Mild depolymerization of silicone grease using aluminum(III) chloride: High-yield synthesis and crystal structure of [{ClSiMe2OAlCl 2}2], and its controlled hydrolysis on aluminum surfaces

Applied Organometallic Chemistry

Volumn 17, Issue 9, 2003, Pages 730-734

  Alexander, Morgan R ^a   Mair, Francis S ^a   Pritchard, Robin G ^a   Warren, John E ^a  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

Aluminum; Depolymerization; Silicon; Siloxane; X ray; XPS

Indexed keywords

ALUMINUM CHLORIDE; SILICONE DERIVATIVE;

ARTICLE; CRYSTAL STRUCTURE; DEPOLYMERIZATION; HYDROLYSIS; NUCLEAR MAGNETIC RESONANCE; ROOM TEMPERATURE; SYNTHESIS; X RAY DIFFRACTION; X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 0041817634     PISSN: 02682605     EISSN: None     Source Type: Journal    
DOI: 10.1002/aoc.500     Document Type: Article

References (17)

1. Apblett AW, Barron AR. Organometallics 1990; 9: 2137.
2. Mulhaupt R, Calabrese J, Ittel SD. Organometallics 1991; 10: 3403.
3. McMahon CN, Bott SG, Alemany LB, Roesky HW, Barron AR. Organometallics 1999; 8: 5395.
4. McMahon CN, Obrey SJ, Keys A, Bott SG, Barron AR. J. Chem. Soc. Dalton Trans. 2000; 2151.
5. Zhdanov AA, Andrianov KA, Bogdanov AA. Izvest. Akad. Nauk SSSR Otdel Khim. Nauk 1961; 1261.
6. Shklover VE, Struchkov YT, Leviskii MM, Zhdanov AA. Zh. Strukt. Khim. 1986; 27: 120.
7. Bonamico M, Dessy G. J. Chem. Soc. A 1968; 291.
8. Cordischi D, Mele A, Somogyi A. J. Chem. Soc. 1964; 5281.
9. Plueddemann EP. Silane Coupling Agents. Plenum Press: New York, 1982.
10. Whittle BR, Whittle JD, Ellis B, Hand RJ, Short RD. J. Adhes. 2001; 77: 1.
11. Van Ooij WJ, Zhu DQ, Prasad G, Jayaseelan S, Fu Y, Teredesai N. Surf. Eng. 2000; 16: 386.
12. Healy MD, Barron AR. J. Organometal. Chem. 1990; 381: 165.
13. Lachaise S, Sabo-Etienne S, Donnadieu B, Chaudret B. Chem Commun. 2003; 214.
14. Alexander MR, Thompson GE, Beamson G. Surf. Interface Anal. 2000; 29: 468.
15. Alexander MR, Short RD, Jones FR, Michaeli W, Blomfield CJ. Appl. Surf. Sci. 1999; 137: 179.
16. Buchanan DR, Harris PM. Acta Crystallogr. Sect. B 1968; 24: 954.
17. Carey DT, Cope-Eatough EK, Vilaplana-Mafé E, Mair FS, Pritchard RG, Warren JE, Woods RJ. Dalton Trans. 2003; 1083.