Silicon rehybridization and molecular rearrangements in hypercoordinate silicon dichelates

Pure and Applied Chemistry

Volumn 79, Issue 6, 2007, Pages 1125-1134

  Kost, Daniel ^a   Gostevskii, Boris ^a,b   Kalikhman, Inna ^a  

^a BEN GURION UNIVERSITY OF THE NEGEV   (Israel)

^b A E FAVORSKY IRKUTSK INSTITUTE OF CHEMISTRY   (Russian Federation)

Author keywords

Bicapped tetrahedral; Hexacoordinate; Molecular rearrangement; Pentacoordinate; Rehybridization; Silicon

Indexed keywords

EID: 34250624859     PISSN: 00334545     EISSN: None     Source Type: Journal    
DOI: 10.1351/pac200779061125     Document Type: Conference Paper

References (45)

1. For reviews on hypercoordinate silicon compounds, see: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev. Top. Curr. Chem. 131, 99 (1986);
2. (b) W. S. Sheldrick. In The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (Eds.), pp. 227-303, John Wiley, Chichester (1989);
3. (c) A. R. Bassindale, P. G. Taylor. In The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (Eds.), pp. 839-892, John Wiley, Chichester (1989);
4. (d) R. J. P. Corriu, J. C. Young. In The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (Eds.), pp. 1241-1288, John Wiley, Chichester (1989);
5. (e) R. R. Holmes. Chem. Rev. 90, 17 (1990);
6. (f) C. Chuit, R. J. P. Corriu, C. Reyé, J. C. Young. Chem. Rev. 93, 1371 (1993);
7. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich. J. Organomet. Chem. 446, 1 (1993);
8. (h) J. G. Verkade. Coord. Chem. Rev. 137, 233 (1994);
9. (i) R. Tacke, O. Dannappel. In Tailor-made Silicon-Oxygen Compounds: From Molecules to Materials, R. Corriu, P. Jutzi (Eds.), pp. 75-86, Vieweg, Braunschweig-Wiesbaden (1996);
10. (j) E. Lukevics, O. A. Pudova. Chem. Heterozycl. Compd. (Engl. Transl.) 32, 1381 (1996);
11. (k) R. R. Holmes. Chem. Rev. 96, 927 (1996):
12. (l) D. Kost, I. Kalikhman. In The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (Eds.), pp. 1339-1445, John Wiley, Chichester (1998);
13. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov. In The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (Eds.), pp. 1447-1537, John Wiley, Chichester (1998);
14. (n) C. Chuit, R. J. P. Corriu, C. Reyé. In Chemistry of Hypervalent Compounds, K.-Y. Akiba (Ed.), pp. 81-146, Wiley-VCH, New York (1999);
15. (o) R. Tacke, M. Pülm, B. Wagner. Adv. Organomet. Chem. 44, 221 (1999);
16. (p) M. A. Brook. Silicon in Organic, Organometallic, and Polymer Chemistry, pp. 97-114, John Wiley, New York (2000);
17. (q) R. Tacke, O. Seiler. In Silicon Chemistry: From the Atom to Extended Systems, P. Jutzi, U. Schubert (Eds.), pp. 324-337, Wiley-VCH, Weinheim (2003);
18. (r) D. Kost, I. Kalikhman. Adv. Organomet. Chem. 5, 1 (2004).
19. (a) D. Kummer, S. H. Abdel Halim. Z. Anorg. Allg. Chem. 622, 57 (1996);
20. (b) N. Kano, F. Komatsu, T. Kawashima. J. Am. Chem. Soc. 123, 10778 (2001);
21. (c) J. Wagler, U. Böhme, E. Brendler, G. Roewer. Organometallics 24, 1348 (2005);
22. (d) J. Wagler, U. Böhme, G. Roewer. Angew. Chem., Int. Ed. 41, 1732 (2002);
23. (e) J. Wagler, U. Böhme, E. Brendler, B. Thomas, S. Goutal, H. Mayr, B. Kempf, G. Ya. Remennikov, G. Roewer. Inorg. Chem. Acta 358, 4270 (2005);
24. (f) N. Kano, M. Yamamura, T. Kawashima. J. Am. Chem. Soc. 126, 6250 (2004).
25. (a) D. Kost, V. Kingston, B. Gostevskii, A. Ellern, D. Stalke, B. Walfort, I. Kalikhman. Organometallics 21, 2293 (2002);
26. (b) I. Kalikhman, B. Gostevskii, O. Girshberg, S. Krivonos, D. Kost. Organometallics 21, 2551 (2002);
27. (c) B. Gostevskii, G. Silbert, K. Adear, A. Sivaramakrishna, D. Stalke, S. Deuerlein, N. Kocher, M. G. Voronkov, I. Kalikhman, D. Kost. Organometallics 24, 2913 (2005);
28. (d) B. Gostevskii, K. Adear, A. Sivaramakrishna, G. Silbert, D. Stalke, N. Kocher, I. Kalikhman, D. Kost. Chem. Commun. 1644 (2004);
29. (e) I. Kalikhman, O. Girshberg, L. Lameyer, D. Stalke, D. Kost. J. Am. Chem. Soc. 123, 4709 (2001).
30. D. Kost, B. Gostevskii, N. Kocher, D. Stalke, I. Kalikhman. Angew. Chem., Int. Ed. 42, 1023 (2003).
31. B. Gostevskii, V. Pestunovich, I. Kalikhman, A. Sivaramakrishna, N. Kocher, S. Deuerlein, D. Leusser, D. Stalke, D. Kost. Organometallics 23, 4346 (2004).
32. (a) I. Kalikhman, B. Gostevskii, O. Girshberg, S. Krivonos, D. Kost. Organometallics 21, 2551 (2002);
33. (b) I. Kalikhman, B. Gostevskii, O. Girshberg, A. Sivaramakrishna, N. Kocher, D. Stalke, D. Kost. J. Organomet. Chem. 686, 202 (2003).
34. I. Kalikhman, B. Gostevskii, M. Botoshansky, M. Kaftory, C. A. Tessier, M. J. Panzner, W. J. Youngs, D. Kost. Organometallics 25, 1252 (2006).
35. (a) C. Breliere, F. Carré, R. J. P. Corriu, M. Poirier, G. Royo, J. Zwecker. Organometallics 8, 1831 (1989);
36. (b) F. Carré, G. Cerveau, C. Chuit, R. J. P. Corriu, C. Reyé. New J. Chem. 16, 63 (1992);
37. (c) K. Boyer-Elma, F. Carré, R. J. P. Corriu, W. E. Douglas. J. Chem. Soc., Chem. Commun. 725 (1995);
38. (d) F. Carré, C. Chuit, R. J. P. Corriu, A. Mehdi, C. Reyé. Organometallics 14, 2754 (1995);
39. (e) J. Belzner, D. Schär, R. Herbst-Inner, B. O. Kneisel, M. Noltemeyer. Tetrahedron 54, 8481 (1998);
40. (f) A. A.-E. Ahdab, G. Rima, H. Gornitzka, J. Barrau. J. Organomet. Chem. 636, 96 (2001);
41. (g) H. H. Karsch, B. Deubelly, U. Keller, F. Bienlein, R. Richter, P. Bissinger, M. Heckel, G. Mueller. Chem. Ber. 129, 759 (1996);
42. (h) J. Wagler, M. Schley, D. Gerlach, U. Böhme, E. Brendler, G. Roewer. Z. Naturforsch., B: Chem. Sci. 60, 1054 (2005).
43. (a) R. Probst, C. Leis, S. Gamper, E. Herdtweck, C. Zybill, N. Auner. Angew. Chem., Int. Ed. 30, 1132 (1991);
44. (b) H. Handwerker, C. Leis, R. Probst, P. Bissinger, A. Grohmann. P. Kiprof, E. Herdtweck, J. Blumel, N. Auner, C. Zybill. Organometallics 12, 2162 (1993).
45. B. Gostevskii, I. Kalikhman, C. A. Tessier, M. J. Panzner. W. J. Youngs, D. Kost. Organometallics 24, 5786 (2005).