Sorption-desorption behavior of bispyrazolato-copper(II) 1D coordination polymers

Journal of the American Chemical Society

Volumn 127, Issue 17, 2005, Pages 6144-6145

  Cingolani, Augusto ^a   Galli, Simona ^b   Masciocchi, Norberto ^b   Pandolfo, Luciano ^c   Pettinari, Claudio ^a   Sironi, Angelo ^d  

^a UNIVERSITY OF CAMERINO   (Italy)

^b UNIVERSITY OF INSUBRIA   (Italy)

^c UNIVERSITY OF PADOVA   (Italy)

^d UNIVERSITY OF MILAN   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER COMPLEX; POLYMER; PYRAZOLE DERIVATIVE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; CRYSTALLOGRAPHY; STRUCTURE ANALYSIS; X RAY POWDER DIFFRACTION;

EID: 18244380590     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja050856+     Document Type: Article

References (21)

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2. (b) Masciocchi, N.; Galli, S.; Sironi, A. Comm. Inorg. Chem. 2005, in press.
3. (a) Kahn, O.; Kröber, J.; Jay, C. Adv. Mater. 1992, 4, 718.
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7. Gasparač, R.; Stupnišek-Lisac, E.; Martin, C. R. Imidazole and its Derivatives as Inhibitors for Prevention of Corrosion of Copper. In Electrochemical Approach to Selected Corrosion and Corrosion Control Studies; Bonora, P. L., Deflorian, F., Eds.; EEC Book Series No. 28: 2000; pp 20-36.
8. See for example: Nomiya, K.; Tsuda, K.; Sudoh, T.; Oda, M. J. Inorg. Biochem. 1997, 68, 39.
9. See for example: Masciocchi, N.; Bruni, S.; Cariati, E.; Cariati, F.; Galli, S.; Sironi, A. Inorg. Chem. 2001, 40, 5897.
10. Barea, E.; Navarro, J. A. R.; Salas, J. M.; Masciocchi, N.; Galli, S.; Sironi, A. J. Am. Chem. Soc. 2004, 126, 3014 and references therein.
11. - moieties favored a novel reaction path, not normally accessible if inorganic salts are used: Davey, R. J.; Allen, K.; Blagden, N.; Cross, I.; Lieberman, H. F.; Quayle, M. J.; Righini, S.; Seton, L.; Tiddy, G. J. Cryst. Eng. Commun. 2002, 4, 257.
12. Bragg = 0.015 for 4801 data collected in the 9-105° range.
13. Ehlert, M. K.; Rettig, S. J.; Storr, A.; Trotter, J. Can. J. Chem. 1991, 69, 432.
14. Bragg = 0.014 for 4851 data (8-105° range, T = 130 °C). No solvent-accessible space found (Spek, A. L. J. Appl. Cryst. 2003, 36, 7).
15. Actually, pure 2 can be prepared employing freshly precipitated 4c and slow heating to ca. 195 °C (3°/min, XRPD evidence).
16. In a typical sorption experiment, ca. 200 mg of 1 was weighed into an open vial and deposited into a 25 mL Schlenk tube, which was then evacuated; a small amount of the reagent was then introduced through a serum cap (liquids) or a faucet (gases) and the vial occasionally shaken. Reaction times were in the minutes to days range, depending on the species (see Table 1).
17. Vapochromic coordination compounds have been recently studied: Fernández, E. J.; López de Luzuriaga, J. M.; Monge, M.; Montiel, M.; Olmos, M. E.; Pérez, J.; Laguna, A.; Mendizabal, F.; Mohamed, A. A.; Fackler, J. P., Jr. Inorg. Chem. 2004, 43, 3573 and references therein.
18. 3 solvates were found to be stable in air at rt; the other solvates showed fast exchange (in the minutes to a few hours time scale) with air moisture, thus hampering complete (and meaningful) XRPD data collections in flat-plate configuration.
19. Masciocchi, N.; Ardizzoia, G. A.; Brenna, S.; LaMonica, G.; Maspero, A.; Galli, S.; Sironi, A. Inorg. Chem. 2002, 41, 6080.
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