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Volumn 7, Issue 4, 2007, Pages 676-685

The different supramolecular arrangements of the triangular [Cu 3(μ3-OH)(μ-pz)3]2+ (pz = Pyrazolate) secondary building units. Synthesis of a coordination polymer with permanent hexagonal channels

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EID: 34247478171     PISSN: 15287483     EISSN: None     Source Type: Journal    
DOI: 10.1021/cg060501h     Document Type: Article
Times cited : (63)

References (54)
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    • (a) Casarin, M.; Corvaja, C.; Di, Nicola, C.; Falcomer, D.; Franco, L.; Monari, M.; Pandolfo, L.; Pettinari, C.; Piccinelli, F.; Tagliatesta, P. Inorg. Chem. 2004, 43, 5865.
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    • Amsterdam Density Functional Package, version 2005; Vrjie Universiteit: Amsterdam, The Netherlands, 2005
    • Amsterdam Density Functional Package, version 2005; Vrjie Universiteit: Amsterdam, The Netherlands, 2005.
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    • SMART & SAINT Software Reference Manuals, Bruker Analytical X-ray Instruments Inc, Madison. WI
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    • Sheldrick, G. M. SHELXTLplus (Windows NT Version) Structure Determination Package, version 5.1; Bruker Analytical X-ray Instruments Inc, Madison, WI, 1998
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    • For sake of clarity, in Figure 1a are evidenced the ADF outcomes pertaining to one trinuclear unit.
    • For sake of clarity, in Figure 1a are evidenced the ADF outcomes pertaining to one trinuclear unit.
  • 30
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    • Hexanuclear islands of compound Id are made by connecting two trinuciear units through two monatomic asymmetric butyrate ions, See ref 3b
    • Hexanuclear "islands" of compound Id are made by connecting two trinuciear units through two monatomic asymmetric butyrate ions, See ref 3b.
  • 36
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    • Due to these interactions, 11 atoms belonging to the two trinuclear and the mononuclear units lie almost exactly coplanar
    • Due to these interactions, 11 atoms belonging to the two trinuclear and the mononuclear units lie almost exactly coplanar.
  • 39
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    • Witteven, H. T.; Nieuwenhuyse, B.; W. L. C.; Reedijk, J. J, Inorg. Nucl. Chem. 1974, 36, 1535.
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    • The most relevant difference consists in the increasing of the distance between the two triangular units of A, with respect to 5, due to larger bite of the bridging NO3- bound through two different oxygens compared with the chloride ion and in the absence of the crystallization water. Nevertheless, compounds A and 5 have even the same Crystallographic group (P4̄2lm) and an almost identical crystal packing
    • lm) and an almost identical crystal packing.
  • 51
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    • It is noteworthy that such dimensions (4-5 A) coincide with those of most molecular sieves used in the normal lab practice for gas and liquid adsorption purposes.
    • It is noteworthy that such dimensions (4-5 A) coincide with those of most molecular sieves used in the normal lab practice for gas and liquid adsorption purposes.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.