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Volumn 2, Issue 3, 2007, Pages 393-396

Ruthenium-catalyzed sequential reactions: Deracemization of secondary benzylic alcohols

Author keywords

Alcohols; Homogeneous catalysis; Oxidation; Reduction; Ruthenium

Indexed keywords


EID: 34250741030     PISSN: 18614728     EISSN: 1861471X     Source Type: Journal    
DOI: 10.1002/asia.200600354     Document Type: Article
Times cited : (42)

References (69)
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    • [7a] we have developed many enantioselective reactions catalyzed by various transition-metal complexes bearing FOXAP as a chiral ligand: a Y. Nishibayashi, S. Uemura, Synlett 1995, 79;
    • [7a] we have developed many enantioselective reactions catalyzed by various transition-metal complexes bearing FOXAP as a chiral ligand: a) Y. Nishibayashi, S. Uemura, Synlett 1995, 79;
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    • T. Iwata, Y. Miyake, Y. Nishibayashi, S. Uemura, J. Chem. Soc. Perkin Trans. 1 2002, 1548; this optically active phosphine ligand is commercially available from Wako Pure Chemical Industries (Japan) as ipFOXAP (065-04331).
    • g) T. Iwata, Y. Miyake, Y. Nishibayashi, S. Uemura, J. Chem. Soc. Perkin Trans. 1 2002, 1548; this optically active phosphine ligand is commercially available from Wako Pure Chemical Industries (Japan) as ipFOXAP (065-04331).
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    • 5875, the ruthenium complex 2 is commercially available from Strem Chemicals USA
    • b) Y. Nishibayashi, A. Yamauchi, G. Onodera, S. Uemura, J. Org. Chem. 2003, 68, 5875 ; the ruthenium complex 2 is commercially available from Strem Chemicals (USA).
    • (2003) J. Org. Chem , vol.68
    • Nishibayashi, Y.1    Yamauchi, A.2    Onodera, G.3    Uemura, S.4
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    • The combination of achiral ruthenium complex in the first oxidation step and Noyori ruthenium complex for asymmetric hydrogenation in the second reduction step gave only moderate enantioselectivity of secondary benzylic alcohols up to 75, ee, G. R. A. Adair, J. M. J. Williams, Chem. Commun. 2005, 5578
    • The combination of achiral ruthenium complex in the first oxidation step and Noyori ruthenium complex for asymmetric hydrogenation in the second reduction step gave only moderate enantioselectivity of secondary benzylic alcohols (up to 75 % ee): G. R. A. Adair, J. M. J. Williams, Chem. Commun. 2005, 5578.
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    • For recent examples, see: a
    • For recent examples, see: a) O. Pàmies, J.-E. Bäckwall, Chem. Rev. 2003, 103, 3247;
    • (2003) Chem. Rev , vol.103 , pp. 3247
    • Pàmies, O.1    Bäckwall, J.-E.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.