Kinetic study of cis-polybutadiene functionalization by in-situ-generated dimethyldioxirane (DMD) in the presence of molybdenum oxide (MoO3) using 1H-NMR spectroscopy

Designed Monomers and Polymers

Volumn 9, Issue 4, 2006, Pages 383-392

  Rajabi, F H ^a   Alavi Nikje, M M ^a   Farahani, B V ^a   Saboury, N ^a  

^a IMAM KHOMEINI INTERNATIONAL UNIVERSITY   (Iran)

Author keywords

Dimethyldioxirane (DMD); Epoxidation; Kinetics; Molybdenum oxide MoO3; Polybutadiene; Potassium peroxymonosulfate (Oxone )

Indexed keywords

ACETONE; CATALYSTS; CONCENTRATION (PROCESS); MOLYBDENUM COMPOUNDS; SYNTHETIC RUBBER; ACTIVATION ENERGY; ENZYME KINETICS; EPOXIDATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDANTS; POLYBUTADIENES; POTASSIUM; RATE CONSTANTS; SPECTRUM ANALYSIS;

DIMETHYLDIOXIRANE (DMD); EPOXIDATION; MOLYBDENUM OXIDE MOO3; POLYBUTADIENE; POTASSIUM PEROXYMONOSULFATE (OXONE®);

REACTION KINETICS; MOLYBDENUM OXIDE;

CATALYTIC EPOXIDATION; DIMETHYLDIOXIRANE; DOUBLE BONDS; EPOXIDATION REACTIONS; FUNCTIONALIZATIONS; KINETIC STUDY; REACTION TEMPERATURE; SIDE REACTIONS;

EID: 33748499139     PISSN: 1385772X     EISSN: None     Source Type: Journal    
DOI: 10.1163/156855506777952147     Document Type: Article

References (16)

1. J.-P. Arlie, Synthetic Rubbers Processes and Economic Data. Technip, Paris (1992).
2. H. Kaczmarek, Polym. Bull. 34, 211 (1995).
3. X. H. Wang, H. X. Zhang, Z. G. Wang and B. Z. Jiang, Polymer 38, 5407 (1997).
4. D. Swern, G. N. Billen, T. W. Findley and J. T. Scanlan, J. Am. Chem. Soc. 67, 1786 (1945).
5. P. Wichacheewa and A. E. Woodward, J. Polym. Sci. Polym. Phys. Edn. 16, 1849 (1978).
6. J. M. Yang, H. T. Lin and W. C. Lai, J. Membr. Sci. 208, 105 (2002).
7. K. A. Jorgensen, Chem. Rev. 89, 431 (1989).
8. A. H. Hoveyda, D. A. Evans and G. C. Fu, Chem. Rev. 93, 1307 (1993).
9. X. Zhang, S. Liu and J. Yin, J. Membr. Sci. 258, 78 (2005).
10. E. M. Davoras and A. G. Coutsolelos, J. Inorg. Biochem. 94, 161 (2003).
11. N. A. Kosel, V. N. Sapunov, B. S. Turov, V. V. Popova and B. F. Ustavshchikov, Polym. Sci. (USSR) Ser. A 22, 2411 (1980).
12. M. M. Alavi Nikje, A. Rafiee and M. Haghshenas, in: Functionalization of Polybutadiene Using Potassium Peroxymonosulfate in the Presence of Phase Transfer Catalyst, Malaysian Chemical Congress (MCC), 27-29 September (2004).
13. X. Jian and A. S. Hay, J. Polym. Sci. Polym. Chem. Edn. 29, 1183 (1991).
14. G. R. Howe and R. R. Hiatt, J. Org. Chem. 36, 2493 (1971).
15. R. A. Sheldon and J. K. Kochi, in: Metal Catalyzed Oxidations of Organic Compounds, p. 33. Academic Press, New York, NY (1981).
16. Y. Zhang, Y. Zhang, X. Z. Chen and Y. X. Zhang, J. React. Funct. Polym. 47, 93 (2001).