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There are only four examples of spirocyclic aluminum siloxides being characterized by X-ray crystallography, namely, HNEt3][Al{(c-C 6H11)7Si7O12(OSiMe 3)}2],23 [HNEt3][Al{(c-C 5H9)7Si7O12(OSiMe 3)}2],4g [HPy][Al{(OSiPh2O) 2SiPh2}2],11 and [HNEt 3][Al{(c-C5H9)7Si7O 12-(OSiMePh2)}2].4e All these anionic complexes have an ammonium counter cation
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