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Volumn 16, Issue 13, 1997, Pages 3055-3067

Butadiene complexes of titanium(II) and titanium(O): Synthesis, butadiene dimerization catalysis, and crystal structures of TiMe2(η4-1,4-C4H4Ph 2)(dmpe) and Ti(η4-C4H6)2(dmpe)

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EID: 0003315619     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9606552     Document Type: Article
Times cited : (22)

References (70)
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    • note
    • 32 are nearly identical despite the large difference in the dihedral angle ø (see Table 4).
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    • note
    • A referee suggested that for 2 the fluxional mechanism may involve equilibration with an isomer in which the open edge of the butadiene ligand is oriented toward a Ti-Me bond rather than a Ti-P bond. We see no evidence of this second isomer, however.
  • 67


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