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14
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33749026617
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For a recent review on macrocyclization of unsaturated lactones by ring-closing metathesis, see:
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For a recent review on macrocyclization of unsaturated lactones by ring-closing metathesis, see:. Gradillas A., and Pérez-Castells J. Angew. Chem., Int. Ed. 45 (2006) 6086-6101
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Gradillas, A.1
Pérez-Castells, J.2
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16
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34248633898
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note
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1H NMR spectra of the crude reaction mixture.
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18
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0026325277
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Phosphonoacetate III can be easily prepared from inexpensive starting materials:
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Phosphonoacetate III can be easily prepared from inexpensive starting materials:. Patois C., Savignac P., About-Jaudet E., and Collignon N. Synth. Commun. 21 (1991) 2391-2396
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(1991)
Synth. Commun.
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Patois, C.1
Savignac, P.2
About-Jaudet, E.3
Collignon, N.4
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19
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34248642727
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note
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Catalyst [Ru]-II was added in six portions over 144 h.
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20
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34248658677
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note
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2,6-Heptadienoic acid I and mixed anhydride IV were prepared according to Ref. 6c.
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24
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0038215596
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For a review on olefin cross-metathesis, see:
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For a review on olefin cross-metathesis, see:. Connon S.J., and Blechert S. Angew. Chem., Int. Ed. 42 (2003) 1900-1923
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(2003)
Angew. Chem., Int. Ed.
, vol.42
, pp. 1900-1923
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Connon, S.J.1
Blechert, S.2
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25
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0001359587
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Hafner A., Duthaler R.O., Marti R., Rihs J., Rhote-Streit P., and Schwarzenbach F. J. Am. Chem. Soc. 114 (1992) 2321-2336
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(1992)
J. Am. Chem. Soc.
, vol.114
, pp. 2321-2336
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Hafner, A.1
Duthaler, R.O.2
Marti, R.3
Rihs, J.4
Rhote-Streit, P.5
Schwarzenbach, F.6
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26
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34248679763
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note
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Crotyltitanium complex Ti(S,S)-I allows the delivery of the nucleophile on the Re face of aldehyde 16.
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28
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34248632399
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note
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Enone 20 was recovered in 40% yield. The catalyst [Ru]-III and 15 were added three times over 72 h. The yields for this reaction range from 27% to 50%.
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30
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15444378446
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Vedrenne E., Dupont H., Oualef S., Elkaïm L., and Grimaud L. Synlett (2005) 670-672
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(2005)
Synlett
, pp. 670-672
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Vedrenne, E.1
Dupont, H.2
Oualef, S.3
Elkaïm, L.4
Grimaud, L.5
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32
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34248683787
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note
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Catalyst [Cu]-I was prepared following the procedure described in Ref. 24.
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