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Volumn 26, Issue 10, 2007, Pages 2482-2484

Ruthenium cluster mediated transformation of linear alkenes into trienyl ligands. Activation of five C(sp3)-H bonds of 1-octene, 1-Nonene, and 1-Decene

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; HYDROGEN BONDS; LIGANDS; OLEFINS;

EID: 34249077513     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om070205h     Document Type: Article
Times cited : (4)

References (39)
  • 1
    • 0037198618 scopus 로고    scopus 로고
    • for selected reviews on C-H bond activation, see: (a) Labinger, J. A.; Bercaw, J. E. Nature 2002, 417, 507.
    • for selected reviews on C-H bond activation, see: (a) Labinger, J. A.; Bercaw, J. E. Nature 2002, 417, 507.
  • 32
    • 34249053889 scopus 로고    scopus 로고
    • Selected crystallographic data are as follows, 2a) 2·0.25CH2Cl2· CHCl3: C59.25H37.5Cl3.5N4O 30Ru14, Mr, 2824.49, triclinic, space group P1, Z, 2, a, 11.949(2) Å, b, 17.876(4) Å, c, 18.820(4) Å, α, 88.188(4)°, β, 80.155(3)°, γ, 85.921(3)°, U, 3950(1) Å3, T, 296(2) K, μ(Mo Kα, 2.790 mm -1, wR1(F2, 0.0458 (I > 2σ(I, CCDC 635238. 2b· 0.5C2H4Cl2: C 30H20ClN2O15Ru7. M r, 1391.42, monoclinic, space group C2/c, Z, 8, a, 33.809(7) Å, b, 11.917(2) Å, c, 18.550(4) Å, β= 93.714(4, U, 7458(3) Å3, T, 296(2) K, μ(Mo Kα, 2.901 mm-1, wR1F2, 0.0
    • 2) = 0.0745 (I > 2σ(I)), CCDC 635242.
  • 33
    • 34249080864 scopus 로고    scopus 로고
    • Selected IR data (CH2Cl2, cm-1; v CO, 2068 (m, 2033 (s, 2015 (vs, 2005 (s, sh, 1974 (m, br, 1934 (w, br, 1825 (w, br, 2a, 2069 (m, 2033 (s, 2014 (vs, 2004 (s, sh, 1974 (m, br, 1933 (w, br, 1825 (w, br, 2b, 2068 (m, 2033 (s, 2015 (vs, 2005 (s, sh, 1974 (m, br, 1934 (w, br, 1825 (w, br, 3a, 2068 (m, 2033 (s, 2015 (vs, 2005 (s, sh, 1974 (m, br, 1934 (w, br, 1825 (w, br, 3b, 2068 (m, 2033 (s, 2013 (vs, 2002 (s, sh, 1974 (m, br, 1934 (w, br, 1825 (w, br, 3c, 2068 (m, 2032 (s, 2013 (vs, 2002 (s, sh, 1973 (m, br, 1932 (w, br, 1825 (w, br, 4a, 4b, Selected 1H NMR data (300 MHz, 293 K, CDCl3; δ(μ 3-H, 18.54 (s, 2a, 17.82 (s, 2b, 17.93 (s, 3a, 18.53 (s, 3b, 17.86 (s, 3c, 17.92 (s) and -17.96 s, 4a, 4b
    • 3-H)): -18.54 (s) (2a); -17.82 (s) (2b); -17.93 (s) (3a); -18.53 (s) (3b); -17.86 (s) (3c); -17.92 (s) and -17.96 (s) (4a + 4b).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.