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Volumn 121, Issue 50, 1999, Pages 11744-11750

BH bond activation of trimethylphosphineborane by transition metal complexes: Synthesis of metal complexes bearing nonsubstituted boryl- trimethylphosphine, CP*M(CO)3(BH2·PMe3) (M = Mo, W)

Author keywords

[No Author keywords available]

Indexed keywords

BORON; METAL COMPLEX; PHOSPHINE DERIVATIVE; TUNGSTEN;

EID: 0033596293     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja992168u     Document Type: Article
Times cited : (61)

References (82)
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    • note
    • 2·L, which look closely related to 2 and 3 in the electronic structure. In base-stabilized silylene complexes, the metal-silicon linkage has a substantial multiple bond character, and the coordination of the Lewis base to the silicon atom is labile in many cases. A short metal-silicon bond distance and a long silicon-donor atom bond length are found very frequently in those.


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