Layering transitions in thin films of spherical-domain block copolymers

Macromolecules

Volumn 40, Issue 7, 2007, Pages 2453-2460

  Stein, Gila E ^a   Kramer, Edward J ^a   Li, Xuefa ^b   Wang, Jin ^b  

^a University of California at Santa Barbara   (United States)

^b ARGONNE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BULK EQUILIBRIUM STRUCTURE; HEXAGONAL LATTICE; LAYERING TRANSITIONS; SPHERICAL DOMAIN BLOCK COPOLYMERS;

BLOCK COPOLYMERS; INTERFACES (MATERIALS); METASTABLE PHASES; MONOLAYERS; TRANSMISSION ELECTRON MICROSCOPY; X RAY SCATTERING;

THIN FILMS;

EID: 34147209939     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma0625509     Document Type: Article

References (28)

1. Stein, G.; Cochran, E.; Katsov, K.; Fredrickson, G.; Kramer, E.; Li, X.; Wang, J. Submitted for publication.
2. Bates, F. S.; Fredrickson, G. H. Annu. Rev. Phys. Chem. 1990, 41, 525-557.
3. Fasolka, M. J.; Mayes, A. M. Annu. Rev. Mater. Res. 2001, 31, 323-355.
4. Koneripalli, N.; Singh, N.; Levicky, R.; Bates, F. S.; Gallagher, P. D.; Satija, S. K. Macromolecules 1995, 28, 2897-2904.
5. Mayes, A. M.; Russell, T. P.; Bassereau, P.; Baker, S. M.; Smith, G. S. Macromolecules 1994, 27, 749-755.
6. Matsen, M. W. J. Chem. Phys. 1997, 106, 7781-7791.
7. Huinink, H. P.; Brokken-Zijp, J. C. M.; van Dijk, M. A.; Sevink, G. J. A. J. Chem. Phys. 2000, 112, 2452-2462.
8. Karim, A.; Singh, N.; Sikka, M.; Bates, F. S.; Dozier, W. D.; Felcher, G. P. J. Chem. Phys. 1994, 100, 1620-1629.
9. Henkee, C. S.; Thomas, E. L.; Fetters, L. J. J. Mater. Sci. 1988, 23, 1685-1694.
10. Yokoyama, H.; Kramer, E. J.; Rafailovich, M. H.; Sokolov, J.; Schwarz, S. A. Macromolecules 1998, 31, 8826-8830.
11. Radzilowski, L. H.; Carvalho, B. L.; Thomas, E. L. J. Polym. Sci., Part B: Polym. Phys. 1996, 34, 3081-3093.
12. Thomas, E. L.; Anderson, D. M.; Henkee, C. S.; Hoffman, D. Nature (London) 1988, 334, 598-601.
13. Matsen, M. W. J. Phys.: Condens. Matter 2002, 14, R21-R47.
14. Thomas, E. L.; Kinning, D. J.; Alward, D. B.; Henkee, C. S. Macromolecules 1987, 20, 2934-2939.
15. Yokoyama, H.; Mates, T. E.; Kramer, E. J. Macromolecules 2000, 33, 1888-1898.
16. Parratt, L. G. Phys. Rev. 1954, 95, 359-369.
17. Tolan, M. X-ray Scattering from Soft Matter Thin Films; Springer Tracts in Modern Physics 148; Springer-Verlag: Berlin, 1999.
18. Lin, Y.; Boker, A.; He, J. B.; Sill, K.; Xiang, H. Q.; Abetz, C.; Li, X. F.; Wang, J.; Emrick, T.; Long, S.; Wang, Q.; Balazs, A.; Russell, T. P. Nature (London) 2005, 434, 55-59.
19. Holy, V.; Pietsch, U.; Baumbach, T. High-Resolut. X-ray Scattering Thin Films Multilayers 1999, 149.
20. Schmidbauer, M. X-ray Diffuse Scattering from Self-Organized Mesoscopic Semiconductor Structures; Springer Tracts in Modern Physics 199; Springer: New York, 2004.
21. Lee, B.; Park, I.; Yoon, J.; Park, S.; Kim, J.; Kim, K. W.; Chang, T.; Ree, M. Macromolecules 2005, 38, 4311-4323.
22. Robinson, I. K. Phys. Rev. B 1986, 33, 3830-3836.
23. Yoneda, Y. Phys. Rev. 1963, 131, 2010-5.
24. Narayanan, S.; Lee, D. R.; Guico, R. S.; Sinha, S. K.; Wang, J. Phys. Rev. Lett. 2005, 94, 145504.
25. Guinier, A. X-Ray Diffraction; W.H. Freeman and Co.: New York, 1963.
26. Tan, H. G.; Yan, D. D.; Shi, A. C. Macromolecules 2004, 37, 9646-9653.
27. Matsen, M. W.; Bates, F. S. Macromolecules 1996, 29, 1091-1098.
28. Note Added in Proof: While theory suggests that HCP is stable, recent experiments on bulk samples indicate that FCC packing is stable near the order-disorder transition for at least one diblock copolymer. Huang, Y.; Hsu, J.; Chen, H.; Hashimoto, T. Macromolecules 2007, 40, 406-409.