Chemical surface modification via radical C-C bond-forming reactions

Journal of the American Chemical Society

Volumn 129, Issue 18, 2007, Pages 5826-5827

  Siegenthaler, Kai Oliver ^a   Schäfer, Andreas ^a   Studer, Armido ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

FUNCTIONAL GROUP;

ARTICLE; CHEMICAL MODIFICATION; CHEMICAL REACTION; CHEMICAL STRUCTURE; ISOMERIZATION; SURFACE PROPERTY;

EID: 34248531614     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0686716     Document Type: Article

References (27)

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25. The same contact angle was obtained if the reaction was run for 20 h.
26. Reaction of 1 with 7-octenyl trimethoxysilane in solution provides the corresponding carboaminoxylation product which can be covalently bound to the surface by standard SAM formation. A CA(adv) of 81 ± 3° was measured (see SI). The same value is obtained for wafer E prepared by surface radical carboaminoxylation showing that the radical C-C bond formation at the surface is indeed a highly efficient process.
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