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33746641275
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Desymmetrization: d) F. Zhang, J. M. Fox, Org. Lett. 2006, 8, 2965-2968.
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33746146011
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Diels-Alder reaction: e J. Qi, W. R. Roush, Org. Lett. 2006, 8, 2795-2798.
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Diels-Alder reaction: e) J. Qi, W. R. Roush, Org. Lett. 2006, 8, 2795-2798.
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0012016624
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Asymmetric aldol: f) D. A. Evans, J. Bartroli, T. L. Shih, J. Am. Chem. Soc. 1981, 103, 2127-2129;
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30144439321
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Alkylation: h) N. Alouane, F. Bernaud, J. Marrot, E. Vrancken, P. Mangeney, Org. Lett. 2005, 7, 5797-5800 .
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9
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33746191442
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Cycloaddition: i S. D. Bull, S. G. Davies, A. C. Garner, D. Kruchinin, M.-S. Key, P. M. Roberts, E. D. Savory, A. D. Smith, J. E. Thompson, Org. Biomol. Chem. 2006, 4, 2945-2964.
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Linezolid (Zyvox) as a representative example: a) S. J. Brickner, Curr. Pharm. Des. 1996, 2, 175-194;
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For the latest reviews on gold catalysis, see: g
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34447551218
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th International Symposium on Chirality, June 25-28, 2006 (abstract due date April 30, 2006), Busan, Korea.
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th International Symposium on Chirality, June 25-28, 2006 (abstract due date April 30, 2006), Busan, Korea.
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29
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I-catalyzed route to 5-methylene-oxazolidin- 2-ones appeared while this manuscript was in preparation: b R. Robles-Machín, J. Adrio, J. C. Carretero, J. Org. Chem. 2006, 71, 5023-5026;
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I-catalyzed route to 5-methylene-oxazolidin- 2-ones appeared while this manuscript was in preparation: b) R. Robles-Machín, J. Adrio, J. C. Carretero, J. Org. Chem. 2006, 71, 5023-5026;
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31
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33644937519
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2 examples
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a) B. M. Trost, J. Jaratjaroonphong, V. Reutrakul, J. Am. Chem. Soc. 2006, 128, 2778-2779 (2 examples);
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34
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For a related one-pot protocol, see: b
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For a related one-pot protocol, see: b) X. Guinchard, Y. Vallée, J.-N. Denis, Org. Lett. 2005, 7, 5147-5150;
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33645801996
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2, 5mol-%) resulted only in partial decomposition after 2 d at room temp., recovering starting 2g in 84% yield. The use of AgOTf (5 mol-%) instead resulted in diminished conversion (22% of 3g for 4 h at room temp.). For examples of the catalytic activity of both gold and protons, see: A. S. K. Hashmi, L. Schwarz, P. Rubenbauer, M. C. Blacko, Adv. Synth. Catal. 2006, 348, 705-708.
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2, 5mol-%) resulted only in partial decomposition after 2 d at room temp., recovering starting 2g in 84% yield. The use of AgOTf (5 mol-%) instead resulted in diminished conversion (22% of 3g for 4 h at room temp.). For examples of the catalytic activity of both gold and protons, see: A. S. K. Hashmi, L. Schwarz, P. Rubenbauer, M. C. Blacko, Adv. Synth. Catal. 2006, 348, 705-708.
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-
-
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38
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34447507049
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The double bond geometry was based on NOE experiments. See Supporting Information
-
The double bond geometry was based on NOE experiments. See Supporting Information.
-
-
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39
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9444284312
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Antioxyauration of alkynes: a A. S. K. Hashmi, J. P. Weyrauch, W. Frey, J. W. Bats, Org. Lett. 2004, 6, 4391-4394.
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Antioxyauration of alkynes: a) A. S. K. Hashmi, J. P. Weyrauch, W. Frey, J. W. Bats, Org. Lett. 2004, 6, 4391-4394.
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-
-
-
40
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0008279550
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In a closely related cyclization of N-carbethoxy N-allyl propargylamine promoted by I2/AgBF4, a similar (Z/E) isomerization was noted, see: b) T. F. Tam, E. Thomas, A. Krantz, Tetrahedron Lett. 1987, 28, 1127-1130
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4, a similar (Z/E) isomerization was noted, see: b) T. F. Tam, E. Thomas, A. Krantz, Tetrahedron Lett. 1987, 28, 1127-1130.
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-
-
-
41
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0033524896
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Isolation: a H. Kakeya, M. Morishita, H. Koshino, T.-L. Morita, K. Kobayashi, H. Osada, J. Org. Chem. 1999, 64, 1052-1053.
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Isolation: a) H. Kakeya, M. Morishita, H. Koshino, T.-L. Morita, K. Kobayashi, H. Osada, J. Org. Chem. 1999, 64, 1052-1053.
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-
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42
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Synthesis: b J. D. Kim, I. S. Kim, C. H. Jin, O. P. Zee, Y. H. Jung, Org. Lett. 2005, 7, 4025-4028 and references cited therein.
-
Synthesis: b) J. D. Kim, I. S. Kim, C. H. Jin, O. P. Zee, Y. H. Jung, Org. Lett. 2005, 7, 4025-4028 and references cited therein.
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-
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43
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33646737239
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For kinetic resolution, see
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