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Volumn , Issue 21, 2007, Pages 3480-3487

Domino [2+2]/[2+1] and [3+2]/[2+1] reaction sequences of alkynyl(alkoxy) chromium fischer carbene complexes

Author keywords

Carbenes; Cyclopropanation; Domino reactions; Oxygen heterocycles

Indexed keywords


EID: 34447579164     PISSN: 1434193X     EISSN: 10990690     Source Type: Journal    
DOI: 10.1002/ejoc.200700077     Document Type: Article
Times cited : (8)

References (34)
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    • For a recent review about captodative cyclopropanes, see
    • For a recent review about captodative cyclopropanes, see: H.-U. Reissig, R. Zimmer, Chem. Rev. 2003, 103, 1151-1196.
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    • A competitive pathway was observed, which led to the corresponding benzannulation adduct as an important byproduct: J. Barluenga, F. Aznar, M. A. Palomero, Chem. Eur. J. 2001, 7, 5318-5324.
    • A competitive pathway was observed, which led to the corresponding benzannulation adduct as an important byproduct: J. Barluenga, F. Aznar, M. A. Palomero, Chem. Eur. J. 2001, 7, 5318-5324.
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    • Product 8 that results from the direct cyclopropanation of 2,3-dihydrofuran was also isolated in 8 % yield. (Chemical Equation Presented)
    • Product 8 that results from the direct cyclopropanation of 2,3-dihydrofuran was also isolated in 8 % yield. (Chemical Equation Presented)
  • 27
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    • For the [3+2] cycloaddition between diazocompounds and alkynyl FCCs, see: K. S. Chan, W. D. Wulff, J. Am. Chem. Soc. 1986, 108, 5229-5236.
    • For the [3+2] cycloaddition between diazocompounds and alkynyl FCCs, see: K. S. Chan, W. D. Wulff, J. Am. Chem. Soc. 1986, 108, 5229-5236.
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    • The acetylenes required to prepare FCCs 1c-e,h are commercially available;
    • a) The acetylenes required to prepare FCCs 1c-e,h are commercially available;
  • 33
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    • 4-Ethynyl-2-methoxy-1-methylbenzene, for 1f, was prepared by a six-step procedure (30% yield) from 4-methylacetophenone: C. Rocaboy, E. Aguilar, unpublished results;
    • b) 4-Ethynyl-2-methoxy-1-methylbenzene, for 1f, was prepared by a six-step procedure (30% yield) from 4-methylacetophenone: C. Rocaboy, E. Aguilar, unpublished results;
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    • 5-Ethynyl-1,2,3-trimethoxybenzene, for 1g: N. J. Lawrence, F. A. Ghani, L. A. Hepworth, J. A. Hadfield, A. T. McGown, R. G. Pritchard, Synthesis 1999, 1656-1660.
    • c) 5-Ethynyl-1,2,3-trimethoxybenzene, for 1g: N. J. Lawrence, F. A. Ghani, L. A. Hepworth, J. A. Hadfield, A. T. McGown, R. G. Pritchard, Synthesis 1999, 1656-1660.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.