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Volumn 46, Issue 29, 2007, Pages 5541-5544

Supramolecular construction of fluorescent J-aggregates based on hydrogen-bonded perylene dyes

Author keywords

Dyes pigments; J aggregates; Nanostructures; Self assembly; Supramolecular chemistry

Indexed keywords

FLUOROPHORES; HYDROGEN BONDS; LUMINANCE; ORGANIC SOLVENTS; SELF ASSEMBLY; SUPRAMOLECULAR CHEMISTRY;

EID: 34547462512     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200701139     Document Type: Article
Times cited : (434)

References (43)
  • 1
    • 85042671105 scopus 로고
    • a) E.E. Jelley, Nature 1936, 138, 1009-1010;
    • (1936) Nature , vol.138 , pp. 1009-1010
    • Jelley, E.E.1
  • 2
    • 42149112490 scopus 로고
    • b) E. E. Jelley, Nature 1937, 139, 631-632;
    • (1937) Nature , vol.139 , pp. 631-632
    • Jelley, E.E.1
  • 7
    • 0017556290 scopus 로고    scopus 로고
    • A. H. Herz, Adv. Colloid Interface Sci. 1977, 8, 237-298;
    • a) A. H. Herz, Adv. Colloid Interface Sci. 1977, 8, 237-298;
  • 8
  • 9
    • 0003127039 scopus 로고    scopus 로고
    • Ed, T. Kobayashi, World Scientific, Singapore
    • c) H. Kuhn, C Kuhn in J-Aggregates (Ed.: T. Kobayashi), World Scientific, Singapore, 1996, pp. 1-40;
    • (1996) J-Aggregates , pp. 1-40
    • Kuhn, H.1    Kuhn in, C.2
  • 16
    • 1542286016 scopus 로고    scopus 로고
    • Some fluorescent aggregates of perylene bisimides have been reported, but they do not display J-type characteristics, such as small Stokes shifts and narrow emission bands: a D. Liu, S. De Feyter, M. Cotlet, U.-M. Wiesler, T. Weil, A. Herrmann, K. Müllen, F. C. De Schryver, Macromolecules 2003, 36, 8489-8498;
    • Some fluorescent aggregates of perylene bisimides have been reported, but they do not display J-type characteristics, such as small Stokes shifts and narrow emission bands: a) D. Liu, S. De Feyter, M. Cotlet, U.-M. Wiesler, T. Weil, A. Herrmann, K. Müllen, F. C. De Schryver, Macromolecules 2003, 36, 8489-8498;
  • 26
    • 11144297945 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2004, 43, 6350-6355;
    • (2004) Chem. Int. Ed , vol.43 , pp. 6350-6355
    • Angew1
  • 31
    • 34547423308 scopus 로고    scopus 로고
    • The perylene bisimide 1 was characterized by NMR spectroscopy, mass spectrometry, and elemental analysis: m.p. 246-247°C; 1H NMR (CDCl3, 400.13 MHz, 300 K, TMS, δ, 8.31 (s, 2H, NH, 8.17 (s, 4H, Hpery, 7.33 (s, 8H, Haryl, 7.15-7.10 (m, 8H, Haryl, 6.97-6.92 (m, 8H, Haryl, 4.02-3.93 (m, 24H, OCH2, 1.85-1.62 (m, 24H, CH2, 1.55-1.35 (m, 24H, CH 2, 1.35-1.10 (m, 192 H, CH2, 0.84-0.78 ppm (m, 36 H, CH3, MS (MALDI-TOF, positive mode, DCTB, m/z calcd for C220H332N2O28: 3450.46 [M+2H, found: 3450.40; UV/Vis (CH2Cl2, λmax (ε, 570 (41 600, 533 (26 800, 444 nm (19000 M-1 cm-1, fluorescence CH2Cl2, λex, 535 nm, λmax, 602 nm, Φfl= 0.93 ±
    • 2O (3466.46): C 76.17, H 9.65, N 0.81; found: C 76.04, H 9.55, N 0.89.
  • 32
    • 0000409284 scopus 로고    scopus 로고
    • Transition dipole moments were calculated according to a reported method: W. Liptay, R. Wortmann, H. Schaffrin, O. Burkhard, W. Reitinger, N. Detzer, Chem. Phys. 1988, 120, 429-438. The molar extinction coefficient and the transition dipole moment for the aggregate are given as the values per aggregatebound monomelic unit.
    • Transition dipole moments were calculated according to a reported method: W. Liptay, R. Wortmann, H. Schaffrin, O. Burkhard, W. Reitinger, N. Detzer, Chem. Phys. 1988, 120, 429-438. The molar extinction coefficient and the transition dipole moment for the aggregate are given as the values per aggregatebound monomelic unit.
  • 36
    • 34547477744 scopus 로고    scopus 로고
    • For a discussion, see the Supporting Information
    • For a discussion, see the Supporting Information.
  • 37
    • 34547416065 scopus 로고    scopus 로고
    • For further details, see the Supporting Information
    • For further details, see the Supporting Information.
  • 40
    • 0003146848 scopus 로고    scopus 로고
    • Previously reported fluorescence quantum yields for cyaninedye J-aggregates are about 40% at room temperature and 70% at 77 K; see: a I. G. Scheblykin, O. P. Varnavsky, M. M. Bataiev, O. Sliusarenko, M. van der Auweraer, A. G. Vitukhnovsky, Chem. Phys. Lett. 1998, 298, 341-350;
    • Previously reported fluorescence quantum yields for cyaninedye J-aggregates are about 40% at room temperature and 70% at 77 K; see: a) I. G. Scheblykin, O. P. Varnavsky, M. M. Bataiev, O. Sliusarenko, M. van der Auweraer, A. G. Vitukhnovsky, Chem. Phys. Lett. 1998, 298, 341-350;
  • 42
    • 4043098304 scopus 로고    scopus 로고
    • fwhm,agg = √V (G. Busse, B. Frederichs, N. K. Petrov, S. Techert, Phys. Chem. Chem. Phys. 2004, 6, 3309-3314).
    • fwhm,agg = √V (G. Busse, B. Frederichs, N. K. Petrov, S. Techert, Phys. Chem. Chem. Phys. 2004, 6, 3309-3314).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.