-
1
-
-
34250165503
-
-
Scheirs, J, Priddy, D. B, Eds, John Wiley & Sons Ltd
-
(a) Cheung, Y. W.; Guest, M. J. In Modern Styrenic Polymers: Polystyrenes and Styrenic Copolymers; Scheirs, J., Priddy, D. B., Eds.; John Wiley & Sons Ltd.: 2003; pp 605-630.
-
(2003)
Modern Styrenic Polymers: Polystyrenes and Styrenic Copolymers
, pp. 605-630
-
-
Cheung, Y.W.1
Guest, M.J.2
-
2
-
-
34250210863
-
-
Scheirs, J, Kaminsky, W, Eds, John Wiley & Sons Ltd
-
(b) Guest, M. J.; Cheung, Y. W.; Diehl, C. F.; Hoenig, S. M. In Metallocene-Based Polyolefins; Scheirs, J., Kaminsky, W., Eds.; John Wiley & Sons Ltd.: 2000; Vol. 2; pp 271-292.
-
(2000)
Metallocene-Based Polyolefins
, vol.2
, pp. 271-292
-
-
Guest, M.J.1
Cheung, Y.W.2
Diehl, C.F.3
Hoenig, S.M.4
-
3
-
-
34250178523
-
-
Eur. Patent 416815, The Dow Chemical Company
-
(a) Stevens, J. C.; Timmers, F. J.; Wilson, D. R.; Schmidt, G. F.; Nickias, P. N.; Rosen, R. K.; Knight, G. W.; Lai, S. Eur. Patent 416815, 1991 (The Dow Chemical Company).
-
(1991)
-
-
Stevens, J.C.1
Timmers, F.J.2
Wilson, D.R.3
Schmidt, G.F.4
Nickias, P.N.5
Rosen, R.K.6
Knight, G.W.7
Lai, S.8
-
4
-
-
34250177375
-
-
U.S. Patent 6,670,432 B1, 2003 The Dow Chemical Company
-
(b) Timmers, F. J. U.S. Patent 6,670,432 B1, 2003 (The Dow Chemical Company).
-
-
-
Timmers, F.J.1
-
5
-
-
34250221581
-
-
3 produced, in addition to ES polymers, substantial amounts of polyethylene and polystyrene homopolymer impurities.
-
3 produced, in addition to ES polymers, substantial amounts of polyethylene and polystyrene homopolymer impurities.
-
-
-
-
7
-
-
0031170235
-
-
(b) Sernetz, F. G.; Mulhaupt, R.; Amor, F.; Eberle, T.; Okuda, J. J. Polym. Sci., Part A: Polym. Chem. 1997, 35, 1571-1578.
-
(1997)
J. Polym. Sci., Part A: Polym. Chem
, vol.35
, pp. 1571-1578
-
-
Sernetz, F.G.1
Mulhaupt, R.2
Amor, F.3
Eberle, T.4
Okuda, J.5
-
8
-
-
34250203678
-
-
U.S. Patent 5,965,756, The Dow Chemical Company
-
(c) McAdon, M. H.; Nickias, P. N.; Patton, J. T.; Shankar, R. B.; Timmers, F. J.; Vanderlende, D. D.; Kolthammer, B. W.; Ueligger, S.; Steven, M. U.S. Patent 5,965,756, 1999, (The Dow Chemical Company).
-
(1999)
-
-
McAdon, M.H.1
Nickias, P.N.2
Patton, J.T.3
Shankar, R.B.4
Timmers, F.J.5
Vanderlende, D.D.6
Kolthammer, B.W.7
Ueligger, S.8
Steven, M.9
-
9
-
-
0032048907
-
-
(d) Xu, G. Macromolecules 1998, 31, 2395-2402.
-
(1998)
Macromolecules
, vol.31
, pp. 2395-2402
-
-
Xu, G.1
-
10
-
-
0032376639
-
-
(e) Arai, T.; Ohtsu, T.; Suzuki, S. Macromol. Rapid Commun. 1998, 19, 327-331.
-
(1998)
Macromol. Rapid Commun
, vol.19
, pp. 327-331
-
-
Arai, T.1
Ohtsu, T.2
Suzuki, S.3
-
11
-
-
0032606715
-
-
(f) Sukhova, T. A.; Panin, A. N.; Babkina, O. N.; Bravaya, N. M. J. Polym. Sci., Part A: Polym. Chem. 1999, 37, 1083-1093.
-
(1999)
J. Polym. Sci., Part A: Polym. Chem
, vol.37
, pp. 1083-1093
-
-
Sukhova, T.A.1
Panin, A.N.2
Babkina, O.N.3
Bravaya, N.M.4
-
13
-
-
0037010852
-
-
(h) Nomura, K.; Okumura, H.; Komatsu, T.; Naga, N.; Imanishi, Y. J. Mol. Catal. A: Chem. 2002, 190, 225-234.
-
(2002)
J. Mol. Catal. A: Chem
, vol.190
, pp. 225-234
-
-
Nomura, K.1
Okumura, H.2
Komatsu, T.3
Naga, N.4
Imanishi, Y.5
-
14
-
-
0037008020
-
-
(i) Nomura, K.; Okumura, H.; Komatsu, T.; Naga. N. Macromolecules 2002, 35, 5388-5395.
-
(2002)
Macromolecules
, vol.35
, pp. 5388-5395
-
-
Nomura, K.1
Okumura, H.2
Komatsu, T.3
Naga, N.4
-
15
-
-
0142247526
-
-
(j) Noh, S. K.; Yang, Y.; Lyoo, W. S. J. Appl. Polym. Sci. 2003, 90, 2469-2474.
-
(2003)
J. Appl. Polym. Sci
, vol.90
, pp. 2469-2474
-
-
Noh, S.K.1
Yang, Y.2
Lyoo, W.S.3
-
16
-
-
34250193789
-
-
(k) Skefil, R.; Sindelaf, P.; Salajka, Z.; Varga, V.; Císařová, I.; Pinkas, J.; Horáček, M.; Mach, K. J. Mol. Catal. A: Chem. 2004, 224, 97-103.
-
(2004)
J. Mol. Catal. A: Chem
, vol.224
, pp. 97-103
-
-
Skefil, R.1
Sindelaf, P.2
Salajka, Z.3
Varga, V.4
Císařová, I.5
Pinkas, J.6
Horáček, M.7
Mach, K.8
-
17
-
-
1642374346
-
-
(l) Noh, S. K.; Lee, M.; Kum, D. H.; Kim, K.; Lyoo, W. S.; Lee. D-H. J. Polym. Sci., Part A: Polym. Chem. 2004, 42, 1712-1723.
-
(2004)
J. Polym. Sci., Part A: Polym. Chem
, vol.42
, pp. 1712-1723
-
-
Noh, S.K.1
Lee, M.2
Kum, D.H.3
Kim, K.4
Lyoo, W.S.5
Lee, D.-H.6
-
18
-
-
3342894898
-
-
(m) Gentil, S.; Pirio, N.; Meunier, P.; Gallou, F.; Paquette, L. A. Eur. Polym. J. 2004, 40, 2241-2246.
-
(2004)
Eur. Polym. J
, vol.40
, pp. 2241-2246
-
-
Gentil, S.1
Pirio, N.2
Meunier, P.3
Gallou, F.4
Paquette, L.A.5
-
19
-
-
2542612839
-
-
(n) Guo, N.; Li, L.; Marks, T. J. J. Am. Chem. Soc. 2004, 126, 6542-6543.
-
(2004)
J. Am. Chem. Soc
, vol.126
, pp. 6542-6543
-
-
Guo, N.1
Li, L.2
Marks, T.J.3
-
20
-
-
13444310870
-
-
(o) Martínez, S.; Exposito, M. T.; Ramos, J.; Cruz, V.; Martínez, M. C.; López, M.; Muñoz-Escalona, A.; Martínez-Salazor. J. J. Polym. Sci., Part A: Polym. Chem. 2005, 43, 711-725.
-
(2005)
J. Polym. Sci., Part A: Polym. Chem
, vol.43
, pp. 711-725
-
-
Martínez, S.1
Exposito, M.T.2
Ramos, J.3
Cruz, V.4
Martínez, M.C.5
López, M.6
Muñoz-Escalona, A.7
Martínez-Salazor, J.8
-
21
-
-
0000863686
-
-
For a review on ethylene-styrene polymerization, see
-
For a review on ethylene-styrene polymerization, see: Pellecchia, C.; Oliva, L. Rubber Chem. Technol. 1999, 72, 553-558.
-
(1999)
Rubber Chem. Technol
, vol.72
, pp. 553-558
-
-
Pellecchia, C.1
Oliva, L.2
-
22
-
-
0000234225
-
-
(a) Longo, P.; Grassi, A.; Oliva, L. Makromol. Chem. 1990, 191, 2387-2396.
-
(1990)
Makromol. Chem
, vol.191
, pp. 2387-2396
-
-
Longo, P.1
Grassi, A.2
Oliva, L.3
-
24
-
-
0000044777
-
-
(c) Pellecchia, C.; Pappalardo, D.; D'Arco, M.; Zambelli, A. Macromolecules 1996, 29, 1158-1162.
-
(1996)
Macromolecules
, vol.29
, pp. 1158-1162
-
-
Pellecchia, C.1
Pappalardo, D.2
D'Arco, M.3
Zambelli, A.4
-
25
-
-
0000079254
-
-
(d) Oliva, L.; Mazza, S.; Longo, P. Macromol. Chem. Phys. 1996, 197, 3115-3122.
-
(1996)
Macromol. Chem. Phys
, vol.197
, pp. 3115-3122
-
-
Oliva, L.1
Mazza, S.2
Longo, P.3
-
27
-
-
0001551383
-
-
(f) Wu, Q.; Ye, Z.; Gao, Q.; Lin, S. Macromol. Chem. Phys. 1998, 199, 1715-1720.
-
(1998)
Macromol. Chem. Phys
, vol.199
, pp. 1715-1720
-
-
Wu, Q.1
Ye, Z.2
Gao, Q.3
Lin, S.4
-
28
-
-
0032098964
-
-
(g) Venditto, V.; De Tullio, G.; Izzo, L.; Oliva, L. Macromolecules 1998, 31, 4027-4029.
-
(1998)
Macromolecules
, vol.31
, pp. 4027-4029
-
-
Venditto, V.1
De Tullio, G.2
Izzo, L.3
Oliva, L.4
-
29
-
-
0033749066
-
-
(h) Pellecchia, C.; Pappalardo, D.; Oliva, L.; Mazzeo, M.; Gruter, G.-J. Macromolecules 2000, 33, 2807-2814.
-
(2000)
Macromolecules
, vol.33
, pp. 2807-2814
-
-
Pellecchia, C.1
Pappalardo, D.2
Oliva, L.3
Mazzeo, M.4
Gruter, G.-J.5
-
30
-
-
3342894898
-
-
(i) Gentil, S.; Pirio, N.; Meunier, P.; Gallou, F.; Paquette. L. A. Eur. Polym. J. 2004, 40, 2241-2246.
-
(2004)
Eur. Polym. J
, vol.40
, pp. 2241-2246
-
-
Gentil, S.1
Pirio, N.2
Meunier, P.3
Gallou, F.4
Paquette, L.A.5
-
31
-
-
4544273858
-
-
(j) Ishiyama, T.; Miyoshi, K.; Nakazawa, H. J. Mol. Catal. A: Chem. 2004, 221, 41-45.
-
(2004)
J. Mol. Catal. A: Chem
, vol.221
, pp. 41-45
-
-
Ishiyama, T.1
Miyoshi, K.2
Nakazawa, H.3
-
32
-
-
27944486996
-
-
(k) Yokota, K.; Kohsaka, T.; Ito, K.; Ishihara. N. J. Polym. Sci. Part A: Polym. Chem. 2005, 43, 5041 -5048.
-
(2005)
J. Polym. Sci. Part A: Polym. Chem
, vol.43
, pp. 5041-5048
-
-
Yokota, K.1
Kohsaka, T.2
Ito, K.3
Ishihara, N.4
-
33
-
-
7444228127
-
-
(l) Luo, Y.; Baldamus, J.; Hou, Z. J. Am. Chem. Soc. 2004, 126, 13910-13911.
-
(2004)
J. Am. Chem. Soc
, vol.126
, pp. 13910-13911
-
-
Luo, Y.1
Baldamus, J.2
Hou, Z.3
-
35
-
-
0029326377
-
-
(a) Oliva, L.; Caporaso, L.: Pellecchia, C.; Zambelli, A. Macromolecules 1995, 28, 4665-4667.
-
(1995)
Macromolecules
, vol.28
, pp. 4665-4667
-
-
Oliva, L.1
Caporaso, L.2
Pellecchia, C.3
Zambelli, A.4
-
36
-
-
0031235310
-
-
(b) Oliva, L.; Longo, P.; Izzo, L.; Di, Serio, M. Macromolecules 1997, 30, 5616-5619.
-
(1997)
Macromolecules
, vol.30
, pp. 5616-5619
-
-
Oliva, L.1
Longo, P.2
Izzo, L.3
-
37
-
-
0032139560
-
-
(c) Arai, T.; Ohlsu, T.; Suzuki, S. Polym. Prepr. (Am. Chem. Soc. Div. Polym. Chem.) 1998, 39, 422.
-
(1998)
Polym. Prepr. (Am. Chem. Soc. Div. Polym. Chem.)
, vol.39
, pp. 422
-
-
Arai, T.1
Ohlsu, T.2
Suzuki, S.3
-
38
-
-
0032302983
-
-
(d) Hou, Z.; Tezuka, H.; Zhang, Y.; Yamazaki, H.; Wakatsuki, Y. Macromolecules 1998, 31, 8650-8652.
-
(1998)
Macromolecules
, vol.31
, pp. 8650-8652
-
-
Hou, Z.1
Tezuka, H.2
Zhang, Y.3
Yamazaki, H.4
Wakatsuki, Y.5
-
39
-
-
0009552645
-
-
(e) Izzo, L.; Oliva, L.; Proto, A.; Trofa, M. Macromol. Chem. Phys. 1999, 200, 1086-1088.
-
(1999)
Macromol. Chem. Phys
, vol.200
, pp. 1086-1088
-
-
Izzo, L.1
Oliva, L.2
Proto, A.3
Trofa, M.4
-
40
-
-
0141718715
-
-
(f) Albers, I.; Kaminsky, W.; Weingarten, U.; Werner, R. Catal. Commun. 2002, 3, 105-112.
-
(2002)
Catal. Commun
, vol.3
, pp. 105-112
-
-
Albers, I.1
Kaminsky, W.2
Weingarten, U.3
Werner, R.4
-
41
-
-
34250207783
-
-
(g) Arai, T.; Hanasato, S.; Nakajima, M.; Ohtsu, T. Polym. Prepr. (Am. Chem. Soc. Div. Polym. Chem.) 2002, 43, 293.
-
(2002)
Polym. Prepr. (Am. Chem. Soc. Div. Polym. Chem.)
, vol.43
, pp. 293
-
-
Arai, T.1
Hanasato, S.2
Nakajima, M.3
Ohtsu, T.4
-
42
-
-
0037130050
-
-
(h) Caporaso, L.; Izzo, L.; Sisti, I.; Oliva, L. Macromolecules 2002, 35, 4866-4870.
-
(2002)
Macromolecules
, vol.35
, pp. 4866-4870
-
-
Caporaso, L.1
Izzo, L.2
Sisti, I.3
Oliva, L.4
-
43
-
-
9244242041
-
-
(i) Exposito, M. T.; Martínez, S.; Ramos, J.; Cruz, V.; Lopez, M.; Muñoz-Escalona, A.; Haider, N.; Martinez-Salazar, J. Polymer 2004, 45, 9029-9038.
-
(2004)
Polymer
, vol.45
, pp. 9029-9038
-
-
Exposito, M.T.1
Martínez, S.2
Ramos, J.3
Cruz, V.4
Lopez, M.5
Muñoz-Escalona, A.6
Haider, N.7
Martinez-Salazar, J.8
-
44
-
-
0000951581
-
-
(a) Fokken, S.; Spaniol, T. P.; Okuda, J.; Sernetz, F. G.; Mulhaupt, R. Organometallics 1997, 16, 4240-4242.
-
(1997)
Organometallics
, vol.16
, pp. 4240-4242
-
-
Fokken, S.1
Spaniol, T.P.2
Okuda, J.3
Sernetz, F.G.4
Mulhaupt, R.5
-
45
-
-
0031095953
-
-
(b) Sernetz, F. G.; Mulhaupt, R.; Fokken, S.; Okuda, J. Macromolecules 1997, 30, 1562-1569.
-
(1997)
Macromolecules
, vol.30
, pp. 1562-1569
-
-
Sernetz, F.G.1
Mulhaupt, R.2
Fokken, S.3
Okuda, J.4
-
46
-
-
0037190730
-
-
(a) Muñoz-Escalona, A.; Cruz, V.; Mena, N.; Martínez, S.; Martinez-Salazar, J. Polymer 2002, 43, 7017-7026.
-
(2002)
Polymer
, vol.43
, pp. 7017-7026
-
-
Muñoz-Escalona, A.1
Cruz, V.2
Mena, N.3
Martínez, S.4
Martinez-Salazar, J.5
-
47
-
-
2242463988
-
-
(b) Martínez, S.; Cruz, V.; Muñoz-Escalona, A.; Martinez-Salazar, J. Polymer 2003, 44, 295-306.
-
(2003)
Polymer
, vol.44
, pp. 295-306
-
-
Martínez, S.1
Cruz, V.2
Muñoz-Escalona, A.3
Martinez-Salazar, J.4
-
48
-
-
0042266258
-
-
(c) Yang, S. H.; Jo, W. H.; Noh, S. K. J. Chem. Phys. 2003, 119, 1824-1837.
-
(2003)
J. Chem. Phys
, vol.119
, pp. 1824-1837
-
-
Yang, S.H.1
Jo, W.H.2
Noh, S.K.3
-
49
-
-
22944436134
-
-
074901/1-079401/4
-
(d) Ramos, J.; Munoz-Escalona, A.; Martinez, S.: Martinez-Salazar, J. J. Chem. Phys. 2005, 122, 074901/1-079401/4.
-
(2005)
J. Chem. Phys
, vol.122
-
-
Ramos, J.1
Munoz-Escalona, A.2
Martinez, S.3
Martinez-Salazar, J.4
-
50
-
-
34250216115
-
-
U.S. Patent 6,150,297, The Dow Chemical Company
-
(a) Campbell, R. E., Jr.; Timmers, F. J.; Shankar, R. B.; Arriola, D. J. U.S. Patent 6,150,297, 2000 (The Dow Chemical Company).
-
(2000)
-
-
Campbell Jr., R.E.1
Timmers, F.J.2
Shankar, R.B.3
Arriola, D.J.4
-
51
-
-
34250181433
-
-
U.S. Patent 6,825,147, The Dow Chemical Company
-
(b) Klosin, J.; Feng, S. S.; Shankar, R. B.; Timmers, F. J. U.S. Patent 6,825,147, 2004 (The Dow Chemical Company).
-
(2004)
-
-
Klosin, J.1
Feng, S.S.2
Shankar, R.B.3
Timmers, F.J.4
-
52
-
-
84972924919
-
-
The convention used for assigning carbon methylene labels such as αβ describes the position relative to the nearest methine carbon in both directions along the polymer chain. Randall, J. C. Rev. Macromol. Chem. Phys. 1989, C29, 201-317
-
The convention used for assigning carbon methylene labels such as αβ describes the position relative to the nearest methine carbon in both directions along the polymer chain. Randall, J. C. Rev. Macromol. Chem. Phys. 1989, C29, 201-317.
-
-
-
-
53
-
-
34250160302
-
-
The substituent effect parameter and corrective terms were taken from ref 11. The values for a phenyl substituent were obtained from: Pretsch, E.; Clerc, T.; Seible, J.; Simon, W. Tables of Spectral Data for Structure Determination of Organic Compounds; Springer-Verlag: 1989.
-
The substituent effect parameter and corrective terms were taken from ref 11. The values for a phenyl substituent were obtained from: Pretsch, E.; Clerc, T.; Seible, J.; Simon, W. Tables of Spectral Data for Structure Determination of Organic Compounds; Springer-Verlag: 1989.
-
-
-
-
54
-
-
34250191923
-
-
A pair of αβ peaks of equal intensity arises from the relative stereochemical arrangement (rac and meso) of the phenyl substituents on either side of αβ methylene units.
-
A pair of αβ peaks of equal intensity arises from the relative stereochemical arrangement (rac and meso) of the phenyl substituents on either side of αβ methylene units.
-
-
-
-
55
-
-
34250183542
-
-
This assumption is not necessary for the kinetic modeling as described herein since the polymers possess reasonably high molecular weights, and end group effects are near zero. This is opposed to low molecular weight oligomers, where chemical shift differences may be observed due to differences in proximity to the end group
-
This assumption is not necessary for the kinetic modeling as described herein since the polymers possess reasonably high molecular weights, and end group effects are near zero. This is opposed to low molecular weight oligomers, where chemical shift differences may be observed due to differences in proximity to the end group.
-
-
-
-
56
-
-
34250206065
-
-
Unpublished results
-
Unpublished results.
-
-
-
-
58
-
-
0001831608
-
-
(b) Zhang, F.; Mu, Y.; Zhao Zhang, L., Y.; Bu, W.; Chen, C.; Zhai, H.; Hong, H. J. Organomet. Chem. 2000, 613, 68-76.
-
(2000)
J. Organomet. Chem
, vol.613
, pp. 68-76
-
-
Zhang, F.1
Mu, Y.2
Zhao Zhang, L.Y.3
Bu, W.4
Chen, C.5
Zhai, H.6
Hong, H.7
-
59
-
-
33947490543
-
-
Corey, E. J.; Uda, Hisashi. J. Am. Chem. Soc. 1963, 85, 1788-1792.
-
(1963)
J. Am. Chem. Soc
, vol.85
, pp. 1788-1792
-
-
Corey, E.J.1
-
60
-
-
34250168405
-
-
See Supporting Information for details
-
See Supporting Information for details.
-
-
-
-
62
-
-
0000607124
-
-
For silatropic shift in cyclopentadienyl derivatives, see
-
For silatropic shift in cyclopentadienyl derivatives, see: Rigby, S. S.; Gupta, H. K.; Werstiuk, N. H.; Bain, A. D.; McGlinchey, M. J. Inorg. Chem. Acta 1996, 251, 355-364.
-
(1996)
Inorg. Chem. Acta
, vol.251
, pp. 355-364
-
-
Rigby, S.S.1
Gupta, H.K.2
Werstiuk, N.H.3
Bain, A.D.4
McGlinchey, M.J.5
-
63
-
-
33947468138
-
-
(a) Cope, A. C.; Field, L.; MacDowell, D. W. H.; Wright, M. E. J. Am. Chem. Soc. 1956, 78, 2547-2551.
-
(1956)
J. Am. Chem. Soc
, vol.78
, pp. 2547-2551
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Cope, A.C.1
Field, L.2
MacDowell, D.W.H.3
Wright, M.E.4
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65
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34250220766
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In theory, silylation could also occur at a quaternary carbon in the Cp. However, due to steric effects this scenario is not very likely
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In theory, silylation could also occur at a quaternary carbon in the Cp. However, due to steric effects this scenario is not very likely.
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66
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0000607124
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Rigby, S. S.; Gupta, H. K.; Werstiuk, N. H.; Bain, A. D.; McGlinchey, M. J. Inorg. Chim. Acta 1996, 251, 355-364.
-
(1996)
Inorg. Chim. Acta
, vol.251
, pp. 355-364
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Rigby, S.S.1
Gupta, H.K.2
Werstiuk, N.H.3
Bain, A.D.4
McGlinchey, M.J.5
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67
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0029344861
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Devore, D. D.; Timmers, F. J.; Hasha, D. L.; Rosen, R. K.; Marks, T. J.; Deck, P. A.; Stem, C. L. Organometallics 1995, 14, 3132-3134.
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(1995)
Organometallics
, vol.14
, pp. 3132-3134
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Devore, D.D.1
Timmers, F.J.2
Hasha, D.L.3
Rosen, R.K.4
Marks, T.J.5
Deck, P.A.6
Stem, C.L.7
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68
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A lower quality structure of 1 has recently been published. Nishii, K.; Ikeda, T.; Akita, M.; Shiono T. J. Mol. Catal. A: Chem. 2005, 231, 241-246.
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A lower quality structure of 1 has recently been published. Nishii, K.; Ikeda, T.; Akita, M.; Shiono T. J. Mol. Catal. A: Chem. 2005, 231, 241-246.
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69
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For other Ti-diphenylbutadiene complexes, see: a
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For other Ti-diphenylbutadiene complexes, see: (a) Spencer, M. D.; Wilson, S. R.; Girolami, G. S. Organometallics 1997, 16, 3055-3067.
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(1997)
Organometallics
, vol.16
, pp. 3055-3067
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Spencer, M.D.1
Wilson, S.R.2
Girolami, G.S.3
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70
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(b) Abboud, K. A.; Nickias, P. N.: Chen, E. Y.-X. Acta Crystallogr., Sect. C 2001, C57, 1408-1409.
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(2001)
Acta Crystallogr., Sect. C
, vol.C57
, pp. 1408-1409
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Abboud, K.A.1
Nickias, P.N.2
Chen, E.Y.-X.3
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71
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0035948489
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Heteroatom Cp and indenyl substitution was shown to exert a considerable electronic effect on the geometry of CGC complexes: (a) Klosin, J, Kruper, W. J, Jr, Nickias, P. N, Roof, G. R, De Waele, P, Abboud, K. A. Organometallics 2001, 20, 2663-2665
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Heteroatom Cp and indenyl substitution was shown to exert a considerable electronic effect on the geometry of CGC complexes: (a) Klosin, J.; Kruper, W. J., Jr.; Nickias, P. N.; Roof, G. R.; De Waele, P.; Abboud, K. A. Organometallics 2001, 20, 2663-2665.
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(b) Grandini, C.; Camurati, I.; Guidotti, S.; Mascellani, N.; Resconi, L.; Nifant'ev, I. E.; Kashulin, I. A.; Ivchenko, P. V.; Mercandelli, P.; Sironi, A. Organometallics 2004, 23, 344-360.
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(2004)
Organometallics
, vol.23
, pp. 344-360
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Grandini, C.1
Camurati, I.2
Guidotti, S.3
Mascellani, N.4
Resconi, L.5
Nifant'ev, I.E.6
Kashulin, I.A.7
Ivchenko, P.V.8
Mercandelli, P.9
Sironi, A.10
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74
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Both 2 and 3 were found to be somewhat less efficient than 1 in ethylene/1-octene polymerization processes. Octene reactivity was found to be comparable for 1 and 2 but much higher for 3 which is consistent with 3 offering a less congested active site. Interestingly, while the molecular weight of ES polymers was found to be the highest for 3 and the lowest for 1, the molecular weight trend is reversed for EO polymerization. See Supporting Information for details.
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Both 2 and 3 were found to be somewhat less efficient than 1 in ethylene/1-octene polymerization processes. Octene reactivity was found to be comparable for 1 and 2 but much higher for 3 which is consistent with 3 offering a less congested active site. Interestingly, while the molecular weight of ES polymers was found to be the highest for 3 and the lowest for 1, the molecular weight trend is reversed for EO polymerization. See Supporting Information for details.
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75
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34250214262
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Catalysts 3a and 3b exhibit comparable ES polymerization performance.
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Catalysts 3a and 3b exhibit comparable ES polymerization performance.
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76
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34250219344
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See Supporting Information for details
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See Supporting Information for details.
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77
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Pangborn, A. B.; Giardello, M. A.; Grubbs, R. H.; Rosen, R. K.; Timmers, F. J. Organometallics 1996, 15, 1518-1520.
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(1996)
Organometallics
, vol.15
, pp. 1518-1520
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Pangborn, A.B.1
Giardello, M.A.2
Grubbs, R.H.3
Rosen, R.K.4
Timmers, F.J.5
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