Christiansen, S. C.; Kumar, D.; Stucky, G. D.; Chmelka, B. F. J. Am. Chem. Soc. 1998, 120, 6940.
28. Schmidt-Rohr, K.; Spiess, H. W. Multidimensional Solid State NMR and Polymers; Academic Press: New York, 1994; p 478.
29. Schmidt-Rohr, K.; Clauss, J.; Spiess, H. W. Macromolecules 1992, 25, 3273.
30. Maciel, G. E.; Sindorf, D. W. J. Am. Chem. Soc. 1980, 102, 7607.
31. Engelhardt, G.; Michel, D. High-Resolution Solid-State NMR of Silicates and Zeolites; Wiley & Sons: New York, 1987.
32. Komoroski, R. High-Resolution NMR Spectroscopy of Synthetic Polymers in Bulk; VCH Publishers: Deerfield Beach, FL, 1986.
33. Diffuse interfaces produce rounded electron density profiles that require fewer Fourier terms to model, thus reducing the number of higher order peaks observed in the resulting XRD pattern (which can be interpreted as the Fourier transform of the structure.)
34. Melosh, N. A.; Davidson, P.; Chmelka, B. F., manuscript in preparation.
35. Sindorf, D. W.; Maciel, G. E. J. Am. Chem. Soc. 1983, 105, 1487.
36. Zumbulyadis, N.; O'Reilly, J. M. Macromolecules 1991, 24, 5294.
37. Ernst, R. R.; Bodenhausen, G.; Wokaun, A. Principles of Nuclear Magnetic Resonance in One and Two Dimensions; Oxford University Press: New York, 1994.
38. 1/2 ∼ 1.1 nm.
39. Cheng, J.; Fone, M.; Ellsworth, M. W. Solid State NMR 1996, 7, 135.
40. Gentzler, M.; Reimer, J. A. Macromolecules 1997, 30, 8365.
41. Zeigler, R. C.; Maciel, G. E. J. Phys. Chem. 1991, 95, 7345.
42. Johansson, A.; Tegenfeldt, J. Macromolecules 1992, 25, 4712.
43. Schantz, S. Macromolecules 1997, 30, 1419.
44. Stejskal, E. O.; Schaefer, J.; Sefcik, M. D.; McKay, R. A. Macromolecules 1981, 14, 4, 275.
45. Geppi, M.; Harris, R. K.; Kenwright, A. M.; Say, B. J. Solid State NMR 1998, 12, 15.
46. 3 moieties).
47. Alexandridis, P.; Hatton, T. A. Colloids Surf. A 1995, 96, 1.
48. Wanka, G.; Hoffmann, H.; Ulbricht, W. Macromolecules 1994, 27, 4145.
49. Melosh, N. A. Ph.D. dissertation, in preparation.
50. Ryan, A. J.; Fairclough, J. P. A.; Hamley, I. W.; Mai, S.; Booth, C. Macromolecules 1997, 30, 1723.
51. 29Si MAS NMR spectra.