Titanocene-methylaluminoxane catalysts for copolymerization of styrene and ethylene: Synthesis and characterization of styrene-ethylene copolymers

Macromolecules

Volumn 30, Issue 4, 1997, Pages 685-693

  Xu, Guangxue ^a   Lin, Shangan ^a  

^a SUN YAT SEN UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYST ACTIVITY; CATALYST SELECTIVITY; CATALYSTS; COPOLYMERIZATION; ETHYLENE; GLASS TRANSITION; MICROSTRUCTURE; MOLECULAR WEIGHT; REACTION KINETICS; STYRENE; SYNTHESIS (CHEMICAL);

METHYLALUMINOXANE (MAO); TITANOCENE BASED CATALYTIC SYSTEM; TRIMETHYLALUMINUM (TMA); WIDE ANGLE X RAY DIFFRACTOMETRY (WAXD);

COPOLYMERS;

EID: 0031077832     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma960792a     Document Type: Article

References (80)

1. (a) Razuvaev, G. A.; Minsker, K. S.; Spapiro, T. S. Vysokomol. Soedin. 1962, 4, 1833.
2. (b) Chenovskaya, R. P.; Levedev, V. P.; Minsker, K. S.; Razuvaev, G. A. Vysokomol. Soedin. 1964, 6, 1313.
3. (c) Kawai, Y.; Katsuta, S. J. Polym. Sci., Part A-1 1970, 8, 2421.
4. (d) Gehrke, K.; Bledzki, A.; Schmidt, B.; Ulbricht, J. Plaste Kautsch. 1971, 18, 87.
5. (e) Schimmel, C.; Gehrke, K. Plaste Kautsch. 1980, 27, 6.
6. (f) Soga, K.; Yanagihara, H. Polym. Bull. (Berlin) 1988, 20, 237.
7. (g) Soga, K.; Yanagihara, H. Macromolecules 1989, 22, 2875.
8. (h) Giudice, L. Del; Cohen, R. E.; Attalla, G.; Bertinotti, F. J. Appl. Polym. Sci. 1985, 30, 4305.
9. (a) Lock, G. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1985, 26, 60.
10. (b) Buscio, V.; Corradini, P.; Savino, V. Makromol. Chem., Rapid Commun. 1984, 5, 737.
11. (c) Takahashi, T.; Mizuno, H.; Thomas, E. L. J. Macromol. Sci., Phys. 1983, B22, 425.
12. (d) Prabhu, P.; Theil, M. H.; Gilbert, R. D. J. Polym. Sci., Polym. Chem. Ed. 1983, 19, 523.
13. (e) Prabhu, P.; Theil, M. H.; Gilbert, R. D. J. Polym. Sci., Polym. Lett. Ed. 1980, 18, 389.
14. (a) Tritto, I.; Li, S.; Sacchi, M. C.; Locatelli, P.; Zannoni, G. Macromolecules 1955, 28, 5358.
15. (b) Waymouth, R. M.; Coates, G.; Mogstad, A. L.; Stein, K.; Fischer, D. Macromol. Symp. 1995, 98, 221.
16. (c) Bochmann, M.; Lancaster, S. J. J. Organomet. Chem. 1995, 497, 55.
17. (d) Chen, Y.; Rausch, M. D.; Chien, J. C. W. Macromolecules 1995, 28, 5399.
18. (e) Kaminsky, W. Catal. Today 1994, 20, 257.
19. (f) Spaleck, W.; Kuber, F.; Winter, A.; Rohrmann, J.; Bachmann, B.; Antberg, M.; Dolle, V.; Paulvs, E. F. Organometallics 1994, 13, 954.
20. (g) Kucht, A.; Kucht, H.; Barry, S.; Chien, J. C. W.; Rausch, M. D. Organometallics 1993, 12, 3075.
21. (h) Xu, G.; Lin, S. Polym. Bull. (Beijing) 1993, 3, 20.
22. (i) Chien, J. C. W.; Salajka, Z.; Dong, S. Macromolecules 1992, 25, 3199.
23. (j) Collins, S.; Kelly, W. M.; Holden, D. A. Macromolecules 1992, 25, 1780.
24. (a) Schupfher, G.; Kaminsky, W. J. Mol. Catal. A: Chem. 1995, 102, 59.
25. (b) Janiak, C.; Lange, K. C. H.; Marquardt, P. Macromol. Rapid Commun. 1995, 16, 643.
26. (c) Rieger, B.; Mu, X.; Mallin, D. T.; Chien, J. C. W. Macromolecules 1990, 23, 3559.
27. (d) Maliin, D. T.; Rausch, M. D.; Lin, Y. G.; Dong, S.; Chien, J. C. W. J. Am. Chem. Soc. 1990, 112, 2030.
28. (a) Gauthier, W. J.; Corrigan, J. F.; Taylor, N. J.; Collins, S. Macromolecules 1995, 28, 3771.
29. (b) Miyake, S.; Okumura, Y.; Inazawa, S. Macromolecules 1995, 28, 3074.
30. (c) Ewen, J. A.; Jones, R. L.; Razavi, A.; Ferrera, J. D. J. Am. Chem. Soc. 1988, 110, 6256.
31. (d) Ishihara, N.; Seimiya, T.; Kuramoto, M.; Uoi, M. Macromolecules 1986, 19, 2465.
32. (e) Kaminsky, W.; Kulper, K.; Brintzinger, H. H.; Wild, F. R. W. P. Angew. Chem., Int. Ed. Engl. 1985, 24, 507.
33. (f) Ewen, J. A. J. Am. Chem. Soc. 1984, 106, 6355.
34. (a) Mukaiyama, T.; Hayakawa, M.; Oouchi, K.; Mitani, M.; Yamada, T. Chem. Lett. 1995, 8, 737.
35. (b) Aaltonen, P.; Lofgren, B. Macromolecules 1995, 28, 5353.
36. (c) Okuda, J.; Koenig, P.; Ngo, S.; Rushkin, I. L. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1994, 35, 524.
37. (d) Kaminsky, W.; Bark, A.; Steiger, R. J. Mol. Catal. 1992, 74, 109.
38. (a) Huang, J.; Rempel, G. L. Prog. Polym. Sci. 1995, 20, 459.
39. (b) Reddy, S. S.; Sivaram, S. Prog. Polym. Sci. 1995, 20, 309.
40. (c) Mohring, P. C.; Coville, N. J. J. Organomet. Chem. 1994, 479, 1.
41. (a) Miyatake, T.; Mizunuma, K.; Kakugo, M. Makromol. Chem., Macromol. Symp. 1993, 66, 203.
42. (b) Kakugo, M.; Miyatake, T.; Mizunuma, K. Stud. Surf. Sci. Catal. 1990, 56, 517.
43. Naganuma, A.; Tazaki, T.; Machida, S. Jpn. Kokai Tokkyo Koho JP 04130114, 1992 (to Polyplastics Co., Ltd.); Chem. Abstr. 1993, 118, 7536.
44. Inoe, N.; Jinno, M.; Shiomura, T. Jpn. Kokai Tokkyo Koho JP 0687937, 1994 (to Mitsui Toatsu Chemicals Inc.); Chem. Abstr. 1994, 121, 109890.
45. Stevens, J. C.; Timmers, F. J.; Wilson, D. R.; Schmidt, G. F.; Nickias, P. N.; Rosen, R. K.; Knight, G. W.; Lai, S. Eur. Pat. Appl. 416815, 1991 (to Dow Chemical Co.); Chem. Abstr. 1991, 115, 93163.
46. Longo, P.; Grassi, A.; Oliva, L. Makromol. Chem. 1990, 191, 2387
47. Lee, D.; Yoon, K.; Lee, E.; Noh, S.; Byun, G.; Lee, C. Macromol. Rapid Commun. 1995, 16, 265.
48. Inoue, N.; Shiomura, T.; Kouno, M. Eur. Pat. Appl. 572990, 1993 (to Mitsui Toatsu Chemicals Inc.); Chem. Abstr. 1994, 121, 58212.
49. Oliva, L.; Caporaso, L.; Pellecchia, C.; Zambelli, A. Macromolecules 1995, 8, 4665.
50. Devore, D. D. Eur. Pat. Appl. 514828, 1991 (to Dow Chemical Co.); Chem. Abstr. 1993, 118, 169790.
51. Pellecchia, C.; Pappalardo, D.; D'Arco, M.; Zambelli, A. Macromolecules 1996, 29, 1158.
52. Aaltonen, P.; Seppala, J. Eur. Polym. J. 1994, 30, 683.
53. Aaltonen, P.; Seppala, J. Eur. Polym. J. 1995, 31, 79.
54. Aaltonen, P.; Seppala, J.; Matilainen, L.; Leskela, M. Macromolecules 1994, 27, 3136.
55. Chien, J. C. W.; Dong, S. Polym. Bull. (Berlin) 1992, 29, 515.
56. Wade, S. J. Chem. Soc., Dalton Trans. 1982, 271.
57. (a) Chien, J. C. W.; Hu, Y. J. Polym. Sci., Part A 1989, 27, 897.
58. (b) Chien, J. C. W.; Wu, J. L. J. Polym. Sci., Polym. Chem. Ed. 1982, 20, 2461.
59. Green, M. L. H.; Ishihara, N. J. Chem. Soc., Dalton Trans. 1994, 657.
60. Lu, Z.; Liao, K.; Lin, S. J. Appl. Polym. Sci. 1994, 53, 1453.
61. Xu, G.; Lin, S. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1994, 35, 686.
62. Chien, J. C. W.; Salajka, Z. J. Polym. Sci., Part A 1991, 29, 1253.
63. Xu, G.; Liu, S.; Lin, S.; Lu, W.; Cheng, D.; Tu, J. Polym. Prepr. (China Chem. Soc., Div. Polym. Chem. Phys.) 1995, 1, 208.
64. (a) Grassi, A.; Pellecchia, C.; Oliva, L. Macromol. Chem. Phys. 1995, 196, 1093.
65. (b) Longo, P.; Proto, A.; Zambelli, A. Macromol. Chem. Phys. 1995, 196, 3093.
66. (c) Grassi, A.; Zambelli, A. Organometallics 1996, 15, 480.
67. (a) Resconi, L.; Bossi, S.; Abis, L. Macromolecules 1990, 23, 4489.
68. (b) Sinn, H.; Bliemeister, J.; Clausnitzer, D.; Tikwe, L.; Winter, H.; Zarncke, O. Transition Metals and Organometallics as Catalysts for Olefin Polymerization; Sinn, H., Kaminsky, W., Eds.; Springer: New York, 1987; p 85.
69. (c) Ramoy, K. C.; O'Brien, J. F.; Hasegawa, I.; Borchert, A. E. J. Phys. Chem. 1965, 69, 3418.
70. (a) Harlan, C. J.; Bott, S. G.; Barron, A. R. J. Am. Chem. Soc. 1995, 117, 6465.
71. (b) Mason, M. R.; Smith, J. M.; Bott, S. G.; Barron, A. R. J. Am. Chem. Soc. 1993, 115, 4971.
72. (c) Pasynkiewicz, Polyhedron 1990, 9, 429.
73. (d) Atwood, J. L.; Zaworotko, M. J. J. Chem. Soc., Chem. Commun. 1983, 302.
74. (d) Kaminsky, W.; Sinn, H. Adv. Organomet. Chem. 1980, 18, 99.
75. (a) Giannetti, E.; Nicoletti, G.; Mazzochi, R. J. Polym. Sci., Polym. Chem. Ed. 1985, 23, 2117.
76. (b) Kaminsky, W. Transition Metal Catalyzed Polymerization; Sympuirk, R. P., Ed.; Harwood Academic Publishers: New York, 1983; p 225.
77. Cam, D.; Albizzati, E.; Cinquina, P. Makromol. Chem. 1990, 191, 1641.
78. (a) Chien, J. C. W.; He, D. J. Polym. Sci., Part A 1991, 29, 1595.
79. (b) Siergiejczyk, L.; Synoradzki, L. J. Organomet. Chem. 1986, 311, 253.
80. Randall, J. C. J. Polym. Sci., Polym. Phys. Ed. 1975, 13, 901.