Epoxidation of polybutadiene using in situ generated dimethyl dioxirane (DMD) in the presence of tetra-n-butyl ammonium bromide

Designed Monomers and Polymers

Volumn 9, Issue 3, 2006, Pages 293-303

  Alavi Nikje, M M ^a   Rafiee, A ^a   Haghshenas, M ^b  

^a IMAM KHOMEINI INTERNATIONAL UNIVERSITY   (Iran)

^b Engineering Research Institute   (Iran)

Author keywords

Epoxidation; Functionalization; In situ generated dimethyldioxirane (DMD); Oxone ; Polybutadiene

Indexed keywords

AMMONIUM COMPOUNDS; CHEMICAL BONDS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; MICROSTRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; BROMINE COMPOUNDS; EPOXIDATION; POLYBUTADIENES;

EPOXIDATION; FUNCTIONALIZATION; IN SITU GENERATED DIMETHYLDIOXIRANE (DMD); OXONE®; PHASE TRANSFER CATALYST (PTC);

POLYBUTADIENES; AMMONIUM COMPOUNDS;

ECO-FRIENDLY; FUNCTIONALIZATIONS; FUNCTIONALIZED; IN SITU GENERATED DIMETHYLDIOXIRANE (DMD); IN-SITU; OVEROXIDATIONS; OXIRANES; PHASE TRANSFER CATALYSTS; REACTION CONDITIONS; RELATIVE REACTIVITIES; RING OPENING; SIDE PRODUCTS; TETRA-N-BUTYL AMMONIUM BROMIDES;

EID: 33745604254     PISSN: 1385772X     EISSN: None     Source Type: Journal    
DOI: 10.1163/156855506777351009     Document Type: Article

References (29)

1. M. P. McGrath, E. D. Sall and S. J. Tremont, Chem. Rev. 95, 381 (1995).
2. R. A. Sheldon and R. A. Van Santen, Catalytic Oxidation. World Scientific, Singapore (1995).
3. P. Wu, T. Tatsumi, T. Komatsu and T. Yashima, J. Catal. 202, 245 (2001).
4. D. E. De Vos, M. Dams, B. F. Sels and P. A. Jacobs, Chem. Rev. 102, 3615 (2002).
5. NEDO, Development of New Processes for Non-Halogen Chemical Processes. NEDO, Tokyo (2003).
6. T. Tatsumi, M. Misono and T. Murahashi, Green Chemistry -Chemistry towards a Sustainable Society. Kodoansha, Tokyo (2001).
7. D. N. Schulz, S. R. Turner and M. A. Gloub, Rubber Chem. Technol. 55, 809 (1982).
8. K. Upidi, J. Appl. Polym. Sci. 23, 3301 (1979).
9. K. Upidi, J. Appl. Polym. Sci. 23, 3311 (1979).
10. C. K. L. Davies, S. V. Wolfe, I. R. Gelling and A. G. Thomas, Polymer 24, 107 (1983).
11. P. Dreyfuss and J. P. Kennedy, Anal. Chem. 47, 771 (1975).
12. P. Dreyfuss and J. P. Kennedy, J. Appl. Polym. Sci. 47, 58 (1977).
13. G. G. Cameron and A. W. S. Duncan, Makromol. Chem. 184, 1153 (1983).
14. G. G. Cameron, M. Y. Qureshi and A. Rudin, Makromol. Chem. 187, 2761 (1986).
15. X. Jian and A. S. Hay, J. Polym. Sci. Part C: Polym. Lett. 28, 285 (1990).
16. J. M. J. Frechet and E. Eichler, Polym. Bull. 7, 345 (1982).
17. X. Jian and A. S. Hay, J. Polym. Sci. Polym. Chem. 29, 1183 (1990).
18. M. Antonietti, S. Forster, J. Hartmann and S. Oestriech, Macromolecules 29, 3800 (1996).
19. W. K. Huang, G. H. Hsiue and W. H. Hou, J. Polym. Sci. Polym. Chem. 26, 1867 (1988).
20. M. Leboucher-Duurand, V. Langlois and P. Guerin, React. Funct. Polym. 31, 57 (1996).
21. M. Gahagen, A. Iraqi, D. C. Cupertino, R. K. Mackie and D. J. Cole-Hamilton, J. Chem. Soc. Chem. Commun., 1688 (1989).
22. A. E. Gerbase, J. R. Gergorio, M. L. A. Von Holleben, M. A. M. Jacobi, L. L. Freitas, C. I. W. Calcagno, A. N. F. Mendes and M. L. Pires, Catal. Today 57, 241 (2000).
23. M. J. Tomaritis and A. G. Coutsolelos, Polymer 33, 1771 (1992).
24. M. M. Alavi Nikje and M. A. Bigdeli, Phosphor. Sulfur Silicon 179, 1445 (2004).
25. M. M. Alavi Nikje, M. A. Bigdeli and M. M. Heravi, Phosphor. Sulfur Silicon 177, 15 (2002).
26. M. M. Alavi Nikje, M. A. Bigdeli and M. M. Heravi, Phosphor. Sulfur Silicon 177, 2309 (2002).
27. M. A. Bigdeli, M. M. Alavi Nikje and M. M. Heravi, Indian J. Heterocycl. Chem. 11, 175 (2001).
28. D. Zuchowska, Polymer 21, 514 (1980).
29. S. Roy, B. R. Gupta and S. K. De, in: Elastomer Technology Handbook, N. P. Cheremisinoff (Ed.), pp. 635-660. CRC Press, Boca Raton, FL (1993).