Molybdenum-mediated alkyne incorporation into an iridaborane framework - Release of the iridacarborane from the molybdenum coordination sphere through a dissociative equilibrium

Angewandte Chemie - International Edition

Volumn 45, Issue 13, 2006, Pages 2119-2122

  De Montigny, Frédéric ^a   Macias, Ramón ^a   Noll, Bruce C ^a   Fehlner, Thomas P ^a  

^a UNIVERSITY OF NOTRE DAME   (United States)

Author keywords

Alkynes; Carboranes; Insertion; Iridium; Molybdenum

Indexed keywords

DISSOCIATION; IRIDIUM; MOLYBDENUM;

ALKYNES; CARBORANES; INSERTION;

ORGANIC COMPOUNDS;

EID: 33746237388     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200504242     Document Type: Article

References (18)

1. C. Elschenbroich, A. Salzer, Organometallics, VCH, New York, 1989.
2. G. O. Spessard, G. L. Miessler, Organometallic Chemistry, Prentice Hall, Upper Saddle River, 1997.
3. R. N. Grimes in Inorganometallic Chemistry (Ed.: T. P. Fehlner), Plenum, New York, 1992, p. 253.
4. A. Suzuki, Organoboranes in Organic Syntheses, Hokkaido Univ., Sapporo, 2004.
5. H. Chen, S. Schlecht, T. C. Semple, J. F. Hartwig, Science 2000, 287, 1995.
6. Z. Duan, M. J. Hampden-Smith, A. P. Sylwester, Chem. Mater. 1992, 4, 1146.
7. L. G. Sneddon, M. J. Pender, K. M. Forsthoefel, U. Kusari, X. Wei, J. Eur. Ceram. Soc. 2005, 25, 91.
8. R. N. Grimes in Current Topics in the Chemistry of Boron (Ed.: G. W. Kabalka), Royal Society of Chemistry, Cambridge, UK, 1994, p. 269.
9. X. Lei, M. Shang, T. P. Fehlner, Chem. Eur. J. 2000, 6, 2653.
10. R. Macías, T. P. Fehlner, A. M. Beatty, B. Noll, Organometallics 2004, 23, 5994.
11. H. Yan, A. M. Beatty, T. P. Fehlner, Organometallics 2002, 21, 5029.
12. H. Yan, B. C. Noll, T. P. Fehlner, J. Am. Chem. Soc. 2005, 127, 4831.
13. B) contain the supplementary crystallographic information for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
14. R. P. Micciche, J. J. Briguglio, L. G. Sneddon, Organometallics 1984, 3, 1396.
15. G. J. Zimmerman, L. G. Sneddon, Inorg. Chem. 1980, 19, 3650.
16. B. Wrackmeyer, H.-J. Schanz, M. Hofmann, P. von R. Schleyer, R. Boese, Eur. J. Inorg. Chem. 1999, 533.
17. R. Macías, T. P. Fehlner, A. M. Beatty, Angew. Chem. 2002, 114, 4016;
18. Angew. Chem. Int. Ed. 2002, 41, 3860.