Lipase-assisted acidolysis of high-laurate canola oil with eicosapentaenoic acid

JAOCS, Journal of the American Oil Chemists' Society

Volumn 82, Issue 12, 2005, Pages 875-879

  Hamam, Fayez ^a   Daun, James ^b   Shahidi, Fereidoon ^a  

^a MEMORIAL UNIVERSITY OF NEWFOUNDLAND   (Canada)

^b GRAIN RESEARCH LABORATORY   (Canada)

Author keywords

Docosahexaenoic acid; Eicosapentaenoic acid; High laurate canola oil; Lipase; Long chain triacylglycerols; Medium chain triacylglycerols; Positional distribution; Structured lipids

Indexed keywords

BACTERIA; FATTY ACIDS; GLYCEROL; LIPASES; LIPIDS;

CANOLA OIL; DOCOSAHEXAENOIC ACID; EICOSAPENTAENOIC ACID; LONG CHAIN TRIACYLGLYCEROLS; MEDIUM CHAIN TRIACYLGLYCEROLS; POSITIONAL DISTRIBUTION; STRUCTURED LIPIDS;

VEGETABLE OILS;

BRASSICA NAPUS; BRASSICA NAPUS VAR. NAPUS; INSECTIVORA; PSEUDOMONAS; PSEUDOMONAS SP.;

EID: 33947373034     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11746-005-1158-2     Document Type: Article

References (25)

1. Akoh, C.C., and K.H. Huang, Enzymatic Synthesis of Structured Lipids: Transesterification of Triolein and Caprylic Acid, J. Food Lipids 2:219-230 (1995).
2. Akoh, C.C., Making New Structured Fats by Chemical Reaction and Enzymatic Modification, Lipid Technol. 9:61-66 (1997).
3. Heird, W.C., S.M. Grundy, and V.S. Hubbard, Structured Lipids and Their Use in Clinical Nutrition, Am. J. Clin. Nutr. 45:320-324 (1986).
4. Lee, T.W., and C.I. Hastilow, Quantitative Determination of Triacylglycerol Profile of Structured Lipid by Capillary Supercritical Fluid Chromatography and High-Temperature Gas Chromatography, J. Am. Oil Chem. Soc. 76:1405-1413 (1999).
5. Kim, I.-H., H. Kim, K.-T. Lee, S.-H. Chung, and S.-N. Ko, Lipase-Catalyzed Acidolysis of Perilla Oil with Caprylic Acid to Produce Structured Lipids, Ibid. 79:363-367 (2002).
6. Lee, K-T., and C.C. Akoh, Structured Lipids: Synthesis and Application, Food Res. Internat. 74:17-34 (1998).
7. Kyle, D.J., The Large-Scale Production and Use of a Single-Cell Oil Highly Enriched in Docosahexaenoic Acid, in Omega-3 Fatty Acids: Chemistry, Nutrition, and Health Effects, edited by F. Shahidi and J.W. Finley, ACS Symposium Series 788, American Chemical Society, Washington, DC, 2001, pp. 92-105.
8. Bang, H.O., and J. Dyerberg, Plasma Lipids and Lipoproteins in Greenlandic West-Coast Eskimos, Acta Med. Scand. 792:85-94 (1972).
9. Bang, H.O., and J. Dyerberg, Lipid Metabolism and Ischemic Heart Disease in Greenland Eskimos, Adv. Nutr. Res. 5:1-21 (1986).
10. Newton, I.S., Long-Chain Fatty Acids in Health and Nutrition, in Omega-3 Fatty Acids: Chemistry, Nutrition, and Health Effects, edited by F. Shahidi and J.W. Finley, ACS Symposium Series 788, American Chemical Society, Washington, DC, 2001, pp. 14-27.
11. Kennedy, J.P., Structured Lipids: Fats of the Future, Food Technol. 55:76-83 (1991).
12. Del Vecchio, A.J., High-Laurate Canola Oil: How Calgene's Program Began, Where It's Headed, INFORM 7:230-240 (1996).
13. Huang, K., and C.C. Akoh, Enzymatic Modification of Melon Seed Oil: Incorporation of Eicosapentaenoic Acid, J. Agric. Food Chem. 42:2646-2648 (1994).
14. Huang, K., and C.C. Akoh, Lipase-Catalyzed Incorporation of n-3 Polyunsaturated Fatty Acids into Vegetable Oils, J. Am. Oil Chem. Soc. 77:1277-1280 (1994).
15. Akoh, C.C., and R.V. Sista, Enzymatic Modification of Borage Oil: Incorporation of Eicosapentaenoic Acid, J. Food Lipids 2:231-238 (1995).
16. Ju, Y., F. Huang, and C. Fang, The Incorporation of n-3 Polyunsaturated Fatty Acids into Acylglycerols of Borage Oil via Lipase-Catalyzed Reactions, J. Am. Oil Chem. Soc. 75:961-965 (1998).
17. Akoh, C.C., and C.O. Moussata, Lipase-Catalyzed Modification of Borage Oil: Incorporation of Capric and Eicosapentaenoic Acids to Form Structured Lipids, Ibid. 75:697-701 (1998).
18. Senanayake, S.P.J.N., and F. Shahidi, Enzyme-Assisted Acidolysis of Borage (Borago officinalis) and Evening Primrose (Oenothera biennis) Oils: Incorporation of Omega-3 Polyunsaturated Fatty Acids, J. Agric. Food Chem. 47:3105-3112 (1999).
19. Akoh, C.C., B.H. Jennings, and D.A. Lillard, Enzymatic Modification of Evening Primrose: Incorporation of Omega-3 Polyunsaturated Fatty Acids, J. Am. Oil Chem. Soc. 75:1059-1062 (1996).
20. Akoh, C.C., B.H. Jennings, and D.A. Lillard, Enzymatic Modification of Trilinolein: Incorporation of n-3 Polyunsaturated Fatty Acids, Ibid. 72:1317-1321 (1995).
21. Soumanou, M.M., U.T. Bornscheuer, U. Schmid, and R.D. Schmid, Synthesis of Structured Triglycerides Lipase Catalysis, Fett/Lipid 700:156-160 (1998).
22. Shimada, Y., A. Sugihara, H. Nakano, T. Yokota, T. Nagao, S. Komemushi, and Y. Tominaga, Production of Structured Lipids Containing Essential Fatty Acids by Immobilized Rhizopus delemar Lipase, J. Am. Oil Chem. Soc. 73:1415-1420 (1996).
23. Kosugi, Y., and N. Azuma, Synthesis of Triacylglycerol from Polyunsaturated Fatty Acids by Immobilized Lipase, J. Am. Oil Chem. Soc. 77:1397-1403 (1994).
24. Fomuso, L.B., and C.C. Akoh, Enzymatic Modification of High-Laurate Canola to Produce Margarine Fat, J. Agric. Food Chem. 49:4482-4487 (2001).
25. Christie, W.W., Structural Analysis of Lipids by Means of Enzymatic Hydrolysis, in Lipid Analysis, edited by W.W. Christie, Pergamon Press, New York, 1982, pp. 155-166.