Hexaruthenium carbonyl cluster complexes with basal edge-bridged square pyramidal metallic skeleton: Efficient synthesis of 2-imidopyridine derivatives and determination of their reactive sites in carbonyl substitution reactions

Inorganic Chemistry

Volumn 43, Issue 17, 2004, Pages 5450-5458

  Cabeza, Javier A ^a   Del Río, Ignacio ^a   García Álvarez, Pablo ^a   Miguel, Daniel ^b   Riera, Víctor ^a  

^a UNIVERSITY OF OVIEDO   (Spain)

^b UNIVERSITY OF VALLADOLID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

2 AMINO 6 METHYLPYRIDINE; 2 AMINOPYRIDINE; 2 IMIDOPYRIDINE DERIVATIVE; AMINE; BIS(DIPHENYLPHOSPHINO)METHANE; CARBONYL DERIVATIVE; HYDROGEN; IMIDE; LIGAND; METAL; METAL COMPLEX; METHANE; NITROGEN; PHOSPHINE DERIVATIVE; PICOLINE DERIVATIVE; PYRIDINE; PYRIDINE DERIVATIVE; RUTHENIUM COMPLEX; TRIPHENYLPHOSPHINE; UNCLASSIFIED DRUG; XYLENE;

ARTICLE; ATOM; CHEMICAL BOND; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; DISSOCIATION; GEOMETRY; HEATING; ISOMER; SUBSTITUTION REACTION; SYNTHESIS; THERMODYNAMICS;

EID: 4043069112     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0492789     Document Type: Article

References (44)

1. For a review on the reactivity of triruthenium carbonyl clusters derived from 2-aminopyridines, see Cabeza, J. A. Eur. J. Inorg. Chem. 2002, 1559.
2. For very recent articles uncovered by reference 1, see (a) Cabeza, J. A.; del Río, I.; García-Granda, S.; Riera, V.; Suárez, M. Organometallics 2002, 21, 2540.
3. (b) Cabeza, J. A.; del Río, I.; García-Granda, S.; Riera, V.; Suárez, M. Organometallics 2002, 21, 5055.
4. (c) Cabeza, J. A.; del Río, I.; Moreno, M.; García-Granda, S.; Pérez-Priede, M.; Riera, V. Eur. J. Inorg. Chem. 2002, 3204.
5. (d) Cabeza, J. A.; del Río, I.; García-Granda, S.; Martínez-Méndez, L.; Moreno, M.; Riera, V. Organometallics 2003, 22, 1164.
6. (e) Cabeza, J. A.; del Río, I.; Riera, V.; Suárez, M.; García-Granda, S. Organometallics 2004, 23, 1107.
7. Cabeza, J. A. In Metal Clusters in Chemistry; Braunstein, P., Oro, L. A., Raithby P. R., Eds.; Wiley-VCH: Weinheim, 1999; p 715.
8. For a review on alkyne hydrogenation mediated by 2-amidopyridine-bridged triruthenium carbonyl cluster complexes, see Cabeza, J. A.; Fernández- Colinas, J. M.; Llamazares, A. Synlett 1995, 579.
9. Nombel, P.; Lugan, N.; Mulla, F.; Lavigne, G. Organometallics 1994, 13, 4673.
10. Nombel, P.; Lugan, N.; Donnadieu, B.; Lavigne, G. Organometallics 1999, 18, 187.
11. Chihara, T.; Tase, T.; Ogawa, H.; Wakatsuki, Y. Chem. Commun. 1999, 279.
12. Lee, K. K. H.; Wong, W. T. J. Chem. Soc., Dalton Trans. 1996, 1707.
13. (a) Adams, R. D.; Babin, J. E.; Tasi, M.; Wolfe, T. A. J. Am. Chem. Soc. 1988, 110, 7093.
14. (b) Adams, R. D.; Babin, J. E.; Tasi, M. Organometallics 1988, 7, 503.
15. (c) Adams, R. D.; Babin, J. E.; Tasi, M.; Wolfe, T. A. New J. Chem. 1988, 12, 481.
16. (d) Adams, R. D.; Qu, X.; Wu, W. Organometallics 1994, 13, 1272.
17. Cabeza, J. A.; del Río, I.; García-Álvarez, P.; Riera, V.; Suárez, M.; García-Granda, S. Dalton Trans. 2003, 2808.
18. Andreu, P. L.; Cabeza, J. A.; Riera, V.; Jeannin, Y.; Miguel, D. J. Chem. Soc., Dalton Trans. 1990, 2201.
19. (a) Link, H.; Fenske, D. Z. Anorg. Allg. Chem. 1999, 625, 1878.
20. (b) Reiss, P.; Fenske, D. Z. Anorg. Allg. Chem. 2000, 626, 2245.
21. (c) Blohm, M. L.; Gladfelter, W. L. Organometallics 1986, 5, 1049.
22. (d) Gervasio, G.; Rossetti, R.; Stanghellini, P. L. J. Chem. Res. 1979, 334, 3943.
23. (e) Ho, E. N. M.; Wong, W. T. J. Chem. Soc., Dalton Trans. 1998, 4215.
24. (f) Ho, E. N. M.; Wong, W. T. J. Chem. Soc., Dalton Trans. 1998, 513.
25. (g) Ho, E. N. M.; Lin, Z.; Wong, W. T. Eur. J. Inorg. Chem. 2001, 1321.
26. (h) Han, S. W. H.; Nguyen, S. T.; Geoffroy, G. L.; Rheingold, A. L. Organometallics 1988, 7, 2034.
27. (i) Scoles, L.; Sterenberg, B. T.; Udachin, K. A.; Carty, A. J. Chem. Commun. 2002, 320.
28. (j) Cabeza, J. A.; del Río, I.; García-Granda, S.; Moreno, M.; Riera, V.; Rosales-Hoz, M. J.; Suárez, M. Eur. J. Inorg. Chem. 2001, 2899.
29. (k) Yeh, W. Y.; Stern, C.; Shriver, D. F. Inorg. Chem. 1996, 35, 7857.
30. (l) Hansert, B.; Powell, A. K.; Vahrenkamp, H. Chem. Ber. 1991, 124, 2697.
31. See, for example, Andreu, P. L.; Cabeza, J. A.; Pellinghelli, M. A.; Riera, V.; Tiripicchio, A. Inorg. Chem. 1991, 30, 4611.
32. 3) fragments, see (a) Cooke, J.; McClung, R. E. D.; Takats, J.; Rogers, R. D. Organometallics 1996, 15, 4459 and references therein.
33. (b) Alex, R. F.; Pomeroy, R. K. Organometallics 1987, 6, 2437.
34. (c) Adams, H.; Agustinho, S. C. M.; Chombe, K.; Mann, B. E.; Smith, S.; Squires, C.; Spey, S. E. Can. J. Chem. 2001, 79, 760.
35. Shen, J. K.; Basolo, F.; Nombel, P.; Lugan, N.; Lavigne, G. Inorg. Chem. 1996, 35, 755.
36. Parkin, S.; Moezzi, B.; Hope H. J. Appl. Crystallogr. 1995, 28, 53.
37. Blessing, R. H. Acta Crystallogr. 1995, A51, 33.
38. Beurskens, P. T.; Beurskens, G.; Bosman, W. P.; de Gelder, R.; García-Granda, S.; Gould, R. O.; Israël, R.; Smits, J. M. M. The DIRDIF-96 Program System; Crystallography Laboratory, University of Nijmegen: The Netherlands, 1996.
39. Sheldrick, G. M. SHELKL97, Version 97-2; University of Göttingen: Germany, 1997.
40. Orpen, A. G. J. Chem. Soc., Dalton Trans. 1980, 2509.
41. Spek, A. L. In Computational Crystallography; Sayre, D., Ed.; Clarendon Press: Oxford, 1982; p 528.
42. Farrugia, L. J. J. Appl. Crystallogr. 1999, 32, 837.
43. Sheldrick, G. M. SADABS, Empirical Absorption Correction Program; University of Göttingen: Göttingen, Germany, 1997.
44. Sheldrick, G. M. SHELXTL, An Integrated System for Solving, Refining, and Displaying Crystal Structures from Diffraction Data, Version 5.1; Bruker AXS, Inc.: Madison, WI, 1998.