Iridium(I)-catalysed asymmetric hydrosilylation of ketones using a chiral oxazolylferrocene-phosphine hybrid ligand

Chemical Communications

Volumn , Issue 7, 1996, Pages 847-848

  Nishibayashi, Yoshiaki ^a   Segawa, Kyohei ^a   Takada, Hiroya ^a   Ohe, Kouichi ^a   Uemura, Sakae ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000398912     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/cc9960000847     Document Type: Article

References (9)

1. For recent works on rhodium-catalysed asymmetric hydrosilylation of ketones, see H. Nishiyama, M. Kendo, T. Nakamura and K. Itoh, Organometallics, 1991, 10, 500; M. Sawamura, R. Kuwano and Y. Ito, Angew. Chem., Int. Ed. Engl., 1994, 33, 111; T. Hayashi, C. Hayashi and Y. Uozumi, Tetrahedron: Asymmetry, 1995, 6, 2503; Y. Nishibayashi, K. Segawa, J. D. Singh, S. Fukuzawa, K. Ohe and S. Uemura, Organometallics, 1996, 15, 370.
2. For recent works on rhodium-catalysed asymmetric hydrosilylation of ketones, see H. Nishiyama, M. Kendo, T. Nakamura and K. Itoh, Organometallics, 1991, 10, 500; M. Sawamura, R. Kuwano and Y. Ito, Angew. Chem., Int. Ed. Engl., 1994, 33, 111; T. Hayashi, C. Hayashi and Y. Uozumi, Tetrahedron: Asymmetry, 1995, 6, 2503; Y. Nishibayashi, K. Segawa, J. D. Singh, S. Fukuzawa, K. Ohe and S. Uemura, Organometallics, 1996, 15, 370.
3. For recent works on rhodium-catalysed asymmetric hydrosilylation of ketones, see H. Nishiyama, M. Kendo, T. Nakamura and K. Itoh, Organometallics, 1991, 10, 500; M. Sawamura, R. Kuwano and Y. Ito, Angew. Chem., Int. Ed. Engl., 1994, 33, 111; T. Hayashi, C. Hayashi and Y. Uozumi, Tetrahedron: Asymmetry, 1995, 6, 2503; Y. Nishibayashi, K. Segawa, J. D. Singh, S. Fukuzawa, K. Ohe and S. Uemura, Organometallics, 1996, 15, 370.
4. For recent works on rhodium-catalysed asymmetric hydrosilylation of ketones, see H. Nishiyama, M. Kendo, T. Nakamura and K. Itoh, Organometallics, 1991, 10, 500; M. Sawamura, R. Kuwano and Y. Ito, Angew. Chem., Int. Ed. Engl., 1994, 33, 111; T. Hayashi, C. Hayashi and Y. Uozumi, Tetrahedron: Asymmetry, 1995, 6, 2503; Y. Nishibayashi, K. Segawa, J. D. Singh, S. Fukuzawa, K. Ohe and S. Uemura, Organometallics, 1996, 15, 370.
5. I-catalysed hydrosilylation of acetophenone was up to 32% ee; J. W. Faller and K. J. Chase, Organometallics, 1994, 13, 989; A. Kinting, H. J. Kreuzfeld and H. P. Abicht, J. Organomet. Chem., 1989, 370, 343.
6. I-catalysed hydrosilylation of acetophenone was up to 32% ee; J. W. Faller and K. J. Chase, Organometallics, 1994, 13, 989; A. Kinting, H. J. Kreuzfeld and H. P. Abicht, J. Organomet. Chem., 1989, 370, 343.
7. Y. Nishibayashi, K. Segawa, K. Ohe and S. Uemura, Organometallics, 1995, 14, 5486.
8. I-catalysed hydrosilylation of acetylfuran: Y. Goldberg and H. Alper, Tetrahedron: Asymmetry, 1992, 3, 1055.
9. I-catalysed hydrosilylation of acetylfuran: Y. Goldberg and H. Alper, Tetrahedron: Asymmetry, 1992, 3, 1055.