Metallaborane reactivity. A stoichiometric mechanism for the insertion of two alkynes into an iridaborane framework via a disposable molybdenum chaperone

Journal of the American Chemical Society

Volumn 129, Issue 11, 2007, Pages 3392-3401

  De Montigny, Frédéric ^a   Macias, Ramón ^a   Noll, Bruce C ^a   Fehlner, Thomas P ^a   Costuas, Karine ^b   Saillard, Jean Yves ^b   Halet, Jean François ^b  

^a UNIVERSITY OF NOTRE DAME   (United States)

^b UNIVERSITÉ DE RENNES 1   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ALLENE; IRIDABORANE; METALLABORANE REACTIVITY; PRECURSOR;

CHEMICAL MODIFICATION; NUCLEAR MAGNETIC RESONANCE; OLEFINS; REACTION KINETICS; STOICHIOMETRY;

MOLYBDENUM COMPOUNDS;

ALKENE; ALKYNE; ALLENE DERIVATIVE; BORANE DERIVATIVE; CHAPERONE; HEX 1 ENE; HEX 2 ENE; IRIDABORANE; IRIDIUM; MOLYBDENUM; POLYCYCLIC AROMATIC HYDROCARBON; TRANSITION ELEMENT; UNCLASSIFIED DRUG;

ARTICLE; BORON 11 NUCLEAR MAGNETIC RESONANCE; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ISOMER; MOLECULAR INTERACTION; NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; SOLID STATE; STOICHIOMETRY; STRUCTURE ANALYSIS;

EID: 33947379564     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja068999z     Document Type: Article

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