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79
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26844473268
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+ of path i-b). As discussed there, this intermediate is a dead end for methanol dehydrogenation without any viable way to the experimentally observed exit channel.
-
-
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80
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26844509060
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note
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This has been verified by intrinsic reaction coordinate (IRC) calculations for the triplet surface.
-
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81
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84
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Note that mere association reactions are disfavored under the low-pressure ICR conditions, but the probability rises with increasing size of the system.
-
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85
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26844490331
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note
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Due to low abundances (<5%), ions with m/z 129 and 143 are not included in Figure 6 for the sake of clarity.
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86
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