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For sake of clarity, in Figure 1a are evidenced the ADF outcomes pertaining to one trinuclear unit.
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For sake of clarity, in Figure 1a are evidenced the ADF outcomes pertaining to one trinuclear unit.
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Hexanuclear islands of compound Id are made by connecting two trinuciear units through two monatomic asymmetric butyrate ions, See ref 3b
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Hexanuclear "islands" of compound Id are made by connecting two trinuciear units through two monatomic asymmetric butyrate ions, See ref 3b.
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Due to these interactions, 11 atoms belonging to the two trinuclear and the mononuclear units lie almost exactly coplanar
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Due to these interactions, 11 atoms belonging to the two trinuclear and the mononuclear units lie almost exactly coplanar.
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The most relevant difference consists in the increasing of the distance between the two triangular units of A, with respect to 5, due to larger bite of the bridging NO3- bound through two different oxygens compared with the chloride ion and in the absence of the crystallization water. Nevertheless, compounds A and 5 have even the same Crystallographic group (P4̄2lm) and an almost identical crystal packing
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lm) and an almost identical crystal packing.
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34247471717
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It is noteworthy that such dimensions (4-5 A) coincide with those of most molecular sieves used in the normal lab practice for gas and liquid adsorption purposes.
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It is noteworthy that such dimensions (4-5 A) coincide with those of most molecular sieves used in the normal lab practice for gas and liquid adsorption purposes.
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