Chemoselective epoxidation of hydroxyl-terminated polybutadiene (HTPB) using in-situ generated dimethyl dioxirane (DMD)

Designed Monomers and Polymers

Volumn 10, Issue 1, 2007, Pages 67-77

  Alavi Nikje, Mir Mohammad ^a   Mozaffari, Zahra ^a  

^a IMAM KHOMEINI INTERNATIONAL UNIVERSITY   (Iran)

Author keywords

Chemoselectivity; Dimethyl dioxirane (DMD); Epoxidation; Hydroxyl terminated polybutadiene (HTPB); Phase transfer catalyst (PTC)

Indexed keywords

CATALYSTS; CHEMICAL BONDS; EPOXIDATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; OXIDANTS; PHASE TRANSITIONS;

CHEMOSELECTIVITY; DIMETHYL DIOXIRANE (DMD); HYDROXYL TERMINATED POLYBUTADIENE (HTPB); PHASE TRANSFER CATALYSTS (PTC);

POLYBUTADIENES;

EID: 33847713290     PISSN: 1385772X     EISSN: None     Source Type: Journal    
DOI: 10.1163/156855507779763630     Document Type: Article

References (23)

1. S. Roy, B. R. Gupta and S. K. De, in: Elastomer Technology Handbook, N. P. Cheremisinoff (Ed.), p. 636. CRC Press, Boca Raton, FL (1993).
2. T. Itoh, K. Jitsukawa, K. Kaneda and S. Teranishi, J. Am. Chem. Soc. 101, 159 (1979).
3. P. B. Latha, K. Adhinarayanan and R. Ramaswamy, Int. J. Adhesion Adhesives 14, 57 (1994).
4. B. Stenberg, G. Ahlblad, T. Reitberger and B. Terselius, Polym. Degrad. Stabil. 65, 179 (1999).
5. L. Akcelrud, M. Aguiar and S. C. D. Menezes, Macromol. Chem. Phys. 195, 3937 (1994).
6. A. E. Gerbase, J. R. Gregorio, M. Martinelli, M. L. A. Von Holleben, M. A. M. Jacobi, L. Del Freitas, C. I. W. Calcagno, A. N. F. Mendes and M. L. Pires, Catal. Today 57, 241 (2000).
7. J. M. Yang, W. C. Lai and H. T. Lin, J. Membr. Sci. 183, 37 (2001).
8. J. M. Yang, H. T. Lin and W. C. Lai, J. Membr. Sci. 208, 105 (2002).
9. D. Zuchowska, Polymer 21, 514 (1980).
10. X. Jian and A. S. Hay, J. Polym. Sci. Polym. Lett. 28, 285 (1990).
11. M. Gahagan, A. Iraqi, D. C. Cupertino, R. K. Mackie and D. J. Cole-Hamilton, J. Chem. Soc. Chem. Commun., 1688 (1989).
12. X. Jian and A. Hay, J. Polym. Sci. Polym. Chem. 29, 1183 (1991).
13. P. Kachasakul, S. Assabumrungrat, P. Praserthdam and U. Pancharoen, Chem. Eng. J. 92, 131 (2003).
14. R. J. Kennedy and A. M. Stock, J. Org. Chem. 25, 1901 (1960).
15. A. C. Besemer, H. Van Bekkum and P. L. Bragd, Carbohydr. Polym. 49, 397 (2002).
16. D. H. Brown Ripin, W. Cai and S. J. Brenek, Tetrahedron Lett. 41, 5817 (2000).
17. V. K. Aggarwal, CH. Lopin and F. Sandrinelli, J. Am. Chem. Soc. 125, 7596 (2003).
18. G. Asensio, M. E. Gonzalez-Nunez, C. Biox-Bernardini, R. Mello and W. Adam, J. Am. Chem. Soc. 115, 7250 (1993).
19. G. Asensio, C. Biox-Bernardini, C. Andreu, M. E. Gonzalez-Nunez, R. Mello, J. O. Edwards and G. B. Carpenter, J. Org. Chem. 64, 4705 (1999).
20. M. M. Alavi Nikje, A. Rafiee and M. Haghshenas, Designed Monomers Polymers 9, 293 (2006).
21. M. M. Alavi Nikje, S. Motahari, M. Haghshenas and R. Khenar Sanami, J. Macromol. Sci. Part A: Pure and Appl. Chem. 43, 1205 (2006).
22. F. H. Rajabi, M. M. Alavi Nikje, B. Vasheghani Frahani and N. Sabouri, Designed Monomers Polymers 9, 383 (2006).
23. R. V. Gemmer, M. A. Golub, J. Polym. Sci. 16, 2985 (1978).