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Volumn 111, Issue 17, 2007, Pages 3278-3286

Dehydrogenation of methanol by vanadium oxide and hydroxide cluster cations in the gas phase

Author keywords

[No Author keywords available]

Indexed keywords

CONDENSATION; DEHYDROGENATION; ELECTROSPRAY IONIZATION; FORMALDEHYDE; FREE RADICALS; MASS SPECTROMETRY; POSITIVE IONS; VANADIUM COMPOUNDS;

EID: 34249095360     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp067454o     Document Type: Article
Times cited : (36)

References (53)
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    • 2) = 0.037 amu cannot be achieved. For an example of relatively high mass resolution using a quadrupole setup, see: Roithová, J.; Schröder, D. Phys. Chem. Chem. Phys., in press.
    • 2) = 0.037 amu cannot be achieved. For an example of relatively high mass resolution using a quadrupole setup, see: Roithová, J.; Schröder, D. Phys. Chem. Chem. Phys., in press.
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    • + in the reactivity screening, which would indeed be interesting for comparison as this species bears an even larger fv of 5.5. Unfortunately, however, the ion with m/z = 182 formed upon ESI of the precursor compound overlaps with isobaric interferences.
    • + in the reactivity screening, which would indeed be interesting for comparison as this species bears an even larger fv of 5.5. Unfortunately, however, the ion with m/z = 182 formed upon ESI of the precursor compound overlaps with isobaric interferences.
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    • + cluster).
    • + cluster).
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    • The actual binding situations of the formaldehyde ligands in the cluster ions are unknown, but coordination via the oxygen lone pairs appears most likely; also see refs. 5, 6, 11, and 21
    • The actual binding situations of the formaldehyde ligands in the cluster ions are unknown, but coordination via the oxygen lone pairs appears most likely; also see refs. 5, 6, 11, and 21.
  • 36
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    • NIST Standard Reference Database Number 69; National Institute of Standards and Technology (NIST): Gaithersburg, MD, Jun 2005 release; see http://webbook.nist.gov/chemistry/.
    • NIST Standard Reference Database Number 69; National Institute of Standards and Technology (NIST): Gaithersburg, MD, Jun 2005 release; see http://webbook.nist.gov/chemistry/.
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    • For methods to probe the nature of neutral molecules formed from gaseous ions, see
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    • a.
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    • For calculated values, see:, SFB 546, Report, Publikationen A4; p
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    • Also because of the low abundance of the channel for Am = +14, this possible product ion is accordingly not specified any further in Table 3.
    • Also because of the low abundance of the channel for Am = +14, this possible product ion is accordingly not specified any further in Table 3.


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